Effect of chlorine on near-liquidus phase equilibria of an Fe–Mg-rich tholeiitic basalt

The importance of Cl in basalt petrogenesis has been recognized, yet constraints on its effect on liquidus crystallization of basalts are scarce. In order to quantify the role of Cl in basaltic systems, we have experimentally determined near-liquidus phase relations of a synthetic Fe–Mg-rich basalt, doped with 0.0–2.5 wt% dissolved Cl, at 0.7, 1.1, and 1.5 GPa. Results have been parameterized and compared with previous data from literature. The effect of Cl on mineral chemistry and liquidus depression is dependent on the starting basaltic composition. The liquidus depression measured for a SiO₂-rich, Al₂O₃-poor basalt is smaller than that observed for a basaltic melt depleted in silica and enriched in FeO_T and Al₂O₃. The effect of Cl on depression of the olivine–orthopyroxene–liquid multiple saturation pressure does not seem to vary with the starting composition of the basaltic liquid. This suggests that Cl may significantly promote the generation of silica-poor, Fe–Al-rich magmas in the Earth, Mars, and the Moon.     

Effect of chlorine on near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 at 1 GPa: Implication for volatile‐induced melting of the Martian mantle

Martian magmas are thought to be rich in chlorine compared with their terrestrial counterparts. Here, we experimentally investigate the effect of chlorine on liquidus depression and near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 and compare these results with previous experimental results on the effect of chlorine on near‐liquidus crystallization of the surface basalts Humphrey and Fastball. Previous experimental results showed that the change in liquidus temperature is dependent on the bulk composition of the basalt. The effect of chlorine on liquidus depression is greater for lower SiO₂ and higher Al₂O₃ magmas than for higher SiO₂ and lower Al₂O₃ magmas. The bulk composition for this study has lower Al₂O₃ and higher FeO contents than previous work; therefore, we provide additional constraints on the effect of the bulk composition on the influence of chlorine on near‐liquidus crystallization. High pressure and temperature crystallization experiments were performed at 1 GPa on a synthetic basalt, of the bulk composition of NWA 6234, with 0–4 wt% Cl added to the sample as AgCl. The results are consistent with previous notions that with increasing wt% Cl in the melt, the crystallization temperature decreases. Importantly, our results have a liquidus depression ?T (°C) from added chlorine that is consistent with the difference in bulk composition and suggest a dependence on both the bulk Al₂O₃ and FeO content. Our results suggest that the addition of chlorine to the Martian mantle may lower magma genesis temperatures and potentially aid in the petrogenesis of Martian magmas.     

On the Parametrization of Urban Land Use in Mesoscale Models

The effects of urban structures on the distribution of meteorological variables can be included in mesoscale models by an appropriate parametrization. The different approaches are conventionally tested against wind profiles in the centre of the urban area while flow distortions around are not considered. In this study, the quality of different parametrizations in capturing the main wind-field modifications in, as well as around, a complex obstacle is investigated. The method applied consists of a building resolved microscale model and a mesoscale model including a suitable parametrization. The results demonstrate that a drag or a porosity approach can reproduce very satisfactorily the main characteristics of the airflow completely, while a simpler roughness length concept in general approximates the mean flow unsatisfactorily.     

Simulating damage evolution and fracture propagation in sandstone containing a preexisting 3-D surface flaw under uniaxial compression

Preexisting flaws and rock heterogeneity have important ramifications on the process of rock fracturing and on rock stability in many applications. Therefore, there is great interest in numerical modelling of rock fracture and the underlying mechanisms. We simulated damage evolution and fracture propagation in sandstone specimens containing a preexisting 3-D surface flaw under uniaxial compression. We applied the linear elastic damage model based on the unified strength theory following the rock failure process analysis code. However, in contrast to the rock failure process analysis code, we used the finite element method with tetrahedron elements on unstructured meshes. It provided higher geometrical flexibility and allowed for a more accurate representation of the disk-shaped flaw with various flaw depths, angles, and lengths through locally adapted meshes. The rock heterogeneity was modelled by sampling the initial local Young's modulus from a Weibull distribution over a cubic grid. The values were then interpolated to the computational finite element method mesh. This method introduced an additional length scale for the rock heterogeneity represented by the cell size in the sampling grid. The generation of three typical surface cracking patterns, called wing cracks, anti-wing cracks, and far-field cracks, were identified in the simulation results. These depend on the geometry of the preexisting surface flaw. The simulated fracture propagation, coalescence types, and failure modes for the specimens with preexisting surface flaw show good agreement with recent experimental studies.     

Storage of carbon in U.S. forests predicted from satellite data,ecosystem modeling,and inventory summaries

A plant and soil simulation model based on satellite observations of vegetation and climate data was used to estimate the potential carbon pools in standing wood biomass across all forest ecosystems of the conterminous United States up to the year 1997. These modeled estimates of vegetative carbon potential were compared to aggregated measurements of standing wood biomass from the U. S. Forest Service’s national Forest Inventory and Analysis (FIA) data set and the Carbon Online Estimator (COLE) to understand: 1) predominant geographic variations in tree growth rate and 2) local land cover and land use history including the time since the last stand-replacing disturbance (e.g., from wildfire or harvest). Results suggest that although wood appears to be accumulating at high rates in many areas of the U.S. (Northwest and Southeast), there are still extensive areas of relatively low biomass forest in the late 1990s according to FIA records. We attribute these low biomass accumulation levels to the high frequency of disturbances, which can be observed even in high production areas such as the Southeast due to frequent forest harvests. Ecosystem models like the one presented in this study have been coupled with satellite observations of land cover and green plant density to uniquely differentiate areas with a high potential for vegetative carbon storage at relatively fine spatial resolution.     

The wind-induced shaping and migration of an isolated dune: A numerical experiment

Numerical experiments are carried out to simulate the development and migration of a barchan dune starting with a conical pile of sand. Such an experiment is done in three steps: (1) computation of the steady-state wind field over and around a barchan using the numerical meso-scale simulation model FITNAH, whereby the horizontal variation of the friction velocity is also calculated; (2) computation of the sand transport using the friction velocity in the transport formula by Lettau and Lettau (1978); (3) computation of the erosion and deposition rates as the divergence of the sand transport, where a special treatment is used for the slip-face of the barchan dune. Adding these rates to the height field leads to a different shape of the dune after a time step t _h . Then this procedure has to be repeated for the next time step t _h .The results are in good agreement with observations: the initial pile of sand develops wings (horns) and a slip-face between them. In addition, flow separation over the lee-side can be simulated. Finally, the tendency to form a barchan in equilibrium is considered.