The origin of chondrules: experimental investigation of metastable liquids in the system Mg2SiO4-SiO2

Laser-melted magnesium silicate droplets, supercooled 400–750°C below their equilibrium liquidus temperatures before crystallization, were examined to provide a comparison with meteoritic and lunar chondrules and to examine physicochemical parameters that may indicate the conditions of their formation. Internal textures of the spherules strikingly resemble textures observed in some chondrules. Definite trends in crystal morphology, crystal width and texture were established with respect to nucleation temperature and bulk composition. Such trends provide a framework for determining the nucleation temperature of chondrules. The only phase to nucleate from the supercooled forsterite-enstatite normative melts was forsterite, which was present in more-than-normative amounts. Highly siliceous glass (~65wt. % SiO₂) was identified interstitially to the forsterite crystals in seven of the spherules and is thought to be present in all. The presence of enstatite and the large proportion of crystals in some meteoritic chondrules implies that they were maintained at temperatures considerably in excess of 600°C at some point in their history.     

Numerical solution of the dispersion equation using a variable dispersion coefficient: method and applications

ABSTRACT

The study presented herein forms part of a wider research project on dispersion prediction in open channel flows which include laboratory, field and numerical investigations. In this paper, a numerical model which uses finite elements in space and finite differences in time for the solution of the convective-dispersion equation is developed and verified. In the model, the dispersion coefficient is considered as a function of time (or distance) during the initial period. It is represented by a modified Fickian type model which has been calibrated by the authors using laboratory data. The numerical model has been used to predict concentration profiles of tracer studies carried out in the laboratory as well as in the field.     

Role of land-surface temperature feedback on model performance for the stable boundary layer

At present a variety of boundary-layer schemes is in use in numerical models and often a large variation of model results is found. This is clear from model intercomparisons, such as organized within the GEWEX Atmospheric Boundary Layer Study (GABLS). In this paper we analyze how the specification of the land-surface temperature affects the results of a boundary-layer scheme, in particular for stable conditions. As such we use a well established column model of the boundary layer and we vary relevant parameters in the turbulence scheme for stable conditions. By doing so, we can reproduce the outcome for a variety of boundary-layer models. This is illustrated with the original set-up of the second GABLS intercomparison study using prescribed geostrophic winds and land-surface temperatures as inspired by (but not identical to) observations of CASES-99 for a period of more than two diurnal cycles. The model runs are repeated using a surface temperature that is calculated with a simple land-surface scheme. In the latter case, it is found that the range of model results in stable conditions is reduced for the sensible heat fluxes, and the profiles of potential temperature and wind speed. However, in the latter case the modelled surface temperatures are rather different than with the original set-up, which also impacts on near-surface air temperature and wind speed. As such it appears that the model results in stable conditions are strongly influenced by non-linear feedbacks in which the magnitude of the geostrophic wind speed and the related land-surface temperature play an important role.     

The occurrence of nocturnal low‐level jets In new England and the Canadian maritimes

Abstract

Detailed low‐level wind data collected in southern New Brunswick each summer since 1973 have revealed the existence of a significant low‐level jet during the evening on many occasions. The major contributing factor is considered to be an opposing thermal wind generated by the land/sea surface temperature difference when the low‐level airflow parallels the coastline. The maximum wind is characteristically located between 300 and 500 m above msl. Intensities have been found as great as 15 m s^‐1 in excess of the 1000‐m wind speed. A detailed study is presented for a well‐documented case on 8 July 1975, using hourly information from three stations near Fredericton, N.B., and Doppler measurements of the drift of a specially equipped research aircraft. There is clear evidence of an undulation in the altitude of the “nose” of the low‐level jet and of a progressive increase in intensity from early evening until midnight.     

Considering dynamic soil structure interaction (SSI) effects on seismic isolation retrofit efficiency and the importance of natural frequency ratio

This paper utilizes and expands on existing coupled BEM–FEM (finite element method) methods for the investigation of the effects of soil structure interaction (SSI) on both an un-retrofitted and seismically isolated typical bridge structure. A simple numerical model of the bridge and surrounding soil is formulated and excited by an earthquake excitation. Utilizing Newmark's β FEM solution method along with the closed form B-spline BIRF method, the structural damped period, composite damping ratio, pier relative displacement, and base shear demand are monitored. From these results, the effects of SSI on this structure are identified. Additionally, the importance of the relative rigidity between the soil-foundation system and the bridge structure is also investigated. The results of the studies indicate that the response of the complete structure system considered is affected by the inclusion of SSI effects. Furthermore, the efficiency of the isolation measures designed using fixed base conditions is decreased by considering SSI over a certain relative rigidity range that is quantified using the structure to soil-foundation natural frequency ratio.     

Stratiform and vein U,Mo and Cu mineralization in the Novoveská Huta area,CSFR

U-Mo and Cu mineralization occurs in horizons as well as in veins in the Permian formations near Novoveská Huta. Ore mineralization is represented by uraninite, U-Ti oxides, coffinite, molybdenite, chalcopyrite, tennantite and pyrite. The isotopic composition of S and C displays a larger variability in the stratiform ores (³⁴S from –32.7 to +2.7 and ¹³C from –27.1 to — 0.5) These data suggest mixing of meteoric solutions with fluids of volcanic origin and a complex history. There is a narrower range of ³⁴S from –18.8 to –4.6 and ¹³C from –6.3 to –2.5% in quartz-carbonate veins with Cu mineralization suggesting a deep source of ore-bearing solutions. The Permian volcanics were a significant source of ore elements.Their contents of U, Mo, Cu and Y are from two to eight times higher than in sedimentary rocks. Accumulations of ore elements in the horizons were formed by the reduction and adsorption processes 240 ± 30 Ma ago according to U-Pb isotopic dating. Due to Alpine tectonism, these low-grade ores (U<0.1 wt%) were remobilized and higher-grade U-Mo ores (U>0.1 wt%) were formed 130 ± 20 Ma ago at temperatures ranging from 110 to 120° C, according to fluid inclusions. Younger veins with Cu mineralization were formed 115 ± 10 Ma according to the model age of Pb at temperatures ranging from 95 to 190°C.     

On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.