Contrasting parageneses in the manganese silicate-carbonate rocks from Parseoni,Sausar Group,India and their interpretation

Mn silicate-carbonate rocks at Parseoni occur as conformable lenses within metapelites and calc-silicate rocks of the Precambrian Sausar Group, India. The host rocks are estimated to have been metamorphosed at uppermost P-T conditions of 500–550°C and 3–4 kbar. The Mn-rich rocks contain appreciable Fe, reflected in the occurrence of magnetite₍₁₎ (MnO 1%), magnetite₍₂₎ (MnO 15%) and magnetite₍₃₎ (MnO 10%). Two contrasting associations of pyroxmangite, with and without tephroite, developed in the Mn silicate-carbonate rocks under isothermal-isobaric conditions. The former assemblage formed in relatively Fe-rich bulk compositions and equilibrated with a metamorphic fluid having a low X _{CO 2} (<0.2), and the latter equilibrated with a CO₂-rich fluid. Rhodochrosite+magnetite₍₁₎+quartz protoliths produced the observed mineral assemblages on metamorphism. Partitioning of major elements between coexisting phases is somewhat variable. Fe shows preference for tephroite over pyroxmangite at the ambient physical conditions of metamorphism. Oxygen fugacity during metamorphism was monitored at or near the QFM buffer in tephroite bearing domains, and the fluid composition was buffered by mineral reactions in respective domains. As compared to other metamorphosed Mn deposits of the Sausar Group, the Mn silicate-carbonate rocks at Parseoni were, therefore, metamorphosed at much lower f _{O 2} through complex mineral-fluid interactions.     

Palaeocurrent and environmental implications from anisotropy of magnetic susceptibility (AMS): a case study from Talchir and Barakar formations,Raniganj Basin,West Bengal,India

Oriented cylindrical cores of rock samples were collected from the Talchir and Barakar formations of the Lower Gondwana Supergroup of the Raniganj Basin exposed in and around Kalyaneshwari and Maithon areas. The cores (2.54 cm diameter and 2.2 cm height) were studied in the low field anisotropy of magnetic susceptibility (AMS) measurement to determine the nature of magnetic fabrics, to correlate it with the sedimentological characteristics and to determine the palaeocurrent patterns. The results derived from the statistical parameters (especially the q-factor), the shapes of the susceptibility ellipsoids and directional data of the AMS indicate that the magnetic fabrics within the studied units are primary (depositional) and are correlatable form the palaeoenvironmental features. The orientation of the maximum (K₁), intermediate (K₂) and minimum (K₃) susceptibility axes is dispersed on the lower hemisphere equal area diagram rather than strong clusters which is not because of secondary (tectonic) influence but due to the moderate to high-energy environment of deposition of the sediments in the studied units. Based on the q-factor (which is 0.581 for Barakar Formation and 0.565 for Talchir Formation which are both <?0.7), it is suggested the AMS indicates that the imbrication of the K₁ axis is the indicator of palaeocurrent. Also, the magnetic foliation (average value?=?1.255) exceeds the magnetic lineation (average value?=?1.107) and the shape parameter exceeds 0 in most cases pointing towards an oblate fabric. The palaeocurrent in the present study as indicated by the K₁ axis imbrication is very similar in both the units under study and is due SW. However, apart from this precise palaeocurrent direction, there exists a certain degree of randomness of the susceptibility axes which are very clear indication of corresponding depositional environments.     

‘Direct’ evidence for water (H2O) in the sunlit lunar ambience from CHACE on MIP of Chandrayaan I

Direct detection of water in its vapour phase in the tenuous lunar environment through in situ measurements carried out by the Chandra’s Altitudinal Composition Explorer (CHACE) payload, onboard the Moon Impact Probe (MIP) of Chandrayaan I mission vindicates the presence of water on the surface of the moon in form of ice at higher lunar latitudes inferred from IR absorption spectroscopy, (especially that of OH), by the Moon Mineralogy Mapper (M³) of Chandrayaan I. The quadrupole mass spectrometer based payload, CHACE, sampled the lunar neutral atmosphere every 4 s with a broad latitudinal (∼40°N to 90°S, with a resolution of ∼0.1°) and altitudinal (from 98 km up to impact on the lunar surface with a resolution of ∼0.25 km) coverage in the sunlit side of the moon for the first time. These two (CHACE and M³) complementary experiments are shown to collectively provide unambiguous signatures for the distribution of water in solid and gaseous phases in Earth’s moon.     

The sunlit lunar atmosphere: A comprehensive study by CHACE on the Moon Impact Probe of Chandrayaan-1

The altitudinal/latitudinal profile of the lunar atmospheric composition on the sunlit side was unraveled for the first time by the Chandra’s Altitudinal Composition Explorer (CHACE) on the Moon Impact Probe, a standalone micro-satellite that impacted at the lunar south pole, as a part of the first Indian mission to Moon, Chandrayaan-1. Systematic measurements were carried out during the descent phase of the impactor with an altitude resolution of ∼250 m and a latitudinal resolution of ∼0.1°. The overall pressure on the dayside and the neutral composition in the mass range 1-100 amu have been measured by identifying 44 and 18 amu as the dominant constituents. Significant amounts of heavier (>50 amu) species also have been detected, the details of which are presented and discussed.     

Sedimentary manganese metallogenesis in response to the evolution of the Earth system

The concentration of manganese in solution and its precipitation in inorganic systems are primarily redox-controlled, guided by several Earth processes most of which were tectonically induced. The Early Archean atmosphere-hydrosphere system was extremely O₂-deficient. Thus, the very high mantle heat flux producing superplumes, severe outgassing and high-temperature hydrothermal activity introduced substantial Mn²⁺ in anoxic oceans but prevented its precipitation. During the Late Archean, centered at ca. 2.75 Ga, the introduction of Photosystem II and decrease of the oxygen sinks led to a limited buildup of surface O₂-content locally, initiating modest deposition of manganese in shallow basin-margin oxygenated niches (e.g., deposits in India and Brazil). Rapid burial of organic matter, decline of reduced gases from a progressively oxygenated mantle and a net increase in photosynthetic oxygen marked the Archean-Proterozoic transition. Concurrently, a massive drawdown of atmospheric CO₂ owing to increased weathering rates on the tectonically expanded freeboard of the assembled supercontinents caused Paleoproterozoic glaciations (2.45-2.22 Ga). The spectacular sedimentary manganese deposits (at ca. 2.4 Ga) of Transvaal Supergroup, South Africa, were formed by oxidation of hydrothermally derived Mn²⁺ transferred from a stratified ocean to the continental shelf by transgression. Episodes of increased burial rate of organic matter during ca. 2.4 and 2.06 Ga are correlatable to ocean stratification and further rise of oxygen in the atmosphere. Black shale-hosted Mn carbonate deposits in the Birimian sequence (ca. 2.3-2.0 Ga), West Africa, its equivalents in South America and those in the Francevillian sequence (ca. 2.2-2.1 Ga), Gabon are correlatable to this period. Tectonically forced doming-up, attenuation and substantial increase in freeboard areas prompted increased silicate weathering and atmospheric CO₂ drawdown causing glaciation on the Neoproterozoic Rodinia supercontinent. Tectonic rifting and mantle outgassing led to deglaciation. Dissolved Mn²⁺ and Fe²⁺ concentrated earlier in highly saline stagnant seawater below the ice cover were exported to shallow shelves by transgression during deglaciation. During the Sturtian glacial-interglacial event (ca. 750-700 Ma), interstratified Mn oxide and BIF deposits of Damara sequence, Namibia, was formed. The Varangian (≡ Marinoan; ca. 600 Ma) cryogenic event produced Mn oxide and BIF deposits at Urucum, Jacadigo Group, Brazil. The Datangpo interglacial sequence, South China (Liantuo-Nantuo ≡ Varangian event) contains black shale-hosted Mn carbonate deposits. The Early Paleozoic witnessed several glacioeustatic sea level changes producing small Mn carbonate deposits of Tiantaishan (Early Cambrian) and Taojiang (Mid-Ordovician) in black shale sequences, China, and the major Mn oxide-carbonate deposits of Karadzhal-type, Central Kazakhstan (Late Devonian). The Mesozoic period of intense plate movements and volcanism produced greenhouse climate and stratified oceans. During the Early Jurassic OAE, organic-rich sediments host many Mn carbonate deposits in Europe (e.g., Úrkút, Hungary) in black shale sequences. The Late Jurassic giant Mn Carbonate deposit at Molango, Mexico, was also genetically related to sea level change. Mn carbonates were always derived from Mn oxyhydroxides during early diagenesis. Large Mn oxide deposits of Cretaceous age at Groote Eylandt, Australia and Imini-Tasdremt, Morocco, were also formed during transgression-regression in greenhouse climate. The Early Oligocene giant Mn oxide-carbonate deposit of Chiatura (Georgia) and Nikopol (Ukraine) were developed in a similar situation. Thereafter, manganese sedimentation was entirely shifted to the deep seafloor and since ca. 15 Ma B.P. was climatically controlled (glaciation-deglaciation) assisted by oxygenated polar bottom currents (AABW, NADW). The changes in climate and the sea level were mainly tectonically forced.     

Kochi,India case study of climate adaptation to floods: Ranking local government investment options

Climate adaptation is uniquely linked to location, making it predominantly a local government and community responsibility. Despite the obligation to act, local governments are hindered by the absence of applicable guides to adaptation decision-making, especially adaptation to extreme events. In this paper, we describe a framework for prioritising adaptation options that could be locally implemented and illustrate it with a study of flooding in Kochi: a city in southern India. Unlike many demand driven, economics based studies, our new framework also incorporates non-economic dimensions of the extremes and potential adaptation options. Local knowledge is used to tackle data gaps and uncertainty related to extreme events: local experts select adaptation options that offer additional benefits besides those related to climate change. These co-benefits aid decision making under uncertainty by giving weight to community priorities. The Indian case study reveals that, risk evaluation and reduction need to be locally contextualised based on resources available, immediate community requirements, planning periods and local expert knowledge. Although there will be residual damage even after implementing selected options, we argue that, climate response will be most likely to be accepted when it also supports pressing needs.