Raman spectroscopy of nanocrystals in rock

Nanocrystals were detected and identified in rocks by the method of Raman spectroscopy. The experiments showed that the Raman scattering spectra of fine-lamellar arkosic sandstone exhibit bands corresponding to lattice vibrations of anatase, α-quartz, and plagioclase. In all spectra of the rock, the bands are displaced towards high frequencies as compared with their position in spectra of single crystals and widen on the same side. These results show that, in all of the studied places of the sample, the particles of anatase, quartz, and plagioclase have nanometer sizes, namely, of the order of 10 nm in anatase and quartz and about 20 nm in plagioclase. Moreover, in different places of the sample, not only the shape and position of the bands under study but also their intensity vary, the latter being directly proportional to the concentration of nanocrystals.     

Isotopic-geochemical signs of coal and bitumen transformation in different-type ore mineralization: Communication 1. Isotopic-geochemical signs of structural transformation of coal and bitumen

Results of the study of natural organic matter (OM) represented by classes of solid and high-molecular-compounds (resin, ozokerite, asphalt, kerite, graphite, and others) are presented. They are developed as dispersed and concentrated segregations, interlayers, and independent accumulations and impregnation in the fracture-vein system and stratiform bodies. They also accompany ore mineralization. Combination of modern tic mineralogical, chemical, isotopic, infrared spectroscopic, and X-ray photoelectron spectroscopic) analytical methods provide insight into the OM transformation during oil formation and ore genesis. Variations in OM composition and properties define the concentration of ore elements and change mechanisms of their fixation (sorption, chemosorption, and reduction). Isotopic-geochemical signs of the structural transformation of Coal and bitumen allow us to elaborate a unified scale of catagenesis and metamorphism of the sapropel-and humus-type OM.