Sediment oxygen consumption and benthic nutrient fluxes on the Louisiana continental shelf: A methodological comparison

There has been considerable discussion but little experimental evidence regarding the comparability of in-situ and remote (shipboard or laboratory) incubations for the determination of sediment oxygen consumption and benthic nutrient flux rates. This paper presents the results of such a comparison, using in situ chamber and shipboard chemostatic systems, for a shallow station on the Louisiana, continental shelf during April 1992. Results indicated no methodological differences between rates of sediment oxygen consumption and nutrient flux (NH₄ ⁺, NO₅ ^?, NO₂ ^?, PO₄ ^3?, and SiO₂/Si(OH)₂) that could be attributed to the removal of cores from shelf sediments. This conclusion implies that subcoring from box cores is no more destructive of sediment structure and salient environmental characteristics than chamber emplacement. Differences between the methods occurred when ambient oxygen concentrations were low (<2 ml l^?1). These differences were caused by initial reaeration of bottom water in the shipboard system and reflect the sensitivity of heterotrophic metabolism, dissolution kinetics, and diffusive fluxes to low oxygen concentrations. The differences in exchange rates observed in this study reiterate the importance in maintaining ambient conditions in the experimental apparatus. The results of this study corroborate the small body of, data that addresses this issue and extends methodological similarities to include nutrient exchanges. Given the comparability of rates, use of remote chemostatic systems is more advantageous for work in shelf environments than in-situ batch methods due to increased statistical rigor, logistical convenience, and the ability to minimize changes in experimental conditions during incubations.     

Pacific Walker Circulation variability in coupled and uncoupled climate models

There is still considerable uncertainty concerning twentieth century trends in the Pacific Walker Circulation (PWC). In this paper, observational datasets, coupled (CMIP5) and uncoupled (AGCM) model simulations, and additional numerical sensitivity experiments are analyzed to investigate twentieth century changes in the PWC and their physical mechanisms. The PWC weakens over the century in the CMIP5 simulations, but strengthens in the AGCM simulations and also in the observational twentieth century reanalysis (20CR) dataset. It is argued that the weakening in the CMIP5 simulations is not a consequence of a reduced global convective mass flux expected from simple considerations of the global hydrological response to global warming, but is rather due to a weakening of the zonal equatorial Pacific sea surface temperature (SST) gradient. Further clarification is provided by additional uncoupled atmospheric general circulation model simulations in which the ENSO-unrelated and ENSO-related portions of the observed SST changes are prescribed as lower boundary conditions. Both sets of SST forcing fields have a global warming trend, and both sets of simulations produce a weakening of the global convective mass flux. However, consistent with the strong role of the zonal SST gradient, the PWC strengthens in the simulations with the ENSO-unrelated SST forcing, which has a strengthening zonal SST gradient, despite the weakening of the global convective mass flux. Overall, our results suggest that the PWC strengthened during twentieth century global warming, but also that this strengthening was partly masked by a weakening trend associated with ENSO-related PWC variability.     

Nutrient Loading and Transformations in the Columbia River Estuary Determined by High-Resolution In Situ Sensors

The Columbia River estuary is characterized by relatively large tidal currents and water residence times of a few days or less. These and other environmental conditions tend to suppress water column productivity and favor the export of riverborne nutrients to the coastal ocean. However, hotspots of biological activity may allow for significant nutrient transformation and removal within the estuary, but these processes have previously been difficult to quantify due to the challenges of obtaining measurements at appropriate frequency and duration. In this study, nutrient biogeochemical dynamics within the salt-influenced region of the estuary were quantified using high-resolution in situ observations of nutrients and physical water properties. During 2010, three autonomous nutrient sensors (Satlantic SUNA, SubChem Systems Inc. APNA, WET Labs Cycle-PO4) that together measured nitrate?+?nitrite, orthophosphate, ammonium, silicic acid, and nitrite were deployed on fixed observatory platforms. Hourly measurements captured tidal fluctuations and permitted an analysis of river and ocean end-member mixing. The results suggested that during summer, the lower estuary released high concentrations of ammonium and phosphate despite low concentrations in the river and coastal ocean. This was likely a result of organic matter accumulation and remineralization in the estuarine turbidity maximum and the lateral bays adjacent to the main channel.     

Rare earth element evidence for differentiation of McMurdo volcanics,Ross Island,Antarctica

Eighteen samples of the McMurdo volcanics on Ross Island, Antarctica consisting of basanitoid, trachybasalt and phonolite have been analyzed for rare earth elements (REE) in order to determine the details of differentiation using quantitative trace element modeling. The basanitoids have REE patterns similar to those for alkali basalts or nephelinites from ocean islands. Since there is no correlation between REE and silica contents among five basanitoids, some of the variability in the REE contents must be related to the extent of partial melting, variation in the residual mineralogies of the mantle during melting, or to inhomogeneities in the REE composition of the mantle.In order to explain the data, more than one differentiation sequence is necessary. In each case a basanitoid melt is the parent which differentiates to trachybasalt upon separation of olivine, clinopyroxene, spinel, ±kaersutite±plagioclase±apatite. If clinopyroxene, kaersutite, anorthoclase, plagioclase and apatite separate from a trachybasalt melt, a mafic phonolite results.If, however, no kaersutite is involved, an anorthoclase phonolite results. A distinct type of mafic phonolite results if kaersutite is one of the minerals that separates from the anorthoclase phonolite. If the anorthoclase phonolite precipitates plagioclase and anorthoclase and if the melt reacts with plagioclase-rich continental rocks, a trachyte results.Formerly spelled: Shine Soon Sun     

Time relationships between volcanism–plutonism–alteration–mineralization in Cu-stratabound ore deposits from the Michilla mining district,northern Chile: a <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronological approach

The Michilla mining district comprises one of the most important stratabound and breccia-style copper deposits of the Coastal Cordillera of northern Chile, hosted by the Middle Jurassic volcanic rocks of the La Negra Formation. ⁴⁰Ar/³⁹Ar analyses carried out on igneous and alteration minerals from volcanic and plutonic rocks in the district allow a chronological sequence of several magmatic and alteration events of the district to be established. The first event was the extrusion of a thick lava series of the La Negra Formation, dated at 159.9 ± 1.0 Ma (2σ) from the upper part of the series. A contemporaneous intrusion is dated at 159.6 ± 1.1 Ma, and later intrusive events are dated at 145.5 ± 2.8 and 137.4 ± 1.1 Ma, respectively. Analyzed alteration minerals such as adularia, sericite, and actinolite apparently give valid ⁴⁰Ar/³⁹Ar plateau and miniplateau ages. They indicate the occurrence of several alteration events at ca. 160–163, 154–157, 143–148, and 135–137 Ma. The first alteration event, being partly contemporaneous with volcanic and plutonic rocks, was probably produced in a high thermal gradient environment. The later events may be related either to a regional low-grade hydrothermal alteration/metamorphism process or to plutonic intrusions. The Cu mineralization of the Michilla district is robustly bracketed between 163.6 ± 1.9 and 137.4 ± 1.1 Ma, corresponding to dating of actinolite coexisting with early-stage chalcocite and a postmineralization barren dyke, respectively. More precisely, the association of small intrusives (a dated stock from the Michilla district) with Cu mineralization in the region strongly suggests that the main Michilla ore deposit is related to a magmatic/hydrothermal event that occurred between 157.4 ± 3.6 and 163.5 ± 1.9 Ma, contemporaneous or shortly after the extrusion of the volcanic sequence. This age is in agreement with the Re–Os age of 159 ± 16 Ma obtained from the mineralization itself (Tristá-Aguilera et al., Miner Depos, 41:99–105,2006).     

Explosive rhyolite tuya formation: classic examples from Kerlingarfjöll,Iceland

Rhyolite eruptions in Iceland mostly take place at long-lived central volcanoes, examples of which are found associated with each of the present-day rift-zone ice caps. Subglacial eruptions at Kerlingarfjöll central volcano produced rhyolite tuyas that are notable for their exposures of early-erupted pyroclastic material. Observations from a number of these edifices are synthesised into a general model for explosive rhyolite tuya formation. Eruptions begin with violent phreatomagmatic explosions that generate massive tuff (mT), but the influence of water quickly declines, leading to the formation of massive lapilli-tuffs (mLT) containing magmatically-fragmented vesicular pumice and ash. These are deposited rapidly near the vent, probably by moist pyroclastic density currents, confined by ice but not within a meltwater lake. The explosive-effusive transition is controlled by the ascent rate and gas content of the magma. An unusual obsidian-rich massive lapilli-tuff lithofacies (omLT) is identified and interpreted as pyroclastic material that was intruded into gas-fluidised deposits at the explosive-effusive transition. The effusive phase of eruption involves the emplacement of intrusions and lava caps. Intrusions of lava into the early-erupted phreatomagmatic deposits are characterised by peperitic margins and the formation of hyaloclastite. Intrusions into stratigraphically higher levels of the pyroclastic material show more limited interaction with the host tephra and have microcrystalline cores. Large lava bodies with columnar-jointed margins cap the tuyas and have intrusive basal contacts with the tephras. The main influence of the ice is to confine the rhyolite eruptive products to immediately above the vent region. This is in contrast to subglacial basaltic tuya-forming eruptions, which are characterised by the formation of meltwater lakes, phreatomagmatic fragmentation and subaqueous deposition. The lack of meltwater storage may reduce the potential for large jökulhlaups.     

The influence of rock structures on coast-line and cliff development around Tintagel,North Cornwall

The paper deals with the morphology of the stretch of coast between Boscastle and the Treligga Cliffs in North Cornwall. The prevalent cliff type is slope-over-wall, either hog's-back or bevelled as defined by Miss Arber (1949). Flat-topped cliffs are less common. It is considered that geological structures—bedding, jointing, faulting and, to a lesser extent, rock-type—have not only had considerable influence on the shape of the cliffs, but have also guided the marine attack on the coast. The evolution of most of the coast features, when seen in plan or profile, has been controlled by the local geological structure. The southern stretch of the coast is sub-parallel to seaward-dipping normal faults which have been stripped of their hanging-walls. Such a cliff line is dominantly a faultline scarp which has suffered slight retrogression.     

Collisional processes in stellar systems

The theory of collisional relaxation in stellar systems is discussed in terms of an expansion in powers of 1/N, the inverse of the total number of stars. The results are expressed in terms of the concept of gravitational polarization.