Nd isotopic evidence for juvenile crust in the Carolina terrane,southern Appalachians

 Nd isotopic analyses of whole-rock samples from the older portion of the Carolina terrane, one of the largest terranes in the Appalachian orogen, demonstrate that part of this terrane is composed of juvenile, mantle-derived crust. These data suggest that the terrane may not have originally been built upon old, evolved basement material but rather may have been built upon oceanic crust. A recent study by other workers demonstrates a more crustally evolved Nd isotopic signature for younger components of the Carolina terrane. These data may indicate that the terrane interacted with evolved crust at a later time, possibly by amalgamation with a more evolved crustal fragment before final accretion to Laurentia, rather than indicating a primary old basement. A juvenile nature for the older portion of the terrane contrasts with models that suggest it is an evolved crustal fragment that formed in a continental margin setting — a scenario proposed to explain the high proportion of felsic volcanic rocks within the terrane. It is herein suggested that Carolina is a chemically evolved but isotopically juvenile crustal fragment, because it remained in an oceanic setting for an unusually long time. In this regard the Carolina terrane is similar to some of the large accreted terranes in the Canadian Cordillera, such as Wrangellia and Alexander. The presence of juvenile crust in the Carolina terrane documents that at least part of the southern Appalachian orogen is not composed solely of reactivated pre-existing continental crust. The importance of this part of the orogen in terms of the volume of juvenile Phanerozoic crustal material in North America may be larger than previously thought. However, until additional major Appalachian terranes have been isotopically characterized the volume of juvenile crust in the whole orogen remains unknown. The isotopic make-up of a terrane can be an important aspect of terrane analysis as different terranes may have significantly different isotopic compositions, while even widespread pieces of a single terrane should have very similar isotopic characteristics. The Nd isotopic data for the Carolina terrane form the beginning of an isotope database for terranes in the southern Appalachians. Received: 15 June 1994/Accepted: 31 January 1995     

Weathering rates of sandstone in a semi-arid environment (Hunter Valley,Australia)

The rate of sandstone weathering in the semi-arid climate of the Hunter Valley, New South Wales, Australia has been estimated from observations of gravestone weathering in the area. The gravestone data points to two distinct stages in the weathering process. The first stage covering the first century of exposure is characterised by a relatively low recession rate of 0.5 mm/100 years. This is followed by a second stage in which the rate of weathering increases sharply to ca 2.5 mm/100 years. The non-linear nature of the weathering trends over time suggests that during the first century of exposure, structural changes took place within the sandstone material, which lay the foundation for accelerated weathering after further exposure. Laboratory trials were also conducted to identify the effectiveness of different weathering processes in the decay of sandstone in this region. Of the four processes examined, only the freeze–thaw cycle produced a significant degree of mass loss and is therefore most likely a strong contributor to the weathering of sandstone in this region.     

Drivers of Change and Sustainability in Linked Social–Ecological Systems: An Analysis in the Volta River Basin of Ghana,West Africa

Understanding the nature and relative importance of various drivers of change is crucial for sustainable management of natural resources and in prioritizing management efforts, allocating limited resources, and understanding cumulative effects. For this article, we employed structured an expert judgments approach to identify, characterize, and assess the relative importance of the key biophysical and socioeconomic drivers of change within the Volta River Basin, West Africa. Precipitation variability, water availability, land use change, drought events, and population growth were perceived as most important, while biodiversity loss, social conflicts, pest and disease occurrence, urbanization, and pollution were viewed as less critical. A majority of these drivers were characterized as “slow” acting processes as compared to rapidly changing drivers. Intra- and interexpert groups agreement were found to be significant and convergent, indicating the reliability of the results. The implications of these results for sustainable water resources management and agricultural production are discussed.     

Validation of ADEOS-II GLI ocean color products using in-situ observations

The Global Imager (GLI) aboard the Advanced Earth Observing Satellite-II (ADEOS-II) made global observations from 2 April 2003 to 24 October 2003. In cooperation with several institutes and scientists, we obtained quality controlled match-ups between GLI products and in-situ data, 116 for chlorophyll-a concentration (CHLA), 249 for normalized water-leaving radiance (nLw) at 443 nm, and 201 for aerosol optical thickness at 865 nm (Tau_865) and Angstrom exponent between 520 and 865 nm (Angstrom). We evaluated the GLI ocean color products and investigated the causes of errors using the match-ups. The median absolute percentage differences (MedPD) between GLI and in-situ data were 14.1–35.7% for nLws at 380–565 nm, 52.5–74.8% nLws at 625–680 nm, 47.6% for Tau_865, 46.2% for Angstrom, and 46.6% for CHLA, values that are comparable to the ocean-color products of other sensors. We found that some errors in GLI products are correlated with observational conditions; nLw values were underestimated when nLw at 680 nm was high, CHLA was underestimated in absorptive aerosol conditions, and Tau_865 was overestimated in sunglint regions. The error correlations indicate that we need to improve the retrievals of the optical properties of absorptive aerosols and seawater and sea surface reflection for further applications, including coastal monitoring and the combined use of products from multiple sensors.     

Impact of pore fluid chemistry on the thermal conductivity of bentonite–sand mixture

Thermal conductivity is an important parameter to consider when designing clay-based barriers for use in deep geological repositories (DGR). In the DGR environment, the infiltration of local saline groundwater can potentially change the pore fluid chemistry of a barrier over its lifetime. This change in chemistry is known to alter the thermal properties of the barrier materials. In order to examine the impact of pore fluid salinity on thermal conductivity, experiments were conducted under both distilled water and saline pore fluid conditions. The material mixtures were prepared at two different dry densities using two different salt types. Furthermore, five different thermal conductivity prediction models were selected and evaluated on their performance with respect to the experimental outcomes. In general, these results indicated that an increase in the constituent pore fluid’s salt concentration leads to a decrease in the thermal conductivity of the material. Additionally, the thermal conductivity values of the materials prepared at a high dry density were greater than of those compacted at a low dry density.     

Exploring the Solution Space of Semi-structured Geographical Problems Using Genetic Algorithms

Semi-structured geographical problems are often addressed by groups of decision-makers. Each group member is likely to have a specific set of objectives that they wish to address and a unique perspective on the way in which the problem should be solved. The solution to such problems often requires consensus building and compromise among decision-makers as they attempt to optimize their own criteria. The set of criteria adopted by a particular decision-maker constrains the set of solutions he/she will deem acceptable. Compromise among multiple decision-makers can occur at the intersection of these constrained solution sets. Knowledge about the criteria space, the solution space, and the relation between the two is often incomplete for semi-structured problems. New tools are needed to explore, analyze, and visualize the solution space of a problem with respect to multiple analytical models and criteria. In this research we explore the utility of genetic algorithms as an effective means to: (1) search the solution space of geographical problems; (2) visualize the spatial ramifications of alternative criteria spaces; and (3) identify compromise solutions.     

Steady convective exchange flows down slopes

: Horizontal exchange flows driven by destabilising buoyancy fluxes through the surface waters of lakes and coastal regions of oceans are important in understanding the transport of nutrients, micro-organisms and pollutants from littoral to pelagic zones. Our interest here is in the discharge flow driven by cooling or destabilising forcing at the water surface in a water body with variable depth due to sloping bottom topography. Flow visualisation studies and measurements in a laboratory model enabled us to develop scaling arguments to predict the dependency of discharge upon surface forcing and the angle of bottom slope. The results were used to interpret both the laboratory measurements and field data from a small shallow lake with sloping sides and an essentially flat bottomed interior, as well as published results from the literature. The steady state horizontal exchange can be described by Q = 0.24 B^1/3 (l tan //(1 + tan /))^4/3, where Q is the discharge rate per unit length of shoreline, / is the angle of the bottom slope, B is the surface buoyancy flux and l is the horizontal length of the forcing region over the slope. The flushing timescale of the wedge shaped littoral region was given by Ff ~ l ^2/3 (1 + tan /) ^4/3/ (B tan / ^1/3. While the buoyancy flux in the field is almost never constant in space or time and the slope from the shore is seldom uniform, we found that the exchange rate was relatively insensitive to buoyancy flux changes and only moderately sensitive to slope.