On the transformation of struvite into newberyite in aqueous systems

The transformation of struvite MgNH₄PO₄ · 6H₂O into newberyite MgHPO₄ · 3H₂O is studied in aqueous solutions at 25° C and 37° C by following the evolution of solutions, supersaturated with respect to both phases in the concentration range 0.025–0.50 M. The precipitation of struvite as the first phase is accompanied by a sharp decrease of pH, which subsequently remains constant. During this period, newberyite crystals can nucleate whereas struvite is dissolving. Another decrease of pH, due to the newberyite growth, is observed when almost all struvite has disappeared. Finally pH tends asymptotically to a constant value, corresponding to a stable equilibrium. The whole process may take several months. At neither stage were epitaxial relationships observed between struvite and newberyite. The shape of the newberyite crystals is an indicator of their origin in mineralogical and biological systems.     

Radiant flux as a guide to relative seismic efficiency

The parameters “radiant flux” (energy radiated per unit area of an earthquake fault in unit time) and “radiant flux per unit displacement” reflect the power dissipated on a fault during slip. Values for moderate-to-large earthquakes range over two orders of magnitude, implying considerable variations in seismic efficiency, even for events of similar magnitude occurring on faults of the same type.     

AERIAL SURVEY: COLONY OF HONG KONG

This paper describes the planning and implementation of a very extensive aerial survey contract undertaken by Hunting Surveys on behalf of the Hong Kong Government. From photography carried out during January and February 1963, photogrammetric plotting at 1 : 600 and 1 : 1200 proceeded steadily over a period of 5 years to the point where all but the highest land in the Colony had been surveyed at one or other of these two large scales. The problems arising from the rather unique terrain conditions and the urban and industrial development of Hong Kong are dealt with mainly from the photographic and photogrammetric aspect but reference is made to the contribution of the Crown Lands and Survey Office of the Public Works Department of Hong Kong, who provided all ground control and undertook field verification.     

周口店多足类化石

1932—1937年间在周口店中国猿人产地及其他地点采得八十馀件节足动物化石,多破碎,完整者极少。颜色不一,由乳白而棕黄,兼有呈半透明玻璃状者。经初步观察,应属节足动物门,多足纲,倍脚目,马陆科,计一属两种: 一、山马陆(Julus of.terrestris)此种在第一,三,十五地点及山顶洞均有发现。此与现生的山马陆无甚差异,仅肛板及由二肛板所成之肛门沟稍大。二、裴氏小马陆(Julus peii Chia & Liu(sp.nov.)此种於第一,四,十五地点及山顶洞均有发现。由身体及头部形态,身体环节数目(三十个以上),知其与山马陆同属。但其决非幼小山马陆,因其体节数目多於长成之山马陆。但与现生於日本的一种 Nipponoiulus truncatus 近似,惟後者体节数较少,尾端钝圆。关於马陆属化石,据现在所知最早发现於始新统地层中,直到现在仍有生存,变异极小。以上所述二种若非与其他脊椎动物化石共生於周口店地点,则其年代颇难鉴定,因其有以後爬入岩隙死後石化之可能,不过上述之标本不但有共生脊椎动物为证,且有的已埋藏於固结的砾岩中,其属於更新统时期可无疑义。     

Noble gas investigations of lunar rocks 10017 and 10071

The noble gases He, Ne, Ar, Kr and Xe and also K and Ba were measured in the Apollo 11 igneous rocks 10017 and 10071, and in an ilmenite and two feldspar concentrates separated from rock 10071. Whole rock K/Ar ages of rocks 10017 and 10071 are (2350 ± 60) × 10⁶ yr and (2880 ± 60) × 10⁶ yr, respectively. The two feldspar concentrates of rock 10071 have distinctly higher ages: (3260 ± 60) × 10⁶ yr and (3350 ± 70) × 10⁶ yr. These ages are still 10 per cent lower than the Rb/Sr age obtained by Papanastassiouet al. (1970) and some Ar⁴⁰ diffusion loss must have occurred even in the relatively coarse-grained feldspar.The relative abundance patterns of spallation Ne, Ar, Kr and Xe are in agreement with the ratios predicted from meteoritic production rates. However, diffusion loss of spallation He³ is evident in the whole rock samples, and even more in the feldspar concentrates. The ilmenite shows little or no diffusion loss. The isotopic composition of spallation Kr and Xe is similar to the one observed in meteorites. Small, systematic differences in the spallation Kr spectra of rocks 10017 and 10071 are due to variations in the irradiation hardness (shielding). The Kr spallation spectra in the mineral concentrates are different from the whole rock spectra and also show individual variations, reflecting the differences in target element composition. The relative abundance of cosmic ray produced Xe¹³¹ differs by nearly 50 per cent in the two rocks. The other Xe isotopes show no variations of similar magnitude. The origin of the Xe¹³¹ yield variability is discussed.Kr⁸¹ was measured in all the samples investigated. The Kr⁸¹/Kr exposure ages of rocks 10017 and 10071 are (480 ± 25) × 10⁶ yr and (350 ± 15) × 10⁶ yr, respectively. Exposure ages derived from spallation Ne²¹, Ar³⁸, Kr⁸³ and Xe¹²⁶ are essentially in agreement with the Kr⁸¹/Kr ages. The age of rock 10071 might be somewhat low because of a possible recent exposure of our sample to solar flare particles.     

Contribution to the origin of the Serguza lead-zinc-pyrite deposit,Northern Iraq

The origin of the Serguza lead-zinc deposit of the Northern Thrust Zone has been suggested to be epigenetic, hydrothermal, structurally controlled by a post Tertiary major fault zone. Reinterpretation of previously obtained data and the evaluation of the present results have provided enough evidence to argue for a different mode of formation. Based upon trace element content of the ore minerals, dating of galena, ore and country rock texture, and the results of the detailed geochemical and geophysical prospecting in the area, it seems that the deposit is strata-bound, stratigraphically controlled within the Triassic dolomites. Its simple mineralogy, chemistry, and other features are comparable with other early Alpine strata-bound leadzinc deposits of the Mediterranean Belt.     

Stratigraphische Untersuchungen an Sedimentkernen des ibero-marokkanischen Kontinentalrandes

Zusammenfassung Biostratigraphie und Ergebnisse der Grobkornanalyse an Sedimenten vom marokkanischen und portugiesischen Kontinentalhang werden an zwei Kernen erläutert. Folgende Parameter scheinen sich besonders zur Korrelation zu eignen: Anteil des terrigenen Materiales an der Sandfraktion, Pteropodengehalt, Korngrößenverteilung des terrigenen Detritus, relative Temperaturangaben nach planktonischen Foraminiferen, Windungssinn von dreiGloborotalia- Arten. Beide Kerne erreichen Sedimente der letzten Kaltzeit, was dadurch unterstrichen wird, daß eistransportiertes, terrigenes Material und Hinweise auf Temperaturminima nach planktonischen Foraminiferen zusammenfallen.

---

Biostratigraphy and the results of the sand grain analysis on Moroccan and Portuguese continental slope sediments are discussed. The investigation is based on samples taken from two cores. The following parameters seem to be well suited for correlation: The percentage of the terrigenous material of the sand-fraction, the pteropod content, grainsize distribution of the terrigeneous material, temperature curves based on planktonic foraminifera and coiling ratios of threeGloborotalia species.In both cores sediments from the last glacial period are reached. This is demonstrated by a very good correlation between the ice-transported terrigenous material and the temperature minima as determined by planktonic foraminifera.

---

Résumé Notre présente étude concerne la biostratigraphie et l'analyse sédimentologique de deux carottes prélevées sur la pente continentale maroco-portugaise. Des corrélations ont été déduites de l'évolution des paramètres suivants: Pourcentage du matériel terrigène et des ptéropodes de la fraction sableuse, répartition granulométrique du matériel terrigène, variation faunique des foraminifères planctoniques, sens de l'enroulement de trois espèces deGloborotalia.Ces deux sondages pénètrent dans les sédiments de la dernière période glaciaire. La présence de matériel terrigène transporté par les glaces et les indications de température fournies par les foraminifères planctoniques s'harmonisent et confirment l'affirmation précédente.

---

. : , Pterododen, , , Globorotalia. . .

     

Premieres datations par la methode K/Ar de quelques laves cenozoiques et quaternaires de sardaigne nord-occidentale

The K/Ar datings made on recent lavas of northwest Sardinia (Logudoro and Bosano districts) show that the calc-alkaline volcanism lasted about 11 m.y. It began at the Oligocene—Miocene limit and ended in the Middle Miocene.A Plio—Quaternary alkaline volcanic cycle followed the Middle Miocene sea transgression. These geochronological measurements complement a recent paleomagnetic study made on these Sardinian lavas.These data enable us to show that the northwest Sardinian volcanism is subsequent to the island drift. Thus, this movement would have ended in the Late Oligocene at the latest.

Résumé

Les datations K/Ar réalisées sur les laves récentes de Sardaigne nord-occidentale (régions du Logudoro et du Bosano) montrent que le volcanisme calco-alcalin a couvert une période de 11 M.A. environ; il a débuté à la limite Oligocène—Miocène pour s'achever au Miocène moyen. Un cycle volcanique alcalin d'âge plio—quaternaire a succédé à la transgression marine du Miocène moyen. Ces mesures géochronologiques complètent une étude paléomagnétique récente effectuée sur ces laves sardes. Ces données permettent de montrer que le volcanisme de la Sardaigne nord-occidentale est postérieur à la dérive de l'ile; ce mouvement aurait donc pris fin, au plus tard, à l'Oligocène supérieur.     

The Heliospheric Plasma Sheet Observed in situ by Three Spacecraft over Four Solar Rotations

Solar Physics - In this paper we present in situ observations of the heliospheric plasma sheet (HPS) from STEREO-A, Wind, and STEREO-B over four solar rotations in the declining phase of...     

东天山伊吾二叠纪花岗质杂岩体的锆石定年、地球化学及其构造意义

伊吾花岗质杂岩体主要由二长花岗岩和碱长花岗岩构成。锆石LA-ICP-MS U-Pb定年分析得到二长花岗岩和碱长花岗岩的侵位年龄分别为284.6±1.4Ma和284.0±1.1Ma。结合地质证据,此年龄表明该杂岩体形成于碰撞之后的二叠纪早期挤压-伸展转折阶段。岩石学、地球化学和同位素等方面的对比研究表明这两种岩石为同一岩浆演化的产物。与二长花岗岩相比,碱长花岗岩表现为硅、碱的含量较高,而铝的含量较低;富Th、U、Nb、Ta,贫Sr、P、Ti、Sm;DI和Rb/Sr升高,Nb/Ta和Zr/Hf下降,从二长花岗岩到碱长花岗岩表现出连续分异演化的趋势。计算得到二长花岗岩和碱长花岗岩的模式年龄(t_(DM))分别为693Ma和763Ma,ε_(Nd)(t)分别为+4.53和+4.64,(~(87)Sr/~(86)Sr)_i分别为0.703858和0.703855,表现出高ε_(Nd)(t)低(~(87)Sr/~(86)Sr)_i的特征。这些特征表明,伊吾岩体的岩浆来自新元古代时从亏损地幔分离出来的初生地壳源区。二长花岗岩岩浆是这种初生地壳岩浆演化的产物,而碱长花岗岩形成于二长花岗岩母岩浆经斜长石、磷灰石、钛铁氧化物、榍石、独居石、褐帘石和锆石等矿物分离结晶后的残留岩浆。