New data on the Pb isotope composition of Noril’sk sulfide ores

Doklady Earth Sciences -     

Transformation of the molecular and supramolecular structure of ozokerite under thermal effect

The transformation of the molecular and supramolecular structure under the thermal effect of ozokerites from the Yarega, Russia; the Borislav, Ukraine; and the Shorsu, Uzbekistan deposits was studied. The elemental analysis, infrared spectroscopy, thermal and X-ray diffraction analyses, gas-liquid and pyrolytic chromatography, gas chromatography-mass spectrosopy, and scanning electron and atomic force microscopy were used. Heating up to 500°C results, first of all, in a decrease in the relative amounts of normal paraffins. Significant transformations at the supramolecular level consist in the enlargement of previously existing structural elements and the formation of new supramolecular units.     

The construction of effective methods for electromagnetic modelling

Summary. This paper deals with the further development of finite-difference methods for electromagnetic field modelling in two-and three-dimensional cases. The main feature of the approach suggested here is the application of generalized asymptotic boundary conditions valid with the accuracy (1/ρ^N), where ρ is the distance from the heterogeneities. The finite-difference approximation of problems under solution is made using the balance method, which results in 5-point difference schemes in the 2-D case and 7-point difference schemes in the 3-D case. To solve the linear system of difference equations the successive over-relaxation (SOR) method is used, the relaxation factor being chosen during the iteration procedure. In view of the vectorial character of the problem for the 3-D case, a successive blocked over-relaxation method (SBOR) is applied.
The model's validity is based on the comparison of the fields accounted at the ground surface with those computed by the integral transformation of excessive currents, determined in the heterogeneity region using the finite-difference scheme.     

Deposition and remobilization of uranium in the North Baikal region: Evidence from the U-Pb isotopic systems of uranium ores

Based on the study of local volumes of minerals, including their microsampling and subsequent analysis of Pb/Pb and U/Pb isotope ratios with the classic methods of isotopic dilution and thermoionization mass spectrometry (TIMS), U-Pb and Pb-Pb isotopic datings of minerals were carried out in uranium ores from deposits in the Akitkan and Nechera-Nichatka ore districts (North Baikal region). Reliable evidence in favor of the Middle Devonian (384 ± 8 Ma) remobilization of Paleoproterozoic primary uranium concentrations and the redeposition of uranium as pitchblende 2 has been obtained for the first time for ores of the Akitkan district. The Paleoproterozoic (1832 ± 13 Ma) age of uraninite mineralization and the timing of the latest (377 ± 5 Ma) transformation of uranium ores at the Chepok deposit (Nechera-Nichatka district) are substantiated.     

The Schlema–Alberoda five-element uranium deposit,Germany: An example of self-organizing hydrothermal system

As a result of integrating geological, mineralogical, and geochemical data on the unique Schlema–Alberoda five-element uranium deposit situated in Federal Republic of Germany and explored in detail down to a depth of 2 km, it has been shown that its formation for more than 100 Ma has been caused by combination of internal and external factors. The latter comprise favorable metallogenic specialization of the region, injection of intrusive bodies bearing the necessary stock of energy, and periodic pulses of tectonic reactivation. The internal factors of self-development involve evolutionary processes, which occur in host rocks at the consecutive stages of prograde and retrograde metamorphism giving rise to alteration of rocks in consistence with physical and chemical laws at variable temperature and degree of system opening.     

Polygenetic and polychronic uranium mineralization at deposits of the Khiagda ore field,Buryatia

The unique combination of several exogenic processes augmenting uranium mineralization followed one another in time at deposits of the Khiagda ore field and gave rise to the formation of uranium resources exceptional for the paleovalley geologic and economic type. The specific geological evolution, volcanic activity, and regional climatic conditions taken together became the main cause of local occurrence of these deposits.     

Rajkonkoski gold-telluride ore occurrence: A new high prospective type of complex noble metal mineralization in the Karelian Proterozoic

The Rajkonkoski ore occurrence is located within the region of the Karelian craton (AR₂) and the Svecofennian folded belt (PR₁) conjugation. It is presented by quartz-carbonate veins in metadoleriles and a zone of brecciation, crumple, and silification of carbonaceous shales within the volcanites of the Soanlakhtinsky suite (PR₁). Ore mineralization in black shales and quartz veins has features of genetic similarity presenting different levels of the ore system controlled by different range strike-slip fault dislocations. At the Rajkonkoski ore occurrence, 41 ore minerals have been identified: 12 tellurides (native tellurium, hedleyite, pilsenite, tsumoite, tellurobismuthite, hessite, stuetzite, radclidzhite, joseite-B, altaite, volynskite, petzite); 4 bismuth-tellurides of the following compositions Bi₃Te, Bi₃Te₂, BiTe₄, PbBiTe; 3 selenides (clausthalite, tellurolaitakarite, native selenium); and 12 native metals (gold, silver, electrum, copper, iron, lead, tin, bismuth, osmiridium). The contents of the main ore minerals in places exceed 10%, and the concentrations of elements reach as follows: Cu and Pb, 5%; Zn, Bi, 1%; Se, 219 ppm; Te, 171 ppm; Sb, 3 ppm; As, 5 ppm; Ag, >0.1%; Au, 35.28 ppm. Ore mineralization is formed during the temperature interval from 550°C up to <170oC in the conditions of high activity of Se and Te, and beginning from medium temperatures (>300°C) complete miscibilities galenite-clausthalite and galenite-altaite are observed. In aggregate with a wide temperature interval (>400°C) of ore process evolution and mineral specia variety of telluride and native metal mineralizations, the original “torsion” of different temperature mineralizations makes it possible to determine the affiliation of the Rajkonkoski ore occurrence to the xenothermal type deposits or epithermal “alkaline,” gold-telluride A-type characterized by a close connection with magmatism of increased alkalinity and the original geochemical (Te-V-F) and mineral (tellurides of gold, silver and other metals, fluorite, roscoelite, vanadium-containing sulfides) associations. Taking into consideration that many of the xenothermal and epithermal A-type gold and silver deposits are large commercial objects, the prospects of the Rajkonkoski ore occurrence and the region of the Karelian craton and Svecofennian folded belt conjugation seem to be significant for noble metal mineralization.