Pore-water response on seasonal environmental changes in intertidal sediments of the Weser Estuary,Germany

In order to determine time-dependent changes in estuarine pore-water chemistry and flux variations across the sediment-water interface, sediment cores of an intertidal mud flat in the Weser Estuary were taken monthly over a one-year period. Sediment temperature, pH, Eh, Cl^–, O₂, NO ₃ ^– , and SO ₄ ^2– pore-water concentrations were measured and showed variations that relate to the changes of surface temperature and estuarine water composition. Fick's first law was applied to quantify diffusive fluxes from concentration gradients in the diffusive boundary layer and in the pore water. Total nitrate fluxes were calculated from flux chamber experiments. Diffusive oxygen fluxes increased from 5 mmol m^–2 d^–1 in winter to 18 mmol m^–2 d^–1 in early summer, while nitrate fluxes into the sediment increased from 3 mmol m^–2 d^–1 in winter to 60 mmol m^–2 d^–1 in early summer. Oxygen and nitrate fluxes into the sediment correlated linearly to sediment temperature. Sulfate fluxes increased from 0.5 mmol m^–2 d^–1 in winter to 10 mmol m^–2 d^–1 in August and September. Converted into carbon fluxes, the sum of these oxidants ranged from 10 mmol m^–2 d^–1 in winter to 80 mmol m^–2 d^–1 in summer. An estimation of the upper limit of the annual nitrate flux into the sediment showed that about 10% of the 250,000 t of nitrate discharged annually by the river may be decomposed within the inner Weser Estuary.     

松辽盆地可地浸砂岩型铀矿成矿地质条件

本文重点讨论了松辽盆地的地质背景、铀源条件、铀矿化异常与岩相古地理以及盆地后期改造的关系，介绍了该盆地后期改造的特征、后期改造的动力条件及铀元素的再分配，探讨了铀矿化异常与复合砂体、氧化还原条件及剥蚀面的关系。在此基础上预测了铀成矿远景地区，选出找矿的重点层位。     

层析成像中的波形反演

在波动方程有限差分数值模拟基础上，用波形记录残差平方并建立目标函数。对目标函数进行梯度优化，我们得出了介质速度的迭代公式。通过计算目标函数梯度我们可以对介质进行速度校正，从而获得反演解。经数值试验证明这是一种很有效的反演方法。     

膨胀土判别与分类的灰关联分析法

基于灰色系统理论，给出一种用于膨胀土判别与分类的新方法—灰关联分析法。实际算例表明，该法具有简单方便、结果客观可靠等优点。     

民和盆地上侏罗统湿型冲积扇沉积

本文通过岩相特征、粘土矿物分布、早期成岩矿物组合、微量元素等特征的综合分析，认为民和盆地上侏罗统下部为一较典型的湿型冲积扇沉积。冲积扇扇中发育河道冲刷充填和漫流沉积，而泥石流不发育。沉积层序与现代湿型冲积扇可对比。扇体中粘土岩及早期成岩矿物组合中富含高岭石，应与扇体发育时的潮湿气候和弱酸性流体的较强的淋滤有关。由粘土岩中微量元素因子分析进一步表明，该地层中富硼、钒的特征与相邻非扇相地层明显不同     

金银寨铀矿的土溶滑坡及其防治初探

根据金银寨铀矿岩层裂隙发育，地表降水形成土溶滑坡的特征，采用水泥煤粉注浆加固，使边坡保持稳定。     

黑龙江省东部跃进山群中绿片岩的地球化学特征及地质意义

跃进山群出露位于佳木斯地块和那丹哈达地体之间，是完达山造山带的组成部分。它由大陆斜坡相沉积物、大洋中脊型玄武岩和洋岛型玄武岩组成，其中有镁铁－超镁铁质岩块体。它不是一个地层单位，而是与活动大陆边缘板块俯冲作用有关的蛇绿混杂岩     

Geochemistry of the Rare Earth Elements in Natural Terrestrial Waters：A Review of What Is Currently Knows

The range of observed chemical compositions of natural terrestrial waters varies greatly especially when compared to the essentially constant global composition of the oceans.The concentrations of the REEs in natural terrestrial waters also exhibit more variation than what was reported in seawater,In terrestrial waters ,pH values span the range from acid up to alkaline,In addition,terrestrial waters can range from very dilute waters through to highly concentrated brines.The REE concentrations and their behavior in natural terrestrial waters reflect these compositional ranges,Chemical weathering of rocks represents the source of the REEs to natural terrestrial waters and ,consequently,the REE signature of rocks can impart their REE signature to associated waters,In addition,Because of the typical low solubilities of the REEs both surface and solution complexation can be important in fractionating REEs in aqueous solution.Both of these processes are important in all natural terrestrial waters,however,their relative importance varies as a function of the overall solution composition,In alkaline waters,for example,Solution complexation of the REEs with carbonate ions appears to control their aqueous distributions whereas in acid waters,the REE signature of the labile fraction of the REEs is readily leached from the rocks.In circumneutral pH waters,both processes appear to be important and their relative significance has not yet been determined.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Environmental and legal aspects of karst areas

 Environmental impacts on karst settings are common as they are more sensitive than those of other rock terrains. Regulatory procedures that are effective in other rock terrains are not necessarily applicable to karst settings. Development and exploitation by man that affect the karst hydrology regime can trigger catastrophic events and result in numerous legal actions where the effects of changes go beyond property boundaries. A great variety of regulations and examples of litigation exist for karst areas. Received: 25 October 1994 · Accepted: 17 October 1995