REE distribution in the resin-asphaltene fractions as a geochemical criterion for identification of sources of trace elements in oil

This paper reports REE data on resin-asphaltene components of oil from six oil-gas-bearing provinces and on bitumoids from inferred oil-source rocks (domanikites and bazhenites). It was shown that, regardless of geological-tectonic structure of the regions, oil composition, depth of reservoirs, and host lithologies, oil exhibits significant REE fractionation, and, unlike bitumoids, positive Eu anomaly. The (Eu/Sm)_n ratio increases from asphaltenes to resins and further to oils. Based on REE distribution in oil, source rocks, and bitumoids, it was concluded that deep-seated fluids were one of the possible sources that defined the trace element composition of oil.     

Rb/Sr isotope studies of Cretaceous granitoids in the central Chukchi region: correctness of geochronological interpretation of results

The validity of the Rb/Sr isotopic ages of Cretaceous granitoid complex in the central Chukchi region has been verified. The performed studies showed that the Rb/Sr isotopic ages of late-orogenic granitoids are not reliable. Their variation can be explained in terms of the mixing of primary mantle magmas with continental-crust matter. Most probably, the variation is due to the constant compositions of mixing components and their proportions.     

Application of a distributed erosion model for the assessment of spatial erosion patterns in the Lushi catchment,China

A grid-based erosion model is developed by integrating the distributed hydrological model, BTOPMC, with the modified USLE to estimate soil erosion and sediment outflow during single storms. The possible sheet, rill, channel erosion types, and sediment transport processes are considered within each grid under the model structure. Instead of representing the sheet erosion and rill erosion separately, the classic USLE method is modified to simulate the lumped sheet–rill erosion during storms. In the modification, the runoff ratio and a relevant correction coefficient are brought into the R-factor which improves the model’s applicability in predicting erosion during single storms. Instead of representing a grid with a unique erosion type, a channel component is assumed to exist in each grid, and its width varies with the upstream contributing area of the grid. This assumption avoids the problems that are caused by the difference between the channel widths in the upstream area and the downstream area if the grid is simply recognized as a channel grid. It also enables the model to be applicable in simulating soil erosion and sediment outflow from a large catchment. Through a case study in the Lushi catchment, China, the results show an overall satisfactory accuracy for the selected events. Moreover, by analyzing the spatial distribution of soil erosion or deposition, the erosion-prone areas are identified for the prioritization purpose.     

Synchrotron-excited luminescence of natural zircon

The luminescence properties of two single zircon crystals from kimberlite of Yakutia have been studied, excited by the DORIS HASYLAB synchrotron, Germany, within energy range from the visible to the soft X-ray region (5–25, 50–200, and 500–620 eV) at temperatures of 300 and 10 K. The luminescence spectra in the range of 2.5 to 6.0 eV and excitation spectra of the main bands have been examined, the physical nature of the luminescence centers has been discussed, and the luminescence properties of a crystal containing growth (radiation) structural defects and a crystal with the same impurities but annealed in air at 1200°C are compared. The zoned structure of the mineral has been considered and the value of the energy gap (E _g) in the mineral has been estimated at 7.1 eV. Two groups of luminescence bands caused by impurities of intrinsic (growth, radiation) nature (E _max = 2.1, 2.7–2.8, and 3.2–3.3 eV) and matrix luminescence (E _max = 4.4−4.7 and 5.4 eV) probably with the participation of excitons were distinguished on the basis of selective excitation of zircon with different synchrotron energies relative to the gap value (E _excit < E _g, E _excit ∼ E _g, and E _excit ≫ E _g). The short-lived component with a response time of 4 ns has been revealed in the afterglow of zircon in the region of 5.4 eV.     

U-Pb isotopic dating of zircons (SHRIMP-II) from granulites of the Ol’khon region of Western Baikal area

Doklady Earth Sciences -     

Mechanism and geochemical implications of the Late Holocene organic carbon burial event: an example from the southwest coast of India

Carbonaceous clay found in the palaeo-deposits of Meenachil River basin was analysed for the total organic carbon, nitrogen and textural characters. Radiocarbon dating of this clay formation and the embedded carbonized wood fragments was also done. The values obtained for the organic carbon, nitrogen and C/N ratio of the carbonaceous clay exhibited a very remarkable range, suggestive of different environmental conditions of formation. It is evident from the present study that since the lignin and cellulose are the dominant components of terrestrial higher plants, allochthonous and submerged organic matter have high C/N ratio. The radio carbon dating of the sediment and wood samples suggested that the palaeo-deposits of Meenachil River basin were formed as result of many transgrassive–regressive episodes, which had started even before the formation of Vembanad Lake. The formation of carbonaceous clay, as found sandwiched in palaeo-deposits, was due to the global eustatic sea-level fluctuations and tectonism.     

Geochemical evidence for the ophiolitic nature of the gabbros,gabbroanorthosites, and ultramafic rocks of the Gerbikan fragment of the Baladek Massif of the southeastern framing of the North Asian craton

The Baladek Massif represents a tectonic block located at the boundary between the SE framing of the North Asian craton and the fold structures of the Galam terrane of the Mongol-Okhotsk fold belt. According to the existing concepts, the rocks of this massif are regarded as Precambrian complexes of the aforementioned craton. This paper reports the results of studying the fragment of the Baladek Massif in the Gerbikan River basin. New geochemical data obtained on the gabbros, gabbroanorthosites, and ultramafic rocks testify to their similarity with typical ophiolite complexes. An underlying complex of metamorphic ultrabasic rocks, a layered complex of pyroxenites and “cumulate” gabbros, gabbroanorthosites, and a complex of isotropic gabbros were distinguished within this fragment. It is highly possible that the basic volcanic rocks and jaspers of the Silurian-Lower Devonian sequences of the Galam segment of the Mongol-Okhotsk fold belt also belong to the inferred ophiolite complex.