Radiative properties of stellar plasmas and open challenges

The lifetime of solar-like stars, the envelope structure of more massive stars, and stellar acoustic frequencies largely depend on the radiative properties of the stellar plasma. Up to now, these complex quantities have been estimated only theoretically. The development of the powerful tools of helio- and astero- seismology has made it possible to gain insights on the interiors of stars. Consequently, increased emphasis is now placed on knowledge of the monochromatic opacity coefficients. Here we review how these radiative properties play a role, and where they are most important. We then concentrate specifically on the envelopes of ?? Cephei variable stars. We discuss the dispersion of eight different theoretical estimates of the monochromatic opacity spectrum and the challenges we need to face to check these calculations experimentally.     

Outstanding Issues for Post-Main Sequence Evolution:

We review the question of the empirical and theoretical instabilityregions in the HR diagram for evolved, compact stars. These include thethree families of pulsating white dwarfs (g-mode pulsators excitedthrough mechanisms associated with partial ionization and convection inthe stellar envelope), the pulsating subdwarf B stars (p-mode variablesexcited through a classic kappa mechanism associated with the radiativelevitation of iron in the stellar envelope), and the `Betsy stars',the brand new class of long-period, g-mode pulsators of the subdwarf Btype discovered recently.     

Experimental sorption of Ni, Cs and Ln onto a montmorillonite up to 150°C

The effect of temperature on the sorption of cations onto a dioctahedral smectite was investigated by running batch experiments at 25, 40, 80 and 150°C. We measured the distribution coefficient (Kd) of Cs⁺, Ni²⁺ and 14 lanthanides (Ln³⁺) between solutions and the montmorillonite fraction of the MX80 bentonite at various pH and ionic strengths. Up to 80°C we used a conventional experimental protocol derived from Coppin et al. (2002). At 150°C, the experiments were conducted in a PTFE reactor equipped with an internal filter allowing the sampling of clear aliquots of solution.The results show a weak but measurable influence of the temperature on the elements sorption. Kd’s for Ni²⁺ and Ln³⁺ increase by a factor 2 to 5 whereas temperature raises from 25 to 150°C. This effect seems higher at high ionic strength. The estimated apparent endothermic sorption enthalpies are 33 ± 10 kJ.mol⁻¹ and 39 ± 15 kJ.mol⁻¹ for Ni²⁺ and Eu³⁺, respectively. On the other hand, the temperature effect on Cs⁺ sorption is only evidenced at low ionic strength and under neutral conditions where the Kd decreases by a factor 3 between 25 and 150°C. Apparent exothermic sorption enthalpy for Cs⁺ on the montmorillonite is −19 ± 5 kJ.mol⁻¹.Experiments conducted at the four temperatures with the coexistence of all of the cations in the reacting solution (100 ppb of each element in the starting solution) or only one of them, produced similar values of Kd. This suggests the absence of competition between the sorbed cations, and consequently a low degree of saturation of the available sites. A fractionation of the lanthanides spectrum is also observed at high pH and high ionic strength whatever the temperature.The conclusion of this study is that the temperature dependence on sorption reflects, as the fractionation of REE or the pH and ionic strength effects, the chemical process which controls the overall reaction. In the case of an exchange dominated reaction (low pH and low ionic strength), the temperature effect is negligible. In the case of surface complexation (high pH and high ionic strength), the observed increase of Kd with temperature reflects either an increase of the sorption equilibrium constant with temperature or an endothermic property for reactions describing the montmorillonite surface chemistry.     

Technosols made with various urban wastes showed contrasted performance for tree development during a 3-year experiment

Vegetation in urban areas is generally living in a stress-inducing environment. Sustaining good soil quality is crucial to improve tree development and heath in such (artificial) environment. This study investigates the dynamics of the physico-chemical properties of Technosol, and compares tree development performances in various waste mixtures. A 3-year experiment was conducted with Acer platanoïdes L. grown in three distinct constructed soils, in three replicates, in 0.480-m³ lysimeters in Angers (France). Four combinations of artefacts were studied either as “growing material” (GM) or “structural material” (SM). Three different SMs were used: (1) a mixture of fine mineral material, demolition rubble and green waste (SM-DR/GW), (2) a mixture of fine mineral material, track ballast and sewage sludge (SM-TB/SS), and (3) the SM currently used by Angers city for green space settlements (SM-CT). Waste characteristics and mixing proportions both affected tree development. Physical properties were not a limiting factor for tree development, despite a relatively low soil water reservoir due to high stone content. Moreover, the chemical properties of the materials, more particularly low water pH and CEC, led to poor tree development in SM-CT, whereas the other two SMs did not affect tree development. SM-TB/SS was the most suitable constructed soil after 3 years because it exhibited satisfactory soil nutrient contents that promoted the best tree crown quality. Waste mixtures can sustain soil functions for tree development. As for urban street tree pits that are 2–8 m³ in volume, soil water, and nutrient autonomy should satisfactorily sustain tree development.     

Symplectic Mapping for Satellites and Space Debris Including Nongravitational Forces

The paper presents an efficient algorithm for the study of satellite and space debris orbits on long time intervals. The averaged equations of motion are integrated by means of the implicit midpoint method. This approach is known as a symplectic mapping technique. The perturbing forces included in the mapping are: the geopotential, the atmospheric drag, lunisolar perturbations and the direct radiation pressure (without shadow effects). The influence of the atmosphere is approximated by simple methods for the estimation of integrals. The described mapping is valid for the wide range of orbits including the resonant and the eccentric ones; it can be helpful in practical and theoretical problems. The lifetime of GPS transfer orbits is discussed as an exemplary application.     

General database for ground water site information

In most cases, analysis and modeling of flow and transport dynamics in ground water systems require long-term, high-quality, and multisource data sets. This paper discusses the structure of a multisite database (the H+ database) developed within the scope of the ERO program (French Environmental Research Observatory, http://www.ore.fr). The database provides an interface between field experimentalists and modelers, which can be used on a daily basis. The database structure enables the storage of a large number of data and data types collected from a given site or multiple-site network. The database is well suited to the integration, backup, and retrieval of data for flow and transport modeling in heterogeneous aquifers. It relies on the definition of standards and uses a templated structure, such that any type of geolocalized data obtained from wells, hydrological stations, and meteorological stations can be handled. New types of platforms other than wells, hydrological stations, and meteorological stations, and new types of experiments and/or parameters could easily be added without modifying the database structure. Thus, we propose that the database structure could be used as a template for designing databases for complex sites. An example application is the H+ database, which gathers data collected from a network of hydrogeological sites associated with the French Environmental Research Observatory.     

A report card and quality indicators for the Seine estuary: from scientific approach to operational tool

The scientific teams from the interdisciplinary Seine-Aval (SA) research program and the SA's operational pole, GIPSA (Groupement d'Intérêt Public Seine-Aval) have worked together to create a report card designed to help the Estuary Council (Conseil de l'Estuaire) revitalize its original functions: maintaining functional links between the various estuarine ecosystems, comprehending and managing the estuary's natural habitats and biological populations, and monitoring and improving the physical-chemical quality of the estuarine waters. The report card will be able to synthesize the information obtained from several system performance variables and available operational indicators. This approach, intended to guide the estuary managers, is the oeuvre of several scientific teams; it is particularly important in the context of the Water Framework Directive because it facilitates the elaboration of a group of relevant indicators, which can then be used as operational tools. A report card will provide decision-makers (e.g., political authorities; national, regional and local institutions and industries) with the key indicators for evaluating the system and predicting changes in terms of selected objectives, such as the preservation and restoration of the estuary's environmental functionalities. The final objective of the research is to choose among the available indicators to approximate potential ecological risks. Integrating the socio-economical data will perhaps lead to setting risk acceptability thresholds for the different uses of the Seine estuary. In the end, collaboration between the scientists, the managers, and the GIPSA operational pole will be essential to produce a viable report card about the environmental status of the Seine estuary. To illustrate the research now under way, this article presents the results for three actions undertaken, concerning: (i) physical indicators (i.e., an inventory of the estuary first as a whole, and then section by section); (ii) benthic indicators (i.e., seven indices which show a moderate EcoQ for the lower part of the estuary); and (iii) a eutrophication indicator (i.e., an indicator for coastal eutrophication potential (ICEP), which helps to limit the nutrient fluxes (N or P) that exceed the silica flux delivered by the Seine network, based on the Redfield ratios for algal propagation).     

How can a few streamflow measurements help to predict daily hydrographs at almost ungauged sites?

Abstract

Available data from nearby gauging stations can provide a great source of hydrometric information that is potentially transferable to an ungauged site. Furthermore, streamflow measurements may even be available for the ungauged site. This paper explores the potential of four distance-based regionalization methods to simulate daily hydrographs at almost ungauged pollution-control sites. Two methods use only the hydrological information provided by neighbouring catchments; the other two are new regionalization methods parameterized with a limited number of streamflow data available at the site of interest. Based on a network of 149 streamgauges and 21 pollution-control sites located in the Upper Rhine-Meuse area, the comparative assessment demonstrates the benefit of making available point streamflow measurements at the location of interest for improving quantitative streamflow prediction. The advantage is moderate for the prediction of flow types (stormflow, recession flow, baseflow) and pulse shape (duration of rising limb and falling limb).

Editor Z.W. Kundzewicz; Associate editor A. Viglione     

New models for heater wells in subsurface simulations, with application to the in situ upgrading of oil shale

Downhole electrical heating can be used to achieve the high temperatures required for in situ upgrading of oil shale or oil sands. Heater-well models are needed if this process is to be simulated accurately. The traditional Peaceman approach used for fluid injection and production wells may not be applicable because it does not capture transient effects, which can be important in downhole heater models. Standard models also neglect the effects of heterogeneity and temperature dependence in the rock properties. Here, we develop two new models for representing heater wells in reservoir simulators. The first model is applicable for homogeneous systems with properties that are not temperature dependent. For such cases, we develop a semi-analytical procedure based on Green’s functions to construct time-dependent heater-well indexes and heater-block thermal transmissibilities. For the general case, which can include both fine-scale heterogeneity and nonlinearity due to the temperature dependence of rock properties, we present a numerical procedure for constructing the heater-well model. This technique is essentially a near-well upscaling method and requires a local fine-scale solution in the near-well region. The boundary conditions are determined using a local-global treatment. The accuracy of the new heater-well models is demonstrated through comparison to reference solutions for example problems. The approach is then applied for the coarse-scale modeling of the in situ upgrading of oil shale, which entails a thermal-compositional simulation with chemical reactions. The model is shown to provide an accurate and efficient solution for this challenging problem.     

The Key Tuffite,Matagami Camp,Abitibi Greenstone Belt,Canada: petrogenesis and implications for VMS formation and exploration

The Key Tuffite is a stratigraphic marker unit for most of the zinc-rich volcanogenic massive sulfide deposits of the Matagami Camp in the Abitibi Greenstone Belt. This 2- to 6-m-thick unit was previously interpreted as a mixture of ash fall (andesitic to rhyolitic tuffaceous components) and volcanogenic massive sulfide (VMS)-related chemical seafloor precipitate (exhalative component). Previous attempts to develop geochemical exploration vectoring tools using metal content within the Key Tuffite were mostly inconclusive due to the complex nature of the Key Tuffite unit and a poor understanding of its composition, origin and relationship with the VMS-forming hydrothermal systems. Detailed mapping and thorough lithogeochemistry of the Key Tuffite in the vicinity of the Perseverance and Bracemac-McLeod deposits indicate that the Key Tuffite is a homogeneous calc-alkaline, andesitic tuff that was deposited before the VMS deposits were formed. The unit is mostly devoid of exhalative component, but it is strongly hydrothermally altered close to orebodies. This is characterized by a strong proximal chloritization and a distal sericitization, which grades laterally into the unaltered Key Tuffite. Neither the Key Tuffite nor the ore was formed by seafloor exhalative processes for the two studied deposits. This probably explains why previously proposed exploration models based on metal scavenging proved unsuccessful and suggests that a re-evaluation of the exhalative model should be done at the scale of the mining camp. However, as shown in this study, hydrothermal alteration can be used to vector towards ore along the Key Tuffite.