A Comparison of Benzene and Toluene Plume Lengths for Sites Contaminated with Regular vs. Ethanol-Amended Gasoline

This article describes various statistical analyses of plume-length data to evaluate the hypothesis that the presence of ethanol in gasoline may hinder the natural attenuation of hydrocarbon releases. Plume dimensions were determined for gasoline-contaminated sites to evaluate the effect of ethanol on benzene and toluene plume lengths. Data from 217 sites in Iowa (without ethanol; set 1) were compared to data from 29 sites in Kansas that were contaminated by ethanol-amended gasoline (10% ethanol by volume; set 2). The data were log-normally distributed, with mean benzene plume lengths (± standard deviation) of 193 ± 135 feet for set 1 and 263 ± 103 feet for set 2 (36% longer). The median lengths were 156 feet and 263 feet (69% longer), respectively. Mean toluene plume lengths were 185± 131 feet for set 1 and 211 ±99 feet for set 2 (14% longer), and the median lengths were 158 feet and 219 feet (39% longer), respectively. Thus, ethanol-containing BTEX plumes were significantly longer for benzene (p < 0.05), but not for toluene. A Wilcoxon signed rank test showed that toluene plumes were generally shorter than benzene plumes, which suggests that toluene was attenuated to a greater extent than benzene. This trend was more pronounced for set 2 (with ethanol), which may reflect that benzene attenuation is more sensitive to the depletion of electron acceptors caused by ethanol degradation. These results support the hypothesis that the presence of ethanol in gasoline can lead to longer benzene plumes. The importance of this effect, however, is probably site-specific, largely depending on the release scenario and the available electron acceptor pool.     

The colonization of periphytic diatom species on artificial substrates in the Ashar canal, Basrah, Iraq

Studies have been conducted between March 1993 and March 1994 in the Ashar canal, a backwater of the Shatt al-Arab River, Iraq. Using artificial substrates, the colonization and development of seventy-five diatom species belonging to twenty genera could be revealed. Taxa apportionment varied seasonally as well as within each season. A few species have been found during all experiments. These are Amphora ovalis, Bacillaria paradoxa, Cocconeis placentula var. euglypta, Cyclotella meneghiniana, Cymbella ventricosa, Navicula tripunctata var. schizonemoides, Rhoicosphenia curvata, and Synedra ulna. The occurrence of B. paradoxa in Experiment 1 (March-April 1993) and Experiment 4 (end of January to beginning of March 1994) was higher than 50%. Similarity of species increased towards the end of each season, and the communities from experiments 1 and 4 were more similar than others. The experiments also suggest that week 4 represents the equilibrium phase while week 6 reflects the increase in biological interactions. The results could also indicate the sequence of primary colonizers and the community development towards the equilibrium.     

Water and sediment outbursts from advanced Franz Josef Glacier,New Zealand

The Franz Josef Glacier, Westland, New Zealand, has a history of catastrophic sediment‐laden outburst ?oods associated with extreme rainfall events when the glacier toe is advanced over its own sediments. Consideration of these events and inspection of recent sediment deposits suggest that there are three distinct modes of outburst. The ?rst is associated with fans fed by over?ow along the glacier margin. As the glacier has advanced across its own fore?eld gravels, it is inferred that the primary drainage conduit has developed a reach of negative slope. In high ?ows massive boulders can block the conduit, trapping lesser clasts. The resulting backup of water causes over?ows through marginal moulins, producing the fan type of deposit. The second type of outburst deposits massive imbricated boulders at a greater or lesser distance from the glacier portal. In this case, pressure buildup drives the blockage out of the portal where the boulders deposit. Smaller materials are generally carried away. The third type consists of very shallow ?ows, and produces massive gravel deposits of uncertain provenance. In this condition, the excess pressure in the conduit results in slight uplift of the glacier and widespread discharge of water and sediment below the glacier snout; gravels and smaller sediments are laid down in a massive deposit across the fore?eld. The massive, boulder‐veneered deposit from the December 1995 outburst is interpreted in the light of the above mechanisms as a hyperconcentrated ?ow deposit from hydraulic jacking, overlain by boulders emplaced by a subsequent conduit outburst. A possible association of outbursts with the present advanced position of the glacier is suggested. Copyright © 2003 John Wiley & Sons, Ltd.     

La vallée d'Ys : un paléoréseau hydrographique immergé en baie de Douarnenez (Finistère,France)

Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).     

New structural and petrologic data on Mesozoic schists in the Rhodope (Bulgaria): geodynamic implications

Structural analysis of low-grade rocks highlights the allochthonous character of Mesozoic schists in southeastern Rhodope, Bulgaria. The deformation can be related to the Late Jurassic–Early Cretaceous thrusting and Tertiary detachment faulting. Petrologic and geochemical data show a volcanic arc origin of the greenschists and basaltic rocks. These results are interpreted as representing an island arc-accretionary complex related to the southward subduction of the Meliata–Maliac Ocean under the supra-subduction back-arc Vardar ocean/island arc system. This arc-trench system collided with the Rhodope in Late Jurassic times. To cite this article: N.G. Bonev, G.M. Stampfli, C. R. Geoscience 335 (2003).     

Wrench tectonics flip at oblique subduction. A model from New Zealand

In eastern North Island New Zealand, oblique subduction of the Pacific Plate beneath the Australian Plate is associated with strain partitioning. Dextral along-strike component of displacement occurred first at Early Miocene major faults within the eastern fore-arc domain. These faults were active from Early Miocene to Pliocene times. Since Pliocene times, most of the movement occurs at western faults such as the Wellington Fault. The latter joins the back-arc domain to the north. The jump of wrench faulting is related to the oblique opening of the back-arc domain. Both phenomena are impeded southwards by the Hikurangi oceanic plateau entering the subduction zone. To cite this article: J. Delteil et al., C. R. Geoscience 335 (2003).     

Classification of artificial (man-made) ground

The legacy inherited from anthropogenic processes needs to be addressed in order to provide reliable and up-to-date ground information relevant to development and regeneration in the urban environment. The legacy includes voids as well as anthropogenic deposits (artificial ground). Their characteristics derive from former quarrying and mining activities industrial processes creating derelict ground, variably consolidated made ground, and contaminated groundwater and soils. All need to be systematically assessed to inform the planning process and provide the basis for engineering solutions. Site-specific investigation needs to be conducted on the back of good quality geoscientific data. This comes from ‘field’ survey, remotely sensed data interpretation, historical maps, soil geochemical sampling, and geotechnical investigation. Three-dimensional and, in the future, four dimensional, characterization of superficial deposits is required to reach an understanding of the potential spatial lithological variability of artificial ground and the geometry of important surfaces, i.e. the boundary conditions. The classification scheme for artificial ground outlined in this paper and adopted by the British Geological Survey, will help in achieving this understanding.     

An experimental investigation of LNAPL migration in an unsaturated/saturated sand

Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting.     

Radio identification and continuum spectra of decameter-wavelength sources

The paper describes a method for the radio identification of decameter-wavelength sources based on their continuum spectra and analysis of their coordinates in relatively large error boxes surrounding a specified position on the sky. The distribution of continuum spectra and identifications in other wavelength ranges are analyzed for the resulting radio catalog. Using identifications with the FIRST and NVSS surveys, the statistics of the spectral index-size and spectral index-flux density distributions for steep-spectrum sources have been studied, and a catalog of ultrasteep-spectrum (α相似文献