Accelerated relative sea-level rise and rapid coastal erosion:: testing a causal relationship for the Louisiana barrier islands

The role of relative sea-level rise as a cause for the rapid erosion of Louisiana's barrier island coast is investigated through a numerical implementation of a modified Bruun rule that accounts for the low percentage of sand-sized sediment in the eroding Louisiana shoreface. Shore-normal profiles from 150 km of coastline west of the Mississippi delta are derived from bathymetric surveys conducted during the 1880s, 1930s and 1980s. An RMS difference criterion is employed to test whether an equilibrium profile form is maintained between survey years. Only about half the studied profiles meet the equilibrium criterion; this represents a significant limitation on the potential applicability of the Bruun rule. The profiles meeting the equilibrium criterion, along with measured rates of relative sea-level rise, are used to hindcast shoreline retreat rates at 37 locations within the study area. Modeled and observed shoreline retreat rates show no significant correlation. Thus, in terms of the Bruun approach, relative sea-level rise has no power for hindcasting (and presumably forecasting) rates of coastal erosion for the Louisiana barrier islands.     

Persistent halogenated compounds in black guillemots (Cepphus grylle) from Greenland--levels, compound patterns and spatial trends

Twenty-seven black guillemot eggs and 39 livers were analysed for polychlorinated biphenyls (PCBs), chlorinated pesticides including chlordane-related compounds and toxaphene, and polybrominated diphenylethers (PBDEs). The samples were collected at Qeqertarsuaq (Godhavn, West Greenland) and Ittoqqortoormiit (Scoresbysund, East Greenland). The concentrations of halogenated organic compounds in samples from East Greenland were somewhat higher than the corresponding concentrations from West Greenland. Differences in compound patterns were found between West and East Greenland, with higher percentages of the heavier PCB molecules, p,p(')-DDE and alpha-HCH in the samples from Ittoqqortoormiit. Similarly, different levels and different compositions were observed for eggs and livers. The eggs had generally higher concentrations of all compounds as well as higher percentages of CHB-50, CHB-62 and alpha-HCH than liver samples from the same area. Dividing the liver samples into age groups revealed increasing concentrations with age.     

Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

Hydrologic factors controlling groundwater salinity in northwestern coastal zone,Egypt

The aim of this article is to assess the main factors influencing salinity of groundwater in the coastal area between El Dabaa and Sidi Barani, Egypt. The types and ages of the main aquifers in this area are the fractured limestone of Middle Miocene, the calcareous sandstone of Pliocene and the Oolitic Limestone of Pleistocene age. The aquifers in the area are recharged by seasonal rainfall of the order of 150 mm/year. The relationship of groundwater salinity against the absolute water level, the well drilling depth, and the ability of aquifer to recharge has been discussed in the present work. The ability of aquifer to locally recharge by direct rainfall is a measure of the vertical permeability due to lithological and structural factors that control groundwater salinity in the investigated aquifers. On the other hand, the fracturing system as well as the attitude of the surface water divide has a prime role in changing both the mode of occurrence and the salinity of groundwater in the area. Directly to the west of Matrouh, where the coastal plain is the narrowest, and east of Barrani, where the coastal plain is the widest, are good examples of this concept, where the water salinity attains its maximum and minimum limits respectively. Accordingly, well drilling in the Miocene aquifer, in the area between El Negila and Barrani to get groundwater of salinities less than 5000 mg/l is recommended in this area, at flow rate less than 10 m³/hr/well. In other words, one can expect that the brackish water is probably found where the surface water divide is far from the shore line, where the Wadi fill deposits dominate (Quaternary aquifer), acting as a possible water salinity by direct rainfall and runoff.     

CASM: a unified state parameter model for clay and sand

The purpose of this paper is to present a simple, unified critical state constitutive model for both clay and sand. The model, called CASM (Clay And Sand Model), is formulated in terms of the state parameter that is defined as the vertical distance between current state (v, p′) and the critical state line in v–ln p′ space. The paper first shows that the standard Cam-clay models (i.e. the original and modified Cam-clay models) can be reformulated in terms of the state parameter. Although the standard Cam-clay models prove to be successful in modelling normally consolidated clays, it is well known that they cannot predict many important features of the behavior of sands and overconsolidated clays. By adopting a general stress ratio-state parameter relation to describe the state boundary surface of soils, it is shown that a simple, unified constitutive model (CASM) can be developed for both clay and sand. It is also demonstrated that the standard Cam-clay yield surfaces can be either recovered or approximated as special cases of the yield locus assumed in CASM. The main feature of the proposed model is that a single set of yield and plastic potential functions has been used to model the behaviour of clay and sand under both drained and undrained loading conditions. In addition, it is shown that the behaviour of overconsolidated clays can also be satisfactorily modelled. Simplicity is a major advantage of the present state parameter model, as only two new material constants need to be introduced when compared with the standard Cam-clay models. © 1998 John Wiley & Sons, Ltd.     

Characterization of hard‐to‐differentiate dune stratification types in the Permian Coconino Sandstone (Arizona,USA)

Dune stratification types, which include grainfall, grainflow and ripple lamination, provide a record of the fine‐scale processes that deposited sediment on palaeo‐dune foresets. While these facies are relatively easy to distinguish in some cross‐bedded sandstones, for others – like the Permian Coconino Sandstone of northern and central Arizona – discrete stratification styles are hard to recognize at the bedding scale. Furthermore, few attempts have been made to classify fine‐scale processes in this sandstone, despite its renown as a classic aeolian dune deposit and Grand Canyon formation. To interpret depositional processes in the Coconino Sandstone, cross‐bed facies were characterized using a suite of sedimentary textures and structures. Bedding parameters were described at multiple scales via a combination of field and laboratory methods, including annotated outcrop photomosaics, strike and dip measurements, sandstone disaggregation and laser‐diffraction particle analysis, high‐resolution scans of thin sections, and scanning electron microscopy. Cross‐beds were observed to be laterally extensive along‐strike, with most dip angles ranging from the mid‐teens to mid‐twenties. While some cross‐bed sets are statistically coarser near their bases, others exhibit no significant vertical sorting trends. Both massive and laminated textures are visible in high‐resolution scans of thin sections, but laminae contacts are commonly indistinct, making normal and reverse grading difficult to define. Diagenetic features, such as stylolite seams and large pores, are also present in some samples and might indicate alteration of original textures like detrital clay laminae and carbonate minerals. Observed textures and sedimentary structures suggest that the cross‐beds may consist of grainflow and grainfall deposits, but these remain difficult to differentiate at outcrop and thin‐section scales. This characterization of fine‐scale processes will play a critical part in the development of depositional models for the Coconino Sandstone and elucidate interpretations for similar cross‐bedded formations.     

Analogue study of particle segregation in pyroclastic density currents, with implications for the emplacement mechanisms of large ignimbrites

Abstract Analogue flume experiments were conducted to investigate the transport and sedimentation behaviour of turbulent pyroclastic density currents. The experimental currents were scaled approximately to the natural environment in three ways: (1) they were fully turbulent; (2) they had a very wide range of particle sizes and associated Rouse numbers (the ratio of particle settling velocity to effective turbulent eddy velocity in the current); and (3) they contained particles of two different densities. Two sets of surge‐type experiments were conducted in a 5 m long, water‐filled lock‐exchange flume at five different volumetric particle concentrations from 0·6% to 23%. In one set (one‐component experiments), the currents contained just dense particles; in the other set (two‐component experiments), they contained both light and dense particles in equal volume proportions. In both sets of experiments, the population of each component had a log‐normal size distribution. In the two‐component experiments, the size range of the light particle population was selected in order to be in hydrodynamic equivalence with that of the dense particles. Dense particles were normally graded, both vertically and downstream, in the deposits from both sets of experiments. The mass loading (normalized to the initial mass of the suspension) and grain size of the dense component in the deposits decreased with distance from the reservoir and were insensitive to initial total particle concentration in the currents. On the other hand, in the two‐component experiments, the light particles were extremely sensitive to concentration. They were deposited in hydrodynamic equivalence with the dense particles from dilute currents, but were segregated efficiently at concentrations higher than a few per cent. With increasing particle concentration, the large, light particles were carried progressively further down the flume because of buoyancy effects. Deposits from the high‐concentration currents exhibited reverse vertical grading of the large, light particles. Efficient segregation of the light component was observed even if the bulk density of the current was less than that of the light particles. In both sets of experiments, marked inflexions in the rate of downstream decline in mass loading and maximum grain size of the dense component can be attributed to the presence of two different particle settling regimes in the flow: (1) particles with Rouse numbers >2·5, which did not respond to the turbulence and settled rapidly; and (2) particles with Rouse numbers <2·5, which followed the turbulent eddies and settled slowly. The results are applied to the transport and sedimentation dynamics of pyroclastic density currents that generate large, widespread ignimbrites. Field data fail to reveal significant departures from aerodynamic equivalence between pumice and lithic clasts in three such ignimbrites: the particulate loads of some large ignimbrites are transported principally in turbulent suspensions of low concentration. In some ignimbrites, the well‐developed inflexions in curves of maximum lithic (ML) size vs. distance can be attributed to the existence of distinct high and low Rouse number particle settling regimes that mark the transition from an overcharged state to one in which the residual particulate load is transported more effectively by turbulence.     

Natural attenuation, biostimulation and bioaugmentation on biodegradation of polycyclic aromatic hydrocarbons (PAHs) in mangrove sediments

The biodegradability of a mixture of PAHs, namely fluorene (Fl), phenanthrene (Phe) and pyrene (Pyr), in mangrove sediment slurry was investigated. At the end of week 4, natural attenuation based on the presence of autochthonous microorganisms degraded more than 99% Fl and Phe but only around 30% of Pyr were degraded. Biostimulation with addition of mineral salt medium degraded over 97% of all three PAHs, showing that nutrient amendment could enhance Pyr degradation. Bioaugmentation with inoculation of a PAH-degrading bacterial consortium enriched from mangrove sediments did not show any promotion effect and the degradation percentages of three PAHs were similar to that by natural attenuation. Some inhibitory effect was observed in bioaugmentation treatment in week 1 with only 50% Fl and 70% Phe degraded. These results indicate that autochthonous microbes may interact and even compete with the enriched consortium during PAH biodegradation. Natural attenuation appeared to be the most appropriate way to remedy Fl- and Phe-contaminated mangrove sediments while biostimulation was more capable to degrade Pyr-contaminated sediments. The study also shows that although a large portion of the added PAHs (more than 95%) was adsorbed onto the sediments at the beginning of the experiment, most PAHs were degraded in 4 weeks, suggesting that the degraders could utilize the adsorbed PAHs efficiently.