Geophysical observations bearing upon the origin of the newfoundland ridge

Multichannel reflection seismic profiles extending southward from the Grand Banks show gently dipping reflectors within “basement” features underlying the Newfoundland Ridge. These reflections appear to be from sedimentary strata, indicating that the Newfoundland Ridge is a remnant of a former sedimentary basin, rather than a ridge of oceanic crust as prescribed by plate tectonic models. Probably this feature is underlain, and to some extent surrounded by, continental crust.     

Iron-formation and glaciogenic rocks of the Rapitan Group,Northwest Territories,Canada

In northwestern Canada, iron-formation occurs as part of the Rapitan Group, a dominantly sedimentary succession of probable Late Precambrian age. The Rapitan Group contains abundant evidence of glaciogenic deposition. It includes massive mixtites which contain numerous faceted and striated clasts. Finely bedded and laminated sedimentary rocks of the Lower Rapitan contain many large isolated (ice-rafted?) intra- and extra-basinal clasts. The Lower and Middle Rapitan are interpreted as products of a glacial marine regime. The iron-formation is interbedded with thin mixtite beds and contains large exotic clasts which are probably indicative of the existence of floating ice at the time of deposition of at least part of the iron-formation. If the apparently low paleolatitudes are confirmed, then glacial marine interpretation of the Rapitan, and the probably correlative Toby Conglomerate of southern British Columbia, support the postulate of a very extensive Late Precambrian ice sheet in North America.Similar iron-formations of similar age are present in South America (Jacadigo Series), in South-West Africa (Damara Supergroup) and in South Australia (Yudnamutana Sub-Group). All of these iron-formations are associated with glaciogenic rocks. In addition to the iron-formations, dolostones, limestones and evaporites (?) are intimately associated with Late Precambrian mixtites, considered by many to be glaciogenic.Huronian (Early Proterozoic) and correlative sequences of North America, and rocks of similar age in South Africa also contain closely juxtaposed undoubted glaciogenic rocks, iron-formations, dolostones and aluminous quartzites. The dolostones and aluminous sedimentary rocks have been interpreted as having formed under warm climatic conditions, but might also be explained by invoking higher P_CO2 levels in the Early Proterozoic atmosphere. By analogy with the Huronian succession, preservation of “warm climate” indicators in mixtite-bearing Late Precambrian sequences does not preclude a glacial origin for the mixtites.     

The petrogenesis of komatiites and related rocks as evidence for a layered upper mantle

Although the CaO/Al₂O₃ ratio of komatiites has been regarded as one of the distinguishing features of these rocks, a comparison of various komatiite and oceanic tholeiite analyses suggests that there is a continuum of ratios between the two. The extremely high MgO values of peridotitic komatiites suggest that they are the result of high degrees of partial melting of the mantle, leaving a harzburgitic residuum depleted in CaO and Al₂O₃, and hence preserving in the melt the original CaO/Al₂O₃ ratio of the parental material. Available chemical models of the mantle have CaO/Al₂O₃ ratios too low to explain the origin of komatiite by such a process. Shallow-level melting of a layered mantle in which clinopyroxene content decreases and garnet content increases with depth, may explain the chemistry of komatiites and related ultrabasic lavas.     

Using geostatistics to elucidate temporal change in the spatial variation of aeolian sediment transport

Little is known about the spatial and temporal scales of variation in aeolian processes. Studies that aim to investigate surface erodibility often sample aeolian sediment transport at the nodes of a regular grid of arbitrary size. Few aeolian transport investigations have the resources to obtain sufficient samples to produce reliable models for mapping the spatial variation of transport. This study reports the use of an innovative nested strategy for sampling multiple spatial scales simultaneously using 40 sediment samplers. Reliable models of the spatial variation in aeolian sediment transport were produced and used for ordinary punctual kriging and stochastic simulated annealing to produce maps for several wind erosion events over a 25 km² playa in western Queensland, Australia. The results support the existence of a highly dynamic wind erosion system that was responding to possibly cyclic variation in the availability of material and fluctuations in wind energy. The spatial scale of transport was considerably larger than the small scale expected of the factors controlling surface erodibility. Thus, it appears that transport cannot be used as a surrogate of erodibility at the scale of this investigation. Simulation maps of transport provided considerably more information than those from kriging about the variability in aeolian sediment transport and its possible controlling factors. The proposed optimal sampling strategy involves a nested approach using ca 50 samplers. Copyright © 2003 John Wiley & Sons, Ltd.     

A theoretical model for reverse water-level fluctuations induced by transient permeability in thrust fault zones

A numerical model was applied to simulate the poroelastic response to changes in fault permeability as a result of earthquakes. The ‘fault valve’ model describes faults as impermeable barriers for fluids except immediately after earthquakes, when fault zones are damaged and transient pathways for fluids are created. In this case the fault is viewed as a discharging well, draining fluids from the surrounding rock. The reverse water-level effect is characterized by the increase of water level in adjacent aquifers and aquitards, resulting from withdrawing fluids through a well. Theoretical calculations suggest that the reverse water-level effect exists also in earthquake cycling and is in the same order of magnitude as the co-seismic hydraulic head change. A significant rise of the hydraulic head (>1 m) occurs within the country rock from both sides of the fault. The rise of the water level takes months to years to occur, and perhaps that is why it cannot be easily distinguished from seasonal hydrologic changes observed in the field. The reverse water-level effect also propagates away from the fault at a rate of hundreds of meters per year, depending on the permeability of the country rock. In deep formations where the permeability is low, the propagation takes years. The magnitude of the reverse water-level effect is greater when the fault efficiently drains fluids, when it is highly permeable and slow to reseal.     

A Modified Radial Diagram Approach for Evaluating Natural Attenuation Trends for Chlorinated Solvents and Inorganic Redox Indicators

Selection of monitored natural attenuation as a ground water remedy requires that sound scientific documentation clearly illustrating the effectiveness of this remedial alternative be presented to regulatory agencies and concerned citizens. An innovative radial diagram approach is applied to illustrate natural attenuation trends for total benzene, toluene, ethylbenzene, and xylenes (BTEX) and chlorinated ethenes at a former fire training area at Pittsburgh Air Force Base, New York. A BTEX-CAH (chlorinated aliphatic hydrocarbons) radial diagram map shows that concentrations of site contaminants are generally decreasing along the primary flowpath downgradient from the source area. This radial diagram map also suggests that there is a spatial correlation between decreasing CAH parent compound concentrations and increasing or stable daughter product concentrations. This provides secondary evidence of intrinsic biodegradation of TCE downgradient from the source area. A SEQUENCE-Redox™ map suggests that there is a spatial correlation between trends in electron acceptor and metabolic byproduct concentrations, and the decline in total BTEX concentrations downgradient from the source area. This correlation provides secondary evidence for the intrinsic biodegradation of total BTEX in the aquifer. This study demonstrates that radial diagram visual aids can provide a clear and efficient approach for documenting natural attenuation lines of evidence, as an alternative or a complement to using multiple contour maps, tabulated data, or log-linear plots.     

Cosmogenic Be dating of the Salpausselkä I Moraine in southwestern Finland

We determined in situ cosmogenic ¹⁰Be ages for nine boulders sampled on the Salpausselkä I (Ss I) Moraine. Previous dating of this moraine indicated that it formed during the Younger Dryas Stadial along the southern margin of the Scandinavian Ice Sheet in southern Finland. Our new exposure ages range from 10.9±1.0 to 13.5±1.2 ¹⁰Be ka, with an error-weighted mean age of 12.4±0.7 ¹⁰Be ka. Our results confirm four previous ¹⁰Be ages obtained 40 km northeast of our sample location. The combined data (n=13) indicate that retreat from the Ss I Moraine occurred at 12.5±0.7 ¹⁰Be ka, in excellent agreement with an age of 12.1 ka for retreat from the Ss I Moraine based on varve chronologies. These results identify the Ss I Moraine as among the best-dated margins associated with Late Quaternary ice sheets.     

The coprecipitation of Sr into calcite precipitates induced by bacterial ureolysis in artificial groundwater: Temperature and kinetic dependence

A suite of experiments was performed to investigate the partitioning of Sr²⁺ (to mimic the radionuclide ⁹⁰Sr) between calcite and artificial groundwater in response to the hydrolysis of urea (ureolysis) by Bacillus pasteurii under simulated in situ aquifer conditions. Experiments were performed at 10, 15, and 20°C over 7 days in microcosms inoculated with B. pasteurii ATCC 11859, containing an artificial groundwater and urea (AGW) or an AGW including a Sr contaminant treatment. During the experiments, the concentration of ammonium generated by bacterial ureolysis increased asymptotically, and derived rate constants (k_urea) that were between 13 and 10 times greater at 20°C than at 15 and 10°C. Calcite precipitation was initiated after similar amounts of urea had been hydrolyzed (∼ 4.0 mmol L^-1) and a similar critical saturation state (mean S_critical = 53, variation = 20%) had been reached, independent of temperature and Sr treatment. Because of the positive relationship between the rate of ureolysis and temperature, precipitation began by the end of day 1 at 20°C, and between days 1 and 2 at 15 and 10°C. The rate of calcite precipitation increased with, and was fundamentally controlled by calcite saturation state (S), irrespective of temperature. The presence of Sr slightly slowed calcite precipitation rates at equivalent values of S, which may reflect the screening of active nucleation and crystal growth sites by Sr. Homogeneous partitioning coefficients (D_Sr) exhibited a positive association with calcite precipitation rates, but were greater at higher experimental temperatures at equivalent precipitation rates (20°C mean = 0.46; 15°C mean = 0.24; 10°C mean = 0.29).     

Marine birds of the Hell Gate Polynya, Nunavut, Canada

The importance of the Hell Gate Polynya to marine birds in High Arctic Canada has not been assessed for two decades. Our breeding season surveys in 2002–04 found 19 species of marine birds using the polynya, in annual numbers perhaps reaching 25000 individuals. The site appears to support nationally significant populations of northern fulmar ( Fulmarus glacialis ), Thayer's gull ( Larus thayeri ) and High Arctic brant ( Branta bernida hrota ), as well as locally important numbers of other species including common eiders ( Somateria mollissima borealis ) and black guillemots ( Cepphus grylle ). The polynya may be particularly important for migration, as many species are observed here earlier than elsewhere in the High Arctic.