High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle

Synthetic spinel harzburgite and lherzolite assemblages were equilibrated between 1040 and 1300° C and 0.3 to 2.7 GPa, under controlled oxygen fugacity (f _{O 2}). f _{O 2} was buffered with conventional and open double-capsule techniques, using the Fe−FeO, WC-WO₂-C, Ni−NiO, and Fe₃O₄−Fe₂O₃ buffers, and graphite, olivine, and PdAg alloys as sample containers. Experiments were carried out in a piston-cylinder apparatus under fluid-excess conditions. Within the P-T-X range of the experiments, the redox ratio Fe³⁺/ΣFe in spinel is a linear function of f _{O 2} (0.02 at IW, 0.1 at WCO, 0.25 at NNO, and 0.75 at MH). It is independent of temperature at given Δlog(f _{O 2}), but decreases slightly with increasing Cr content in spinel. The Fe³⁺/ΣFe ratio falls with increasing pressure at given Δlog(f _{O 2}), consistent with a pressure correction based on partial molar volume data. At a specific temperature, degree of melting and bulk composition, the Cr/(Cr+Al) ratio of a spinel rises with increasing f _{O 2}. A linear least-squares fit to the experimental data gives the semi-empirical oxygen barometer in terms of divergence from the fayalite-magnetite-quartz (FMQ) buffer:

The structural state of the former lower continental crust in Calabria (S. Italy)

In the Northern Serre (S. Italy), a continuous section through a former lower continental crust is exposed (Schenk 1984, 1985). These granulite facies rocks have not been penetratively deformed during their uplift to higher crustal levels. Therefore, they allow to study the structural state of the lower continental crust. Most rockforming minerals, among them ortho- and clinopyroxene and cordierite, show recrystallization structures. Quarz basal subgrain boundaries are developed in lower levels of the lower crust and disappear toward higher levels. In addition to dimensional orientations of the rockforming minerals, the preferred crystallographic orientations of plagioclases, cordierite, amphibole, pyroxenes and, rarely, quartz reflect the strain orientation of the prograde high-T deformation. During this deformation, the stretching direction was constant NNE-SSW throughout the exposed lower crustal section. Shear indicators are rare. This points to the fact that deformation has been homogeneous and coaxial flattening. There is only a small variation in orientation and strength of textures throughout the exposed lower crust. Therefore, neighbouring layers of different composition rather than different deformation might serve as seismic reflectors in the former lower crust.

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Zusammenfassung In der nördlichen Serre (Süditalien) ist ein zusammenhängender Bereich einer ehemaligen kontinentalen Unterkruste aufgeschlossen (Schenk 1984, 1985). Diese granulitfaziellen Gesteine sind bei ihrem Aufstieg in höhere Krustenbereiche nicht durchgreifend überprägt worden. Deshalb läßt sich an ihnen noch der strukturelle Zustand der ehemaligen Unterkruste studieren. Außer in Feldspäten, Quarz und Amphibol tritt auch in Ortho- und Klinopyroxen und in Cordierit Rekristallisation auf. In tieferen Krustenniveaus sind im Quarz basisparallele Subkorngrenzen entwickelt, die in höheren Krustenbereichen nicht auftreten. Sowohl die Gestaltregelungen der gesteinsbildenden Minerale als auch die kristallographischen Plagioklas-, Cordierit-, Amphibol-, Pyroxen- und (seltener) Quarzregelungen spiegeln die Strain-orientierung der prograden hochtemperierten Deformation wider. Während dieser Deformation blieb die Streckung im gesamten Unterkrustenbereich konstant NNE-SSW orientiert. Scherindikatoren sind selten. Beides deutet darauf hin, daß die Deformation homogen und als koachsiale Plättung abgelaufen ist. Im gesamten aufgeschlossenen Unterkrustenbereich variieren weder Intensität noch Orientierung der kristallographischen und gestaltlichen Regelungen der gesteinsbildenden Minerale wesentlich. Deshalb sollten in der ehemaligen Unterkruste Lagen unterschiedlicher Deformation weniger als seismische Reflektoren in Frage kommen als Lagen unterschiedlicher Zusammensetzung.

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Résumé Le Massif de la Serre Septentrionale en Calabre (Sud de l'Italie) représente un tronçon d'une ancienne croûte continentale profonde (Schenk 1984, 1985). Les roches du faciès granulite qui le constituent n'ont pas subi de déformation penetrative lors de leur ascension dans les niveaux plus superficiels de la croûte. Leur étude permet donc de reconstruire les caractéristiques structurales de l'ancienne croûte profonde. Non seulement les feldspaths, le quartz et l'amphibole, mais encore l'orthopyroxène, le clinopyroxène et la cordiérite ont recristallisé. Dans les niveaux les plus profonds de la croûte on observe dans les cristaux de quartz des bordures de sous-grains parallèles à la base. Celles-ci n'apparaissent plus dans les niveaux plus superficiels. L'orientation des cristaux des minéraux constitutifs des roches, de même que l'orientation des réseaux cristallins du plagioclase, de la cordiérite, de l'amphibole, du pyroxène et (mais plus rarement) du quartz réflètent la direction de contrainte de la phase de déformation prograde de haute température. Pendant cette phase de déformation, la direction d'extension est demeurée NNE-SSW. Les témoins de cisaillement sont rares, ce qui montre que la déformation s'est effectuée de façon homogène, en relation avec un aplatissement coaxial. Les textures varient très peu en orientation comme en intensité dans toute la coupe de croûte profonde exposée. En conséquence, l'existence de réflecteurs sismiques devrait refléter des différences dans les compositions minéralogiques des roches plutôt que dans leurs caractéristiques structurales.

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Coulomb-trapped particles in the electromagnetic fields of an oblique magnetic rotator

An oblique, rotating magnetized sphere emits electromagnetic waves which, for large magnetization, can quickly accelerate charged particles to very high energies. A central, attractive Coulomb force can trap particles in the region beyond the light cylinder by balancing the accelerating influence of the radiation on the particles. We sample some of the particle orbits possible under these dynamical conditions. A general feature of these orbits is that non-interacting particles started with random initial conditions in the domain of attraction of these orbits will arrange themselves on a curve corotating with the axis of magnetization. Such particle configurations can be a source of pulsed radiation. In the idealized case of no interparticle interactions the spectral index for the radiation emitted by one frequently occurring configuration is found to be –2/3, for emission from radio to -ray frequencies. The dynamical conditions in this simple model closely match those prevalent in outer pulsar magnetospheres, making it possible that part of the radiation from pulsars is emitted by trapped plasma in the region beyond the light cylinder.     

Interpretation of the frequency distribution of isochrone ages of nearby F and G stars

The frequency distribution of isochrone ages of nearby F and G stars is used in a synthetic approach to the history of the star-formation rate (SFR). On the basis of stellar evolutionary sequences, age distributions are calculated for different assumptions on the SFR history. Models with a constant past SFR provide a good fit of the empirical age distributions, unless a feature at ages 4 Gyr. If real, a shoulder in the empirical frequency distribution of isochrone ages at 4–5 Gyr points toward an enhanced SFR during a more or less (1 to 6 Gyr) extended period which ceased with a peak about 4 Gyr ago. It is shown that models with such a nonmonotonous SFR history reproduce the empirical stellar age distribution and, moreover, the age-metallicity relation and the metallicity distribution of nearby stars. An era of enhanced star formation in this time interval is consistent with recently published interpretation of several age-dependent properties in different samples of nearby stars.     

The even-odd systematics inR-process nuclide abundances

We report and discuss solar systemN _R abundances for nuclidesA>70, obtained as differences between measured solar system abundances and calculatedS-process contributions. The abundance peak atA163 in the rare Earth element region reveals properties which are similar to those of theR-process peaks corresponding to magic neutron numbersN=82 andN=126. We observe that systematic differences in theN _R abundances of even-A and odd-A nuclides are restricted to specific mass regions. We discuss possible interpretations and conclude that these differences are most probably related to the properties of nuclear species during _– to the stability valley.... A genesis of the elements such as is sketched out would not be confined to our little Solar System, but would probably follow the same general sequence of events in every center of energy now visible as a Star. Sir William Crookes (1886)Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988.     

Bipolar nebulae and jets from young stars: Contributions from calar alto

The topic is reviewed with emphasis on observations in the optical and near infrared spectral range.Paper presented at a Workshop on The Role of Dust in Dense Regions of Interstellar Matter, held at Georgenthal, G.D.R., in March 1986.     

Nuclear reactions on accreting neutron star surface

The production of X-rays and gamma-rays in bursts is believed to be due to the rapid burning of matter accreted onto a neutron star surface from its companion, most probably a giant star. The accreted matter consists mainly of hydrogen and helium and a very small amount of heavy elements. Due to the infall of matter, the temperature at the bottom layers is raised to a value of the order of 10⁸ K. The neutron star surface density is>10⁷ g cm^–3. As hydrogen burning is a slow process under any temperature and density conditions, we consider the helium-burning reactions as the source of gamma-rays in the neutron star surface. Under high-density conditions the ordinary laboratory reaction rates should become modified. At high-density conditions, the strong screening effect due to the polarising cloud of electrons around the ions become important and enhances the reaction rates considerably. The helium-burning reactions are calculated under such conditions. The abundances of helium-burning products such as¹²C, 1¹⁶O, and²⁰Ne, etc., are computed. Under high-density and temperature conditions carbon is found to be more abundant than oxygen. Neon is completely absent in almost all the relevant physical conditions in which a strong screening effect is operative. It is suggested that explosive burning of accreted helium of 10^–13 M will account for the observed energy of gamm-ray burst.     

Response of earth and venus ionospheres to corotating solar wind stream of 3 July 1979

Corotating solar wind streams emanating from stable coronal structures provide an unique opportunity to compare the response of planetary ionospheres to the energy conveyed in the streams. For recurrent solar conditions the signal propagating outward along spiral paths in interplanetary space can at times exhibit rather similar content at quite different downstream locations in the ecliptic plane. Using solar wind measurements from plasma detectors on ISEE-3, Pioneer Venus Orbiter (PVO) and Helios-A, as well as in-situ ion composition measurements from Bennett Ion Mass Spectrometers on the Atmosphere Explorer-E and PVO spacecraft, corotating stream interactions are examined at Earth and Venus. During May–July 1979 a sequence of distinct, recurrent coronal regions developed at the Sun. Analysis of these regions and the associated solar wind characteristics indicates a corrresponding sequence of corotating streams, identifiable over wide distances. The time series of solar wind velocity variations observed at Earth, Venus, and the Helios-A positions during June–July attests to intervals of corotating stream propagation. The characteristics of the stream which passed Earth on July 3, are observed at Helios-A and at Venus (PVO) about 8 days later, consistent with the spiral path propagation delay times between the locations in the ecliptic plane. On July 3, Earth and Venus have a wide azimuthal separation of about 142 . Although the planetary environments are distinctly different, pronounced and somewhat analagous ionospheric responses to the stream passage are observed at both Earth and Venus. The response to the intercepted stream is consistent with independent investigations which have shown that the variability of the solar wind momentum flux is an important factor in the solar wind-ionosphere interaction at both planets.     

Upper limits on the total radiant energy of solar flares

We establish limits on the total radiant energy of solar flares during the period 1980 February – November, using the solar-constant monitor (ACRIM) on board the Solar Maximum Mission. Typical limits amount to 6 × 10²⁹ erg/s for a 32-second integration time, with 5σ statistical significance, for an impulsive emission; for a gradual component, about 4 × 10³² ergs total radiant energy. The limits lie about an order of magnitude higher than the total radiant energy estimated from the various known emission components, suggesting that no heretofore unknown dominant component of flare radiation exists.     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.