Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).     

A RATAN-600 Zenith-Field sky survey. Catalog of radio sources

A catalog of radio sources detected in a deep RATAN-600 survey is presented. The catalog was obtained in the region 0^h ≤ RA_2000.0 ≤ 24^h, Dec_2000.0 = 41°30′42″ ± 2′, at the declination of the bright radio source 3C 84. There were nine sessions of multi-wavelength observations at wavelengths λ = 1–55 cm, and more than 300 daily scans were accumulated at each wavelength. This is the first stage in the reduction of an extensive database accumulated by the Cosmological Gene Project. The RATAN-600 Zenith Field (RZF) catalog was obtained at the central wavelength of 7.6 cm, and contains 437 radio sources, virtually all of which have been identified with NVSS objects. Most of the flux densities for the catalog sources are above the 5σ level. Noise from faint (mainly new) background sources at a level of about 0.8 mJy has been detected. The minimum flux density of the catalog, 2.5 mJy, is comparable to the flux-density linit of the NVSS catalog. The catalog is more than 80% complete for sources with flux densities >3 mJy.     

Behavior of uranium under conditions of interaction of rocks and ores with subsurface water

The behavior of uranium during interaction of subsurface water with crystalline rocks and uranium ores is considered in connection with the problem of safe underground insulation of spent nuclear fuel (SNF). Since subsurface water interacts with crystalline rocks formed at a high temperature, the mineral composition of these rocks and uranium species therein are thermodynamically unstable. Therefore, reactions directed toward the establishment of equilibrium proceed in the water-rock system. At great depths that are characterized by hindered water exchange, where subsurface water acquires near-neutral and reducing properties, the interaction is extremely sluggish and is expressed in the formation of micro- and nanoparticles of secondary minerals. Under such conditions, the slow diffusion redistribution of uranium with enrichment in absorbed forms relative to all other uranium species is realized as well. The products of secondary alteration of Fe- and Ti-bearing minerals serve as the main sorbents of uranium. The rate of alteration of minerals and conversion of uranium species into absorbed forms is slow, and the results of these processes are insignificant, so that the rocks and uranium species therein may be regarded as unaltered. Under reducing conditions, subsurface water is always saturated with uranium. Whether water interacts with rock or uranium ore, the equilibrium uranium concentration in water is only ≤10^?8 mol/l. Uraninite ore under such conditions always remains stable irrespective of its age. The stability conditions of uranium ore are quite suitable for safe insulation of SNF, which consists of 95% uraninite (UO₂) and is a confinement matrix for all other radionuclides. The disposal of SNF in massifs of crystalline rocks at depths below 500 m, where reducing conditions are predominant, is a reliable guarantee of high SNF stability. Under oxidizing conditions of the upper hydrodynamic zone, the rate of interaction of rocks with subsurface water increases by orders of magnitude and subsurface water is commonly undersaturated with uranium. Uranium absorbed by secondary minerals, particularly by iron hydroxides and leucoxene, is its single stable species under oxidizing conditions. The impact of oxygen-bearing water leads to destruction of uranium ore. This process is realized simultaneously at different hypsometric levels even if the permeability of the medium is variable in both the lateral and vertical directions. As a result, intervals containing uranyl minerals and relics of primary uranium ore are combined in ore-bearing zones with intervals of completely dissolved uranium minerals. A wide halo of elevated uranium contents caused by sorption is always retained at the location of uranium ore entirely destroyed by weathering. Uranium ore commonly finds itself in the aeration zone due to technogenic subsidence of the groundwater table caused by open-pit mining or pumping out of water from underground mines. The capillary and film waters that interact with rocks and ores in this zone are supplemented by free water filtering along fractures when rain falls or snow is thawing. The interaction of uranium ore with capillary water results in oxidation of uraninite, accompanied by loosening of the mineral surface, formation of microfractures, and an increase in solubility with enrichment of capillary water in uranium up to 10^?4 mol/l. Secondary U(VI) minerals, first of all, uranyl hydroxides and silicates, replace uraninite, and uranium undergoes local diffusion redistribution with its sorption by secondary minerals of host rocks. The influx of free water facilitates the complete dissolution of primary and secondary uranium minerals, the removal of uranium at the sites of groundwater discharge, and its redeposition under reducing conditions at a greater depth. It is evident that the conditions of the upper hydrodynamic zone and the aeration zone are unfit for long-term insulation of SNF and high-level wastes because, after the failure of containers, the leakage of radionuclides into the environment becomes inevitable.     

Formation of the composition and quality of carbonate mineral water of the Elburgan water bearing complex (Essentuki Town)

The problems of underground water formation in the Elburgan water bearing stratum in conditions close to a marine sedimentation basin are considered in this article. As well, we consider variations in water composition under the influence of mixing with ground waters during water pumping for commercial purposes, and the deterioration of water quality caused by a decrease in the mineralization of mixture, considered with respect to the degree of mineralization accepted for waters used for medical purposes.     

Geochemistry and age of metamorphic rocks of the Khavyven Highland,eastern Kamchatka

The metamorphic rocks of the Khavyven Highland in eastern Kamchatka were determined to comprise two complexes of metavolcanic rocks that have different ages and are associated with subordinate amounts of metasediments. The complex composing the lower part of the visible vertical section of the highland is dominated by leucocratic amphibole-mica (±garnet) and epidote-mica (±garnet) crystalline schists, whose protoliths were andesites and dacites and their high-K varieties of the island-arc calc-alkaline series. The other complex, composing the upper part of the vertical section, consists of spilitized basaltoids transformed into epidote-amphibole and phengite-epidote-amphibole green schists, which form (together with quartzites, serpentinized peridotites, serpentinites, and gabbroids) a sea-margin ophiolitic association. The high LILE concentrations, high K/La, Ba/Th, Th/Ta, and La/Nb ratios, deep Ta-Nb minima, and low (La/Yb)_N and high ⁸⁷Sr/⁸⁶Sr ratios of the crystalline schists of the lower unit are demonstrated to testify to their subduction nature and suggest that their protolithic volcanics were produced in the suprasubduction environment of the Ozernoi-Valaginskii (Achaivayam-Valaginskii) island volcanic arc of Campanian-Paleogene age. The green schists of the upper unit show features of depleted MOR tholeiitic melts and subduction melts, which cause the deep Ta-Nb minima, and low K/La and ⁸⁷Sr/⁸⁶Sr ratios suggesting that the green schists were formed in a marginal basin in front of the Ozernoi-Valaginskaya island arc. Recently obtained K-Ar ages in the Khavyven Highland vary from 32.4 to 39.3 Ma and indicate that the metamorphism of the protolithic rocks occurred in the Eocene under the effect of collision and accretion processes of the arc complexes of the Ozernoi-Valaginskii and Kronotskii island arcs with the Asian continent and the closure of forearc oceanic basins in front of them. The modern position of the collision suture that marks the fossil subduction zone of the Ozernoi-Valaginskii arc and is spatially restricted to the buried Khavyven uplift in the Central Kamchatka Depression, which is characterized by well-pronounced linear gravity anomalies.     

Corundum-group minerals in rocks of the Khibiny alkaline pluton,Kola Peninsula

Five minerals of the corundum group have been identified in the Khibiny pluton with certainty. Corundum proper and karelianite occur only in hornfels after volcanic and sedimentary rocks. Xenoliths of hornfels mark the ring faults that bound foidalite within the field of foyaite. Hematite occurs in hydrothermally altered nepheline syenite and crosscutting hydrothermal veins related to the ring faults. Minerals of the ilmenite-pyrophanite series are present in all rocks of the pluton, including veins. Accessory ilmenite in foyaite varies from the manganese variety and pyrophanite in the inner and outer parts of the pluton to manganese-free ilmenite in zone of the Main Ring Fault. In xenoliths of volcanic rocks and alkaline ultramafic rocks, ilmenite is enriched in magnesium. The zoning in distribution of the above-mentioned minerals and the character of variation in their compositions from margins of the pluton to its center are consistent with the petrochemical zoning formed as a result of foyaite alteration of near ring faults.     

Changing poverty distribution in Bolivia: the role of rural–urban migration and urban services

Bolivia is a country with high levels of poverty and inequality among its peoples and regions. For the nation and its urban and rural areas, trends in the social and spatial distribution of poverty (and extreme poverty) are identified from 1976 to 2003 using UBN data with minor support where appropriate from poverty lines. The main survey between 1992 and 2001 uses composite and selected UBN to track detailed poverty change for the country’s nine departments, its ten largest cities and a selection of other smaller urban and rural municipalities. Because of rising background increases in population in the various surveyed administrative units, many instances of relative reductions in poverty are accompanied by rising absolute increases. Marked spatial variations in poverty and development in the country over the last several decades are identified as the main driver for the country’s quickening pace of rural–urban migration. As a result, the paper concludes by assessing two different but closely related views. One investigation tests the notion that because more poor people have been living in Bolivia’s cities than in its rural areas since the mid to late 1990s, rapid rural–urban migration has simply shifted the locus of poverty from the countryside to the cities in a process called, the ‘urbanisation of poverty.’ A second, more challenging, investigation assesses the view that the flow of poor rural people to the better serviced urban areas of Bolivia has actually acted to alleviate national poverty levels.     

Urban effect on the formation of the Moskva River environmental state (historical aspect)

Results of long-term monitoring of water quality parameters of the Moskva River section within the limits of the city are generalized. The dynamics in quality parameters of the water entering the city wastewater treatment plants, purified effluents of the treatment plants, and river water is analyzed. A relationship between the concentration of organic matter in the river water at the exit from the city and WWTP capacity is demonstrated. Periods of unfavorable environmental state of the river in terms of oxygen regime are singled out based on oxygen regime dynamics. Variations in the river self-purification process are shown. It is stated that purified effluents of the WWTP are a component of the city hydrological system.     

Expected loss‐based alarm threshold set for earthquake early warning systems

Earthquake early warning systems (EEWS) seem to have potential as tools for real‐time seismic risk management and mitigation. In fact, although the evacuation of buildings requires warning time not available in many urbanized areas threatened by seismic hazard, they may still be used for the real‐time protection of critical facilities using automatic systems in order to reduce the losses subsequent to a catastrophic event. This is possible due to the real‐time seismology, which consists of methods and procedures for the rapid estimation of earthquake features, as magnitude and location, based on measurements made on the first seconds of the P‐waves. An earthquake engineering application of earthquake early warning (EEW) may be intended as a system able to issue the alarm, if some recorded parameter exceeds a given threshold, to activate risk mitigation actions before the quake strikes at a site of interest. Feasibility analysis and design of such EEWS require the assessment of the expected loss reduction due to the security action and set of the alarm threshold. In this paper a procedure to carry out these tasks in the performance‐based earthquake engineering probabilistic framework is proposed. A merely illustrative example refers to a simple structure assumed to be a classroom. Structural damage and non‐structural collapses are considered; the security action is to shelter occupants below the desks. The cost due to a false alarm is assumed to be related to the interruption of didactic activities. Results show how the comparison of the expected losses, for the alarm‐issuance and non‐issuance cases, allows setting the alarm threshold on a quantitative and consistent basis, and how it may be a tool for the design of engineering applications of EEW. Copyright © 2007 John Wiley & Sons, Ltd.