Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test,Texas, USA

Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic CO₂ that must be sequestered to mitigate global warming and related climate changes. To investigate the potential for the long-term storage of CO₂ in such aquifers, 1600 t of CO₂ were injected at 1500 m depth into a 24-m-thick “C” sandstone unit of the Frio Formation, a regional aquifer in the US Gulf Coast. Fluid samples obtained before CO₂ injection from the injection well and an observation well 30 m updip showed a Na–Ca–Cl type brine with ∼93,000 mg/L TDS at saturation with CH₄ at reservoir conditions; gas analyses showed that CH₄ comprised ∼95% of dissolved gas, but CO₂ was low at 0.3%. Following CO₂ breakthrough, 51 h after injection, samples showed sharp drops in pH (6.5–5.7), pronounced increases in alkalinity (100–3000 mg/L as HCO₃) and in Fe (30–1100 mg/L), a slug of very high DOC values, and significant shifts in the isotopic compositions of H₂O, DIC, and CH₄. These data, coupled with geochemical modeling, indicate corrosion of pipe and well casing as well as rapid dissolution of minerals, especially calcite and iron oxyhydroxides, both caused by lowered pH (initially ∼3.0 at subsurface conditions) of the brine in contact with supercritical CO₂.     

Searches for very high energy gamma rays from blazars with CANGAROO-III telescope in 2005-2009

We have searched for very high energy (VHE) gamma rays from four blazars using the CANGAROO-III imaging atmospheric Cherenkov telescope. We report the results of the observations of H 2356-309, PKS 2155-304, PKS 0537-441, and 3C 279, performed from 2005 to 2009, applying a new analysis to suppress the effects of the position dependence of Cherenkov images in the field of view. No significant VHE gamma ray emission was detected from any of the four blazars. The GeV gamma-ray spectra of these objects were obtained by analyzing Fermi/LAT archival data. Wide range (radio to VHE gamma-ray bands) spectral energy distributions (SEDs) including CANGAROO-III upper limits, GeV gamma-ray spectra, and archival data, even though they are non-simultaneous, are discussed using a one-zone synchrotron self-Compton (SSC) model in combination with a external Compton (EC) radiation. The HBLs (H 2356-309 and PKS 2155-304) can be explained by a simple SSC model, and PKS 0537-441 and 3C 279 are well modeled by a combination of SSC and EC model. We find a consistency with the blazar sequence in terms of strength of magnetic field and component size.     

Radio Emission of Flares and Coronal Mass Ejections

We review recent progress on our understanding of radio emission from solar flares and coronal mass ejections (CMEs) with emphasis on those aspects of the subject that help us address questions about energy release and its properties, the configuration of flare?–?CME source regions, coronal shocks, particle acceleration and transport, and the origin of solar energetic particle (SEP) events. Radio emission from electron beams can provide information about the electron acceleration process, the location of injection of electrons in the corona, and the properties of the ambient coronal structures. Mildly relativistic electrons gyrating in the magnetic fields of flaring loops produce radio emission via the gyrosynchrotron mechanism, which provides constraints on the magnetic field and the properties of energetic electrons. CME detection at radio wavelengths tracks the eruption from its early phase and reveals the participation of a multitude of loops of widely differing scale. Both flares and CMEs can ignite shock waves and radio observations offer the most robust tool to study them. The incorporation of radio data into the study of SEP events reveals that a clear-cut distinction between flare-related and CME-related SEP events is difficult to establish.     

THE BEGINNING OF THE USING OF ZINC IN CHINA.

In my work, Lapidarium Sinicum, the chapter on brass is speciallydevoted to this inquiry. Recently Dr. Read of the U. S. Bureau of Mineswrote to Dr. Ting, suggesting the question whether "The knowledge ofzinc-smelting in India is previous to that developed in China." Therefore     

Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.     

Selection of regional historical rainfall time series as input to urban drainage simulations at ungauged locations

It has become established practice during the past 20 years to use high-resolution historical rainfall time series as input to hydrological model packages for detailed simulation of urban drainage systems. However, sufficiently long rain series are rarely available from the exact catchment in question and simulations are hence often based on available rain series from other locations. Extreme rainfall properties of importance to the performance of urban storm drainage systems vary significantly even in regions with only minor physiographic differences. Part of this variation can be explained by regional variations of the mean annual rainfall and the remaining statistical residue can be interpreted as statistical uncertainty.In Denmark, more than 75 high-resolution rain gauges are installed across a total area of 43,000 m. About 40 gauges had sufficiently long records to be included in a comprehensive national investigation where newly developed statistical regionalisation procedures were used to model the regional variation of extreme rainfalls. On this basis, a spreadsheet model was made available for estimation of extreme design rainfalls and the associated uncertainty at any location in the country. Statistics were furthermore computed to classify historical rainfall time series according to the developed regional model, and this makes it possible to assess the uncertainty related with using different historical rain series for simulations at ungauged locations.This research indicates that use of historical point rainfall data at ungauged locations introduces a significant uncertainty that is largely overlooked in today's practice. The engineering recommendation is to select historical rain series based on an evaluation of the local physiographic characteristics (e.g., the mean annual rainfall) and a (pre-defined) desired safety level of the simulations.     

An Improved Approach for Parameterizing Surface-Layer Turbulent Transfer Coefficients in Numerical Models

Based on classic iterative computation results, new equations to calculate the surface turbulent transfer coefficients are proposed, which allow for large ratios of the momentum and heat roughness lengths. Compared to the Launiainen scheme, our proposed scheme generates results closer to classical iterative computations. Under unstable stratification, the relative error in the Launiainen scheme increases linearly with increasing instability, even exceeding 15%, while the relative error of the present scheme is always less than 8.5%. Under stable stratification, the Launiainen scheme uses two equations, one for 0 < Ri _B ≤ 0.08 and another for 0.08 < Ri _B ≤ 0.2, and does not consider the condition that Ri _B > 0.2, while its relative errors in the region 0 < Ri _B ≤ 0.2 exceed 31 and 24% for momentum and heat transfer coefficients, respectively. In contrast, the present scheme uses only one equation for 0 < Ri _B ≤ 0.2 and another equation for Ri _B > 0.2, and the relative error of the present scheme is always less than 14%.     

A new algorithm to estimate sky condition based on 5 minutes-averaged values of clearness index and relative optical air mass

Summary This work describes a new algorithm to characterize sky condition in intervals of 5 min using four categories of sun exposition: apparent sun with cloud reflection effects; apparent sun without cloud effects; sun partially concealed by clouds; and sun totally concealed by clouds. The algorithm can also be applied to estimate hourly and daily sky condition in terms of the traditional three categories: clear, partially cloudy and cloudy day. It identifies sky conditions within a confidence interval of 95% by minimizing local climate and measurement effects. This is accomplished by using a logistic cumulative probability function to characterize clear sky and Weibull cumulative probability function to represent cloudy sky. Both probability functions are derived from frequency distributions of clearness index, based on 5 minutes-averaged values of global solar irradiance observed at the surface during a period of 6 years in Botucatu, Southeastern of Brazil. The relative sunshine estimated from the new algorithm is statistically comparable to the one derived from Campbell-Stocks sunshine recorder for both daily and monthly values. The new method indicates that the highest frequency of clear sky days occurs in Botucatu during winter (66%) and the lowest during the summer (38%). Partially cloudy condition is the dominant feature during all months of the year.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.