Thermal and isotopic profiling of the Pipeline hydrothermal system: Application to exploration for Carlin-type gold deposits

New exploration techniques are vital to the search for new orebodies in mature terranes, as well as for extensions of existing orebodies. This research focused on application of low-temperature dating techniques (primarily apatite fission-tracks) and stable isotope measurements (carbon and oxygen in carbonate rocks) in and around the Pipeline deposit, a Carlin-type gold system. The primary purpose of the project was to assess whether these techniques could provide exploration vectors that might be used in conjunction with other geologic, geochemical, and geophysical techniques to determine the locus of fossil hydrothermal fluid flow, and the attendant possibility of finding economic mineral deposits.At Pipeline, measurements of apatite fission-tracks and (U − Th) / He geochronometry yield a clear indication of the elevated temperatures associated with the fossil hydrothermal system. The pattern is one of a central target (Pipeline deposit) with decreasing thermal effects as far as several kilometers laterally from the known ore zone. Because of the irregular nature of fluid flow through fractures, a significant number of samples are required to discern this pattern, but the pattern is quite clear from the 32 samples in and around the Pipeline pit.Stable isotope measurements of carbonate rocks yield patterns centered on the Pipeline pit area. Oxygen isotopes in particular are shifted toward lower values as the result of interaction between the hydrothermal fluids and carbonate rocks. Carbon isotopes show a pattern, but it is somewhat more difficult to interpret than the oxygen isotope pattern. As with the geochronometric patterns, isotopic indications of fluid flow are present several kilometers from the ore zone at Pipeline. Also as with the geochronometric data, a relatively large sample set is required to see the pattern. At Pipeline, the patterns are evident in approximately 45 surface samples and very clearly in the cross-sections containing approximately 100 samples.From these data, it is clear that thermal and stable isotopic measurements on rocks at a significant distance from the known Pipeline hydrothermal system record the passage of hot fluids through the rock. Both techniques provide a footprint of the Pipeline system that is several diameters larger than the ore zone (as presently known). Therefore, thermochronologic and stable isotopic measurements can be utilized in conjunction with other techniques as part of an overall exploration strategy for Carlin-type deposits. Although these techniques do not provide a direct indication of the metal content of the fossil hydrothermal fluids, they do provide an indication of the robustness of fluid flow and the potential size of a hydrothermal system.     

The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere

The production rate and isotopic composition of H₂ derived from radiolytic reactions in H₂O were measured to assess the importance of radiolytic H₂ in subsurface environments and to determine whether its isotopic signature can be used as a diagnostic tool. Saline and pure, aerobic and anaerobic water samples with pH values of 4, 7, and 10 were irradiated in sealed vials at room temperature with an artificial γ source, and the H₂ abundance in the headspace and its isotopic composition were measured. The H₂ concentrations were observed to increase linearly with dosage at a rate of 0.40 ± 0.04 molecules (100 eV)⁻¹ within the dosage range of 900 to 3500 Gray (Gy; Gy = 1 J Kg⁻¹) with no indication of a maximum limit on H₂ concentration. At ∼2000 Gy, the H₂ concentration varied only by 16% across the experimental range of pH, salinity, and O₂. Based upon this measured yield and H₂ yields for α and β particles, a radiolytic H₂ production rate of 10⁻⁹ to 10⁻⁴ nM s⁻¹ was estimated for the range of radioactive element concentrations and porosities typical of crustal rocks. The δD of H₂ was independent of the dosage, pH (except for pH 4), salinity, and O₂ and yielded an αD_H2O-H2 of 2.05 ± 0.07 (αD_H2O-H2 = (D/H)_H2O to (D/H)_H2), slightly less than predicted radiolytic models. Although this radiolytic fractionation value is significantly heavier than that of equilibrium isotopic exchange between H₂ and H₂O, the isotopic exchange rate between H₂ and H₂O will erase the heavy δD of radiolytic H₂ if the age of the groundwater is greater than ∼10³ to 10⁴ yr. The millimolar concentrations of H₂ observed in the groundwater of several Precambrian Shields are consistent with radiolysis of water that has resided in the subsurface for a few million years. These concentrations are well above those required to support H₂-utilizing microorganisms and to inhibit H₂-producing, fermentative microorganisms.     

Changing poverty distribution in Bolivia: the role of rural–urban migration and urban services

Bolivia is a country with high levels of poverty and inequality among its peoples and regions. For the nation and its urban and rural areas, trends in the social and spatial distribution of poverty (and extreme poverty) are identified from 1976 to 2003 using UBN data with minor support where appropriate from poverty lines. The main survey between 1992 and 2001 uses composite and selected UBN to track detailed poverty change for the country’s nine departments, its ten largest cities and a selection of other smaller urban and rural municipalities. Because of rising background increases in population in the various surveyed administrative units, many instances of relative reductions in poverty are accompanied by rising absolute increases. Marked spatial variations in poverty and development in the country over the last several decades are identified as the main driver for the country’s quickening pace of rural–urban migration. As a result, the paper concludes by assessing two different but closely related views. One investigation tests the notion that because more poor people have been living in Bolivia’s cities than in its rural areas since the mid to late 1990s, rapid rural–urban migration has simply shifted the locus of poverty from the countryside to the cities in a process called, the ‘urbanisation of poverty.’ A second, more challenging, investigation assesses the view that the flow of poor rural people to the better serviced urban areas of Bolivia has actually acted to alleviate national poverty levels.     

Re-evaluation of focal depths and source mechanisms of selected earthquakes in the Afar depression

We present a stepwise inversion procedure to assess the focal depth and model earthquake source complexity of seven moderate-sized earthquakes  (6.2 > M _w > 5.1)  that occurred in the Afar depression and the surrounding region. The Afar depression is a region of highly extended and intruded lithosphere, and zones of incipient seafloor spreading. A time-domain inversion of full moment tensor was performed to model direct P and SH waves of teleseismic data. Waveform inversion of the selected events estimated focal depths in the range of 17–22 km, deeper than previously published results. This suggests that the brittle–ductile transition zone beneath parts of the Afar depression extends more than 22 km. The effect of near-source velocity structure on the moment tensor elements was also investigated and was found to respond little to the models considered. Synthetic tests indicate that the size of the estimated, non-physical, non-isotropic source component is rather sensitive to incorrect depth estimation. The dominant double couple part of the moment tensor solutions for most of the events indicates that their occurrence is mainly due to shearing. Parameters associated with source directivity (rupture velocity and azimuth) were also investigated. Re-evaluation of the analysed events shows predominantly normal faulting consistent with the relative plate motions in the region.     

Landslide susceptibility and hazard mapping in Australia for land-use planning — with reference to challenges in metropolitan suburbia

This paper provides an overview of the history and current status of landslide susceptibility and hazard mapping for land-use zoning in Australia. It also describes a case study of landslide hazard mapping in a medium density, coastal, suburban residential area of metropolitan Sydney, New South Wales, Australia, with relatively steep terrain. Issues covered include identification and mapping of existing and potential landslides, and susceptibility and hazard zoning for regulatory management and land-use planning. The method involves application of the principles contained within the AGS (2000) guideline, and as updated by the AGS (2007 a,b,c,d,e) suite of guidelines.     

The formation and evolution of the Bitincke nickel laterite deposit, Albania

The Bitincke nickel laterite deposit, located in the south east of Albania, contains an estimated ore resource of 35.6?Mt of nickel ore with a grade of 1.2?% Ni. The deposit developed on peridotites within Late Jurassic ophiolites which were obducted in the Early Cretaceous and which form part of the Albanian Mirdita ophiolite zone. Limestones and conglomerates overlying the deposit delimit the minimum age of lateritization to the mid-Eocene. The laterite is composed of two distinct ore zones characterized by silicate nickel and iron oxide phases. Within the silicate zone, Ni concentrations reach a maximum of 1.5?wt% and although laterally and vertically variable this zone is typically characterized by olivine and serpentine at the base of the horizon which are gradually replaced by secondary silicates and iron oxides up section. The boundary between the silicate and the oxide zone above is normally sharp and characterized by an increase in Fe₂O₃ (from ~10 to 80?wt%), decreases in SiO₂ (from ~30 to 5?wt%) and a dramatic reduction in MgO content (from ~10 to 0.1?wt%). The oxide horizon is dominated by goethite and displays relatively little variation in textural morphology or geochemistry. Nickel concentrations are greatest near the base of this zone, reaching a maximum of 2.3?wt%. Weathering profile formation and variation in the thickness of the deposit was controlled by the interaction between topography, faulting and protolith fracture density. The oxide zone formed on topographic highs was subject to increased rates of erosion, whereas the laterite profile within topographic lows, and in areas of relatively high fracture density, tends to be thicker due to increased permeability. The most substantive sections of the Ni laterite weathering profile developed in small fault controlled basins and were preserved by the deposition of a sequence of limestones and mudstones.     

Wave propagation in a magnetic cylinder

The nature of oscillations in a magnetic cylinder embedded in a magnetic environment is investigated. It is shown that the standard slender flux tube analysis of a kink mode in a cylinder excludes the possibility of a second mode, which arises under photospheric conditions. Under coronal conditions, two widely separated classes of oscillation can be freely sustained, one on an acoustic time-scale and the other on an Alfvénic time-scale. The acoustic-type oscillations are always present, but the much shorter period, Alfvénic-type, oscillations arise only in high density (strictly, low Alfvén velocity) loops. An application to waves in fibrils is also given, and suggests (following Wentzel, 1979) that they are fast kink waves propagating in a density enhancement.     

Nonlinearly selected frequencies in coronal loops

A nonlinear process for the resonant generation of low-frequency fast magnetosonic kink waves in coronal loops is discussed. The efficiency of the process is strongly enhanced due to the existence of a nonlinearly selected frequency produced by a constant frequency difference in the dispersion curves in the short wavelength limit. The kink wave with the selected frequency interacts with high-frequency kink and sausage waves. The efficiency of such interaction does not require coherence in the interactive waves. In a loop of width 2 × 10³ km, field strength 50 G and number density 5 × 10¹⁵ m^–3, the nonlinearly selected frequency is of order 46 mHz (period 21.8 s), but this may range through 11 mHz to 184 mHz (periods 86.5 s to 5.4 s) for typical coronal conditions.     

Comparison of conceptual landscape metrics to define hillslope-scale sediment delivery ratio

The aim of this study was to evaluate four metrics to define the spatially variable (regionalised) hillslope sediment delivery ratio (HSDR). A catchment model that accounted for gully and streambank erosion and floodplain deposition was used to isolate the effects of hillslope gross erosion and hillslope delivery from other landscape processes. The analysis was carried out at the subcatchment (~ 40 km²) and the cell scale (400 m²) in the Avon-Richardson catchment (3300 km²), south-east Australia. The four landscape metrics selected for the study were based on sediment travel time, sediment transport capacity, flux connectivity, and residence time. Model configurations with spatially-constant or regionalised HSDR were calibrated against sediment yield measured at five gauging stations. The impact of using regionalised HSDR was evaluated in terms of improved model performance against measured sediment yields in a nested monitoring network, the complexity and data requirements of the metric, and the resulting spatial relationship between hillslope erosion and landscape factors in the catchment and along hillslope transects. The introduction of a regionalised HSDR generally improved model predictions of specific sediment yields at the subcatchment scale, increasing model efficiency from 0.48 to > 0.6 in the best cases. However, the introduction of regionalised HSDR metrics at the cell scale did not improve model performance. The flux connectivity was the most promising metric because it showed the largest improvement in predicting specific sediment yields, was easy to implement, was scale-independent and its formulation was consistent with sedimentological connectivity concepts. These properties make the flux connectivity metric preferable for applications to catchments where climatic conditions can be considered homogeneous, i.e. in small-medium sized basins (up to approximately 3000 km² for Australian conditions, with the Avon-Richardson catchment being at the upper boundary). The residence time metric improved model assessment of sediment yields and enabled accounting for climatic variability on sediment delivery, but at the cost of greater complexity and data requirements; this metric might be more suitable for application in catchments with important climatic gradients, i.e. large basins and at the regional scale. The application of a regionalised HSDR metric did not increase data or computational requirements substantially, and is recommended to improve assessment of hillslope erosion in empirical, semi-lumped erosion modelling applications. However, more research is needed to assess the quality of spatial patterns of erosion depicted by the different landscape metrics.