MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Web Geoservices and Ancient Cadastral Maps: The Web C.A.R.T.E. Project

In the State Archive of Como, Northern Italy, about 15,000 historical maps belonging to different national cadastral productions are preserved. The Web C.A.R.T.E. project was started to enhance the accessibility of this valuable cartographic heritage using FOSS (Free and Open Source Software) technologies. The system, which implements specific web geoservices for cataloguing and visualization, should assist the State Archive of Como in the digital management of its cartographic resources and related information. After the high‐resolution digitization step, maps undergo a georeferencing operation. A special statistical procedure for choosing the best mathematical model was developed, verifying also strengths and weaknesses of georeferencing with a common free and Open Source GIS. Next, metadata consistent with current Italian standards were added to the georeferenced maps using an ad hoc localized version of GeoNetwork Opensource (recently provided as the official Italian version of the software). A dedicated WebGIS system was built for publishing the georeferenced cadastral maps. This system is capable of navigating large raster data in a georeferenced framework and easily retrieving their metadata. The WebGIS system for the State Archive of Como is an important contribution for the preservation of the original historical paper maps and also a great modernization and simplification of the end user's access to this archive.     

New algorithms for shoreline monitoring from coastal video systems

Video systems have become widely used all around the world in coastal monitoring strategies, allowing both high temporal and spatial sampling frequency, with low logistic and costs efforts. The present paper deals with a new tool for coastal images processing, aimed at the automatic shoreline detection and data analysis. The tool is composed by a shoreline detection routine implemented in a web-application, addressed at images processing (i.e. shoreline extraction and geo-rectification), data analysis and sharing results about beach actual state and shore evolution in quasi-real time. The Shoreline Detection Model (SDM) is based on a new algorithm, implementing image-processing procedures, which allows extracting the sea/land boundary from automatic segmented Timex images. The SDM calibration and validation has been performed on different coastal images derived from a video monitoring system installed at Alimini (Lecce, IT) in 2005, by comparing automatic shoreline contours with the manual detected ones. Moreover, in December 2015, new video monitoring systems were installed in South Italy (Porto Cesareo and Torre Canne, Apulia region), at sandy beaches affected by erosion phenomena. The application of the SDM on images recorded by the new systems has allowed testing the model feasibility at sites characterized by different morphological features and geographical exposition. The present describes in detail the SDM algorithm and the image processing procedures used. The results of the model calibration and validation performed at Alimini and the tests performed at Porto Cesareo on first images are reported.     

Prof. & Ph. D Zhu Qing

Geo-spatial Information Science -     

Using GB-SAR technique to monitor slow moving landslide

A Ground-Based SAR (GB-SAR) interferometer was employed to measure the surface displacements of a landslide occurring in the Carnian Alps, north-eastern Italy, which has affected a national road and seriously damaged a road tunnel still under construction. Moreover, since the landslide is located on the left bank of the Tagliamento River Valley, it is feared that this mass movement might dam the river, creating a basin that would increase natural hazard for the valley inhabitants. The data collected from December 2002 to July 2005 by a conventional monitoring system, consisting of a GPS network and boreholes equipped with inclinometric tubes, showed that the landslide was moving at a quasi-constant rate of about 3 cm per year. Due to the slow deformation rate of the landslide, a recently developed GB-SAR technique based on the analysis of a restricted ensemble of coherent points was used. Two surveys, each lasting two days, were planned in December 2004 and July 2005, in order to map and measure the surface displacements that occurred over time. The results from the radar were compared with the ones derived from the GPS monitoring network. An agreement was achieved among the data collected, showing the capability of the GB-SAR technique to measure displacements even within a time span of several months between the surveys.     

Continuous in situ measurements of volcanic gases with a diode-laser-based spectrometer: CO<Subscript>2</Subscript> and H<Subscript>2</Subscript>O concentration and soil degassing at Vulcano (Aeolian islands: Italy)

We report on a continuous-measurement campaign carried out in Vulcano (Aeolian islands, Sicily), devoted to the simultaneous monitoring of CO₂ and H₂O concentrations. The measurements were performed with an absorption spectrometer based on a semiconductor laser source emitting around a 2-μm wavelength. The emitted radiation was selectively absorbed by two molecular ro-vibrational transitions specific of the investigated species. Data for CO₂ and H₂O concentrations, and CO₂ soil diffusive flux using an accumulation chamber configuration, were collected at several interesting sampling points on the island (Porto Levante beach- PLB, Fossa Grande Crater – FOG- and Valley of Palizzi, PAL). CO₂/H₂O values, measured on the ground, are very similar (around 0.019 (± 0.006)) and comparable to the previous discrete detected values of 0.213 (Fumarole F5-La Fossa crater rim) and 0.012 (Fumarole VFS – Baia Levante beach) obtaid during the 1977–1993 heating phase of the crater fumaroles.     

Nummulitids,lepidocyclinids and Sr-isotope data from the Oligocene of Kutch (western India) with chronostratigraphic and paleobiogeographic evaluations

Due to its intermediate geographical position between the Mediterranean and W Pacific, the Oligocene shallow-marine sequence of Kutch (India) is of key importance in paleobiogeographical interpretations. Larger benthic foraminifera (LBF) are a fundamental link for the correlation between the Mediterranean shallow benthic zones (SBZ) and the W Pacific ‘letter stages’. LBF were re-evaluated by morphometric studies of the internal test from five stratigraphic sections of the Maniyara Fort Formation. Based on their significant affinity to coeval fauna in the Mediterranean, they were assigned to W Tethyan SBZ zones, supported by Sr-isotope stratigraphy. In the Basal Member, traditionally considered as early Rupelian, we identified Nummulites bormidiensis, N. kecskemetii and Heterostegina assilinoides assigning it to the early Chattian SBZ 22B Zone. The Coral Limestone Member, previously considered as late Rupelian, is also assigned to this zone, for the presence of N. bormidiensis, Eulepidina formosoides-dilatata and Nephrolepidina morgani-praemarginata. Its early Chattian age (26.5–29 Ma) is further supported by Sr-isotope data. Miogypsinoides complanatus and Spiroclypeus margaritatus in the Bermoti Member (the top of the formation) document the late Chattian SBZ 23 Zone and the Sr-isotope data (22.5–24 Ma) place it close to the Oligocene–Miocene boundary.