Long-term modeling of alteration-transport coupling: Application to a fractured Roman glass

To improve confidence in glass alteration models, as used in nuclear and natural applications, their long-term predictive capacity has to be validated. For this purpose, we develop a new model that couples geochemical reactions with transport and use a fractured archaeological glass block that has been altered for 1800 years under well-constrained conditions in order to test the capacity of the model.The chemical model considers three steps in the alteration process: (1) formation of a hydrated glass by interdiffusion, whose kinetics are controlled by a pH and temperature dependent diffusion coefficient; (2) the dissolution of the hydrated glass, whose kinetics are based on an affinity law; (3) the precipitation of secondary phases if thermodynamic saturation is reached. All kinetic parameters were determined from experiments. The model was initially tested on alteration experiments in different solutions (pure water, Tris, seawater). It was then coupled with diffusive transport in solution to simulate alteration in cracks within the glass. Results of the simulations run over 1800 years are in good agreement with archaeological glass block observations concerning the nature of alteration products (hydrated glass, smectites, and carbonates) and crack alteration thicknesses. External cracks in direct contact with renewed seawater were altered at the forward dissolution rate and are filled with smectites (400−500 μm). Internal cracks are less altered (by 1 or 2 orders of magnitude) because of the strong coupling between alteration chemistry and transport. The initial crack aperture, the distance to the surface, and sealing by secondary phases account for these low alteration thicknesses. The agreement between simulations and observations thus validates the predictive capacity of this coupled geochemical model and increases more generally the robustness and confidence in glass alteration models to predict long-term behavior of nuclear waste in geological disposal or natural glass in the environment.     

Beach morphology and change along the mixed grain-size delta of the dammed Elwha River, Washington

Sediment supply provides a fundamental control on the morphology of river deltas, and humans have significantly modified these supplies for centuries. Here we examine the effects of almost a century of sediment supply reduction from the damming of the Elwha River in Washington on shoreline position and beach morphology of its wave-dominated delta. The mean rate of shoreline erosion during 1939–2006 is ~ 0.6 m/yr, which is equivalent to ~ 24,000 m³/yr of sediment divergence in the littoral cell, a rate approximately equal to 25–50% of the littoral-grade sediment trapped by the dams. Semi-annual surveys between 2004 and 2007 show that most erosion occurs during the winter with lower rates of change in the summer. Shoreline change and morphology also differ spatially. Negligible shoreline change has occurred updrift (west) of the river mouth, where the beach is mixed sand to cobble, cuspate, and reflective. The beach downdrift (east) of the river mouth has had significant and persistent erosion, but this beach differs in that it has a reflective foreshore with a dissipative low-tide terrace. Downdrift beach erosion results from foreshore retreat, which broadens the low-tide terrace with time, and the rate of this kind of erosion has increased significantly from ~ 0.8 m/yr during 1939–1990 to ~ 1.4 m/yr during 1990–2006. Erosion rates for the downdrift beach derived from the 2004–2007 topographic surveys vary between 0 and 13 m/yr, with an average of 3.8 m/yr. We note that the low-tide terrace is significantly coarser (mean grain size ~ 100 mm) than the foreshore (mean grain size ~ 30 mm), a pattern contrary to the typical observation of fining low-tide terraces in the region and worldwide. Because this cobble low-tide terrace is created by foreshore erosion, has been steady over intervals of at least years, is predicted to have negligible longshore transport compared to the foreshore portion of the beach, and is inconsistent with oral history of abundant shellfish collections from the low-tide beach, we suggest that it is an armored layer of cobble clasts that are not generally competent in the physical setting of the delta. Thus, the cobble low-tide terrace is very likely a geomorphological feature caused by coastal erosion of a coastal plain and delta, which in turn is related to the impacts of the dams on the Elwha River to sediment fluxes to the coast.     

Détection de carrières souterraines par sismique haute résolution à Annet-sur-Marne (France)Underground cavities detection by using high resolution seismics at Annet-sur-Marne (France)

Seismic methods were tested to detect underground cavities in the surroundings of Annet-sur-Marne (Seine-et-Marne, France). Cavities are located in three Ludian gypsum layers, between 30 and 80 m in depth. A high resolution seismic profile 450 m long was carried out so that the first third and the other part are respectively above non-exploited and exploited areas. Data processing highlights a series of reflections related to the marl–gypsum interfaces in the non-exploited area, while these reflections disappear in the exploited area. With the help of numerical simulations, this feature is interpreted as a disorganisation of wave fronts reflected on interfaces because of the presence of cavities. To cite this article: G. Grandjean et al., C. R. Geoscience 334 (2002) 441–447.     

General relativistic magnetohydrodynamic and Monte Carlo Modeling of sagittarius A*

Using the tunneling method we derive the Hawking temperature of the nonextremal rotating charged black hole in the Gödel universe of five-dimensional minimal supergravity theory found by Wu. We successfully recovered the tunneling probability of charged Dirac particles and the expected Hawking temperature of the black hole, which is exactly consistent with that obtained by other methods.     

Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.