Natural Attenuation of Perchlorate in Denitrified Groundwater

Monitoring of a well‐defined septic system groundwater plume and groundwater discharging to two urban streams located in southern Ontario, Canada, provided evidence of natural attenuation of background low level (ng/L) perchlorate (ClO₄^?) under denitrifying conditions in the field. The septic system site at Long Point contains ClO₄^? from a mix of waste water, atmospheric deposition, and periodic use of fireworks, while the nitrate plume indicates active denitrification. Plume nitrate (NO₃^?‐N) concentrations of up to 103 mg/L declined with depth and downgradient of the tile bed due to denitrification and anammox activity, and the plume was almost completely denitrified beyond 35 m from the tile bed. The ClO₄^? natural attenuation occurs at the site only when NO₃^?‐N concentrations are <0.3 mg/L, after which ClO₄^? concentrations decline abruptly from 187 ± 202 to 11 ± 15 ng/L. A similar pattern between NO₃^?‐N and ClO₄^? was found in groundwater discharging to the two urban streams. These findings suggest that natural attenuation (i.e., biodegradation) of ClO₄^? may be commonplace in denitrified aquifers with appropriate electron donors present, and thus, should be considered as a remediation option for ClO₄^? contaminated groundwater.     

Low temperature (LT) combustion of sediments does not necessarily provide accurate radiocarbon ages for site chronology

Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies.     

Phase-array decomposition of a seismic section

A seismic re fraction/wide-angle reflection profile is analysed for the presence of correlated events ('phases'). The correlation problem is formulated in terms of temporally, spatially and frequency-local complex covariances. For robustness, the method concentrates on phase rather than amplitude information. This allows a computationally efficient algorithm that can make allowance for signal correlation length and can model curved wavefronts. A statistical test based on residual phase misfit across the analysed subarray is used to assess the probability that a detected event represents a real correlated signal.
With our chosen analysis parameters and confidence level (over 99.9 per cent). 1222 events were detected in the data. Using simple techniques based on 1-D earth models, detected events are associated with a small number of particular wave types. In this way, we have succeeded in classifying almost 95 per cent of the detected events. Those that remain describe those components of the data that are inconsistent with our simple ray paths in the 1-D assumption and with our prescribed tolerance. These include reverberations, near-surface guided waves and reflected waves from strongly laterally inhomogeneous structures. According to our modelling, about 25 per cent of the detected events are consistent with simple P -wave reflected energy, and these are to a very large extent (over 85 per cent) distinct from all the other wave-type models we have used. A direct mapping of the detected events into the offset-depth domain reveals dear internal and external consistencies among the detections for the various wave types. Estimated earth structure is consistent with models from previous analyses based on much larger data sets.
We have thus succeeded in extracting correlated events from the data and decomposing these, approximately but meaningfully, into distinct classes (ray paths)     

Application of optical techniques to the study of plumes in stratified fluids

Digital techniques for the correction of signal distortions that arise in planar laser-induced fluorescence (PLIF) measurements (by PC-based video digitizing systems) of jets and plumes and the production of flow statistics in both time and space are reviewed. The entire concentration field is repeatedly imaged in s intervals over hundreds of thousands a points in a plane. By the recognition of signal distortion sources and the employment of corrections, a clearer picture of tracer concentrations may be realized.Fluorescence studies are made with a planar sheet of laser light 430 mm tall and 1.5 mm thick. The fluorescence excitation produced from trace concentrations of Rhodamine 6G is used to visualize and measure the propagation of a jet or plume in a density stratified laboratory tank. The emitted light is collected by a CCD camera in a 512 × 480 pixel format over a 940 × 715 mm field of view. The captured images are corrected for transverse laser sheet intensity distribution; laser beam attenuation; refraction; lens vignette; time varying and spatial noise; digitization aspect ratio; camera response. The measurement and methods of correction are discussed in detail. The resulting image data can then be used to collect tracer concentration statistics for jets and plumes. Instantaneous (i.e. over of a second intervals), average, maximum, minimum, standard deviation, and coefficient of variation are given as introductory examples of image statistics realizable for a buoyant jet.     

Tracer anomaly evolution in the flow field of an isolated eddy

We explore the horizontal stirring of a passive tracer field in the vicinity of an isolated, finite amplitude, quasigeostrophic, β-plane eddy. We consider stirring in the presence of a uniform background gradient of tracer concentration as well as cases in which the tracer anomaly is initially contained within the eddy.This paper reports a survey of phenomenology based upon numerical experiments. We explore the sensitivity of results to physical parameters and to various aspects of the numerical simulation.Under the joint effects of β and of non-linearity, the eddy center migrates. Time dependent effects in a radiated wake provide important stirring mechanisms for the background tracer field. An unexpected, persistent result is a tendency to propel a tendril of tracer westward from near the launch latitude of the eddy. In some cases, the westward penetration of the tendril is even further than the migration of the eddy center.Tracer properties characteristics of the launch site of the eddy tend to be captured and carried with the eddy. However, tracer leaks from the eddy, due to both explicit diffusion-like effects and eddy interaction with background flow features, can result in drawing off of secondary tracer patches.We also calculate trajectories of Lagrangian particles launched in and around the eddy.     

Re-evaluation of focal depths and source mechanisms of selected earthquakes in the Afar depression

We present a stepwise inversion procedure to assess the focal depth and model earthquake source complexity of seven moderate-sized earthquakes  (6.2 > M _w > 5.1)  that occurred in the Afar depression and the surrounding region. The Afar depression is a region of highly extended and intruded lithosphere, and zones of incipient seafloor spreading. A time-domain inversion of full moment tensor was performed to model direct P and SH waves of teleseismic data. Waveform inversion of the selected events estimated focal depths in the range of 17–22 km, deeper than previously published results. This suggests that the brittle–ductile transition zone beneath parts of the Afar depression extends more than 22 km. The effect of near-source velocity structure on the moment tensor elements was also investigated and was found to respond little to the models considered. Synthetic tests indicate that the size of the estimated, non-physical, non-isotropic source component is rather sensitive to incorrect depth estimation. The dominant double couple part of the moment tensor solutions for most of the events indicates that their occurrence is mainly due to shearing. Parameters associated with source directivity (rupture velocity and azimuth) were also investigated. Re-evaluation of the analysed events shows predominantly normal faulting consistent with the relative plate motions in the region.     

Numerical experiments on the onset of convective instability in the Earth's mantle

Summary. A simplified model of convection in the mantle is used to investigate the transient effect of cooling a fluid layer from above, The model, representing the mantle overlain by the lithosphere, consists of a two-dimensional fluid layer overlain by a solid conducting lid. The initial temperature of both layers is the same, with the top surface of the lid kept at 0°C throughout. We observe the onset of small-scale flow in the model. In the absence of internal heating the behaviour of the system is controlled by the Rayleigh number, R , and the ratio of the thicknesses of the two layers, a . The onset time of convection as defined by reference to conduction temperature profiles is related simply to a boundary layer critical Rayleigh number. The mean temperature profiles for the convection model are also compared with the observed depth—age relation for oceanic lithosphere and the results are used to estimate the viscosity of the mantle.     

Comparison of conceptual landscape metrics to define hillslope-scale sediment delivery ratio

The aim of this study was to evaluate four metrics to define the spatially variable (regionalised) hillslope sediment delivery ratio (HSDR). A catchment model that accounted for gully and streambank erosion and floodplain deposition was used to isolate the effects of hillslope gross erosion and hillslope delivery from other landscape processes. The analysis was carried out at the subcatchment (~ 40 km²) and the cell scale (400 m²) in the Avon-Richardson catchment (3300 km²), south-east Australia. The four landscape metrics selected for the study were based on sediment travel time, sediment transport capacity, flux connectivity, and residence time. Model configurations with spatially-constant or regionalised HSDR were calibrated against sediment yield measured at five gauging stations. The impact of using regionalised HSDR was evaluated in terms of improved model performance against measured sediment yields in a nested monitoring network, the complexity and data requirements of the metric, and the resulting spatial relationship between hillslope erosion and landscape factors in the catchment and along hillslope transects. The introduction of a regionalised HSDR generally improved model predictions of specific sediment yields at the subcatchment scale, increasing model efficiency from 0.48 to > 0.6 in the best cases. However, the introduction of regionalised HSDR metrics at the cell scale did not improve model performance. The flux connectivity was the most promising metric because it showed the largest improvement in predicting specific sediment yields, was easy to implement, was scale-independent and its formulation was consistent with sedimentological connectivity concepts. These properties make the flux connectivity metric preferable for applications to catchments where climatic conditions can be considered homogeneous, i.e. in small-medium sized basins (up to approximately 3000 km² for Australian conditions, with the Avon-Richardson catchment being at the upper boundary). The residence time metric improved model assessment of sediment yields and enabled accounting for climatic variability on sediment delivery, but at the cost of greater complexity and data requirements; this metric might be more suitable for application in catchments with important climatic gradients, i.e. large basins and at the regional scale. The application of a regionalised HSDR metric did not increase data or computational requirements substantially, and is recommended to improve assessment of hillslope erosion in empirical, semi-lumped erosion modelling applications. However, more research is needed to assess the quality of spatial patterns of erosion depicted by the different landscape metrics.     

Development of tools to estimate conveyance losses in the Truckee River, USA

A method to estimate stream conveyance losses, including stream bank seepage and evapotranspiration from riparian areas, was developed for the Truckee River in California and Nevada (USA). Aquifer diffusivity is the primary variable required to compute aquifer head and seepage. Head and seepage conceptual models developed in previous studies were calibrated using stream stage and aquifer head at five sites along the Truckee River. The equations for head require numerical convolution to solve. It was found that head is insensitive to diffusivity and a single value for diffusivity provides good results at all study sites. Also, because releases from storage are usually prescribed as a step increase in flow for a given period of time followed by a step decrease in flow, an analytic solution for volume of seepage can be used in place of numerical convolution. Under typical operating conditions, seepage volume represents a small fraction of the total reservoir releases. Uncertainty in seepage estimates can be reduced with increased accuracy in hydraulic conductivity. This work demonstrates a valuable technique to estimate conveyance losses under natural and managed stream flow.