Assessment of regional air pollution distribution by point cumulative semivariogram method at Erzurum urban center, TURKEY

In the assessment of air quality, regional distribution and dispersion with distance are important, together with the variations of pollutants in time. On this occasion, the point cumulative semi-variogram (PCSV) method is used in order to find simply regional distribution of pollutants of Erzurum urban centre. This method is based simply on the summation of square differences in air pollutant concentrations between different sites. Monthly regional variation maps of Erzurum are constructed by finding radius of influence (for SO₂, from 1000 m to 3500 m and, for TSP, 1000–2000 m) and PCSV scattering diagram data at different levels by using monthly average sulphur dioxide (SO₂) and total suspended particulate (TSP) matter concentrations in 2001–2002 winter season. Consequently, the air pollution distribution of Erzurum is assessed.     

Neue Beobachtungen zur Deutung der knolligen Magnesite im Tonschieferkomplex des alpinen Buntsandsteins der Nördlichen Kalkalpen

Magnesitknollen in den roten Tonschiefern des alpinen Buntsandsteins (Werfener Schiefer) wurden in fast allen der bearbeiteten Profile zwischen Innsbruck und Saalfelden angetroffen. Es handelt sich um drei Typen von Magnesitknollen, die in ihrer Genese voneinander abweichen: 1. Kryptokristalline Konkretionen frühdiagenetischer Ausfällung; 2. Syntektonische Rekristallisationsgefüge von knolligem Habitus, die in ihrer Entstehung zeitlich mit der Durchbewegung der sandig-tonigen Nebengesteine zusammenfallen; 3. Postdeformative Spatmagnesite, welche innerhalb des schiefrigen Starrgefüges als Konkretionen auskristallisierten und die Wegsamkeit der Schieferung als bevorzugte Wachstumsrichtung benützten.

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Nodular magnesite has been found in most sections of Lower Triassic red beds (Werfener Schiefer) of the Northern Calcareous Alps between Innsbruck and Saalfelden, Austria. Three genetic types of magnesite can be differentiated: 1. Cryptocrystalline concretions of early diagenetic origin; 2. Syntectonic recrystallisation fabrics of nodular habit which formed while the sandshale matrix underwent deformation; 3. Post-tectonic spar-magnesite concretions which grew preferentially along tectonic cleavage surfaces.

     

On the temperature distribution in the solar corona

An improved value of coronal temperature is obtained by the degree of ionization method taking various processes into consideration. Comparison with some of the existing results has also been made.     

Observations of the structure and evolution of solar flares with a soft X-ray telescope

132 soft X-ray flare events have been observed with The Aerospace Corporation/Marshall Space Flight Center S-056 X-ray telescope that was part of the ATM complement of instruments aboard Skylab. Analyses of these data are reported in this paper. The observations are summarized and a detailed discussion of the X-ray flare structures is presented. The data indicated that soft X-rays emitted by a flare come primarily from an intense well-defined core surrounded by a region of fainter, more diffuse emission. Loop structures are found to constitute a fundamental characteristic of flare cores and arcades of loops are found to play a more important role in the flare phenomena than previously thought. Size distributions of these core features are presented and a classification scheme describing the brightest flare X-ray features is proposed. The data show no correlations between the size of core features and: (1) the peak X-ray intensity, as indicated by detectors on the SOLRAD satellite; (2) the rise time of the X-ray flare event, or (3) the presence of a nonthermal X-ray component. An analysis of flare evolution indicates evidence for preliminary heating and energy release prior to the main phase of the flare. Core features are found to be remarkably stable and retain their shape throughout a flare. Most changes in the overall configuration seem to be the result of the appearance, disappearance or change in brightness of individual features, rather than the restructuring or re-orientation of these features. Brief comparisons with several theories are presented.     

The effect of cracks on the thermal expansion of rocks

Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems.     

Sea‐level and ocean‐current control on carbonate‐platform growth,Maldives, Indian Ocean

Multichannel high‐resolution seismic and multibeam data were acquired from the Maldives‐isolated carbonate platform in the Indian Ocean for a detailed characterization of the Neogene bank architecture of this edifice. The goal of the research is to decipher the controlling factors of platform evolution, with a special emphasis on sea‐level changes and changes of the oceanic currents. The stacking pattern of Lower to Middle Miocene depositional sequences, with an evolution of a ramp geometry to a flat‐topped platform, reflects variations of accommodation, which here are proposed to be primarily governed by fluctuations of relative sea level. Easterly currents during this stage of bank growth controlled an asymmetric east‐directed progradation of the bank edge. During the late middle Miocene, this system was replaced by a twofold configuration of bank development. Bank growth continued synchronously with partial bank demise and associated sediment‐drift deposition. This turnover is attributed to the onset and/or intensification of the Indian monsoon and related upwelling and occurrence of currents, locally changing environmental conditions and impinging upon the carbonate system. Mega spill over lobes, shaped by reversing currents, formed as large‐scale prograding complexes, which have previously been interpreted as deposits formed during a forced regression. On a regional scale, a complex carbonate‐platform growth can occur, with a coexistence of bank‐margin progradation and aggradation, as well as partial drowning. It is further shown that a downward shift of clinoforms and offlapping geometries in carbonate platforms are not necessarily indicative for a sea‐level driven forced regression. Findings are expected to be applicable to other examples of Cenozoic platforms in the Indo‐Pacific region.     

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test,Texas, USA

Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic CO₂ that must be sequestered to mitigate global warming and related climate changes. To investigate the potential for the long-term storage of CO₂ in such aquifers, 1600 t of CO₂ were injected at 1500 m depth into a 24-m-thick “C” sandstone unit of the Frio Formation, a regional aquifer in the US Gulf Coast. Fluid samples obtained before CO₂ injection from the injection well and an observation well 30 m updip showed a Na–Ca–Cl type brine with ∼93,000 mg/L TDS at saturation with CH₄ at reservoir conditions; gas analyses showed that CH₄ comprised ∼95% of dissolved gas, but CO₂ was low at 0.3%. Following CO₂ breakthrough, 51 h after injection, samples showed sharp drops in pH (6.5–5.7), pronounced increases in alkalinity (100–3000 mg/L as HCO₃) and in Fe (30–1100 mg/L), a slug of very high DOC values, and significant shifts in the isotopic compositions of H₂O, DIC, and CH₄. These data, coupled with geochemical modeling, indicate corrosion of pipe and well casing as well as rapid dissolution of minerals, especially calcite and iron oxyhydroxides, both caused by lowered pH (initially ∼3.0 at subsurface conditions) of the brine in contact with supercritical CO₂.