A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

Young runoff fractions control streamwater age and solute concentration dynamics

We introduce a new representation of coupled solute and water age dynamics at the catchment scale, which shows how the contributions of young runoff waters can be directly referenced to observed water quality patterns. The methodology stems from recent trends in hydrologic transport that acknowledge the dynamic nature of streamflow age and explores the use of water age fractions as an alternative to the mean age. The approach uses a travel time‐based transport model to compute the fractions of streamflow that are younger than some thresholds (e.g., younger than a few weeks) and compares them to observed solute concentration patterns. The method is here validated with data from the Hubbard Brook Experimental Forest during spring 2008, where we show that the presence of water younger than roughly 2 weeks, tracked using a hydrologic transport model and deuterium measurements, mimics the variation in dissolved silicon concentrations. Our approach suggests that an age–discharge relationship can be coupled to classic concentration–discharge relationship, to identify the links between transport timescales and solute concentration. Our results highlight that the younger streamflow components can be crucial for determining water quality variations and for characterizing the dominant hydrologic transport dynamics.     

Climate change impacts on wildfires in a Mediterranean environment

We analyse the observed climate-driven changes in summer wildfires and their future evolution in a typical Mediterranean environment (NE Spain). By analysing observed climate and fire data from 1970 to 2007, we estimate the response of fire number (NF) and burned area (BA) to climate trends, disentangling the drivers responsible for long-term and interannual changes by means of a parsimonious Multi Linear Regression model (MLR). In the last forty years, the observed NF trend was negative. Here we show that, if improvements in fire management were not taken into account, the warming climate forcing alone would have led to a positive trend in NF. On the other hand, for BA, higher fuel flammability is counterbalanced by the indirect climate effects on fuel structure (i.e. less favourable conditions for fine-fuel availability and fuel connectivity), leading to a slightly negative trend. Driving the fire model with A1B climate change scenarios based on a set of Regional Climate Models from the ENSEMBLES project indicates that increasing temperatures promote a positive trend in NF if no further improvements in fire management are introduced.     

CO<Subscript>2</Subscript>-driven large mafic explosive eruptions: the Pozzolane Rosse case study from the Colli Albani Volcanic District (Italy)

Generally, the intensity and magnitude of explosive volcanic activity increase in parallel with SiO₂ content. Pyroclastic-flow-forming eruptions in the Colli Albani ultrapotassic volcanic district (Italy) represent the most striking exception on a global scale, with volumes on the order of tens of cubic kilometres and K-foiditic compositions (SiO₂ even <42 wt.%). Here, we reconstruct the pre-eruptive scenario and event dynamics of the ~456 ka Pozzolane Rosse (PR) eruption, the largest mafic explosive event of the Colli Albani district. In particular, we focus on the driving mechanisms for the unusually explosive eruption of a low-viscosity, mafic magma. Geologic, petrographic and geochemical data with mass balance calculations, supported by experimental data for Colli Albani magma compositions, provide evidence for significant ingestion of carbonate wall rocks by the Pozzolane Rosse K-foiditic magma. Moreover, the scattered occurrence of cored bombs in Pozzolane Rosse pyroclastic-flow deposits records carbonate entrainment even at the eruptive time scale, as also tested quantitatively by thermal modelling of magma–carbonate interaction and carbonate assimilation experiments. We suggest that the addition of free CO₂ from decarbonation of country rocks was the major factor controlling magma explosivity. High CO₂ activity in the volatile component, coupled with magma depressurisation, produced extensive leucite crystallisation at short time scales, resulting in a dramatic increase in magma viscosity and volatile pressurisation, which was manifested a change of eruptive dynamics from early effusion to the Pozzolane Rosse's highly explosive eruption climax.     

Searching for inner-Earth objects: a possible ground-based approach

The likely existence of bodies orbiting the Sun with aphelia Q < 0.983 AU has been suggested by numerical simulations of the dynamical evolution of the near-Earth objects (NEOs) population. For obvious reasons, these hypothetical minor bodies are called inner-Earth objects (IEOs). While much progresses has been made in learning more about the Amor, Apollo, and Aten population from surveys optimized for their discovery, no large, systematic, and similar observation projects devoted to the search of IEOs have been started. For their own orbital nature, IEOs can be observed only at small solar elongations (<90°), corresponding to regions of the sky currently neglected by the modern, ongoing surveys. This paper discusses a possible ground-based approach to look for IEOs, providing some useful tricks and the results of simulated surveys devoted to their discovery. It will be shown that such a search promises interesting results, the setup of a dedicated project being highly recommended.     

The ultraviolet absorber on Venus: Amorphous sulfur

The large backscattering cross section of the particles composing the upper clouds on Venus suggests that a small quantity of high refractive index material is present in the clouds. We propose that this material is elemental sulfur and that sulfur also accounts for the absorption of uv-visible radiation at wavelengths outside of the SO₂ absorption bands. A physical-chemical model of the clouds shows that sulfur, with a mass comparable to that of the observed Mode 1 particles, can be produced in oxygen-poor regions of the upper clouds and in rising air columns. Sulfur production from SO₂ can be rapid, which explains the observed correlation between SO₂ and the uv absorber. The sulfur is properly located to be the uv absorber uv absorber since its calculated concentration rapidly increases with depth in the upper clouds, but it is largely absent in the middle and lower clouds. Sulfur nucleation provides a means of generating the observed bimodal particle size distribution in the upper clouds. Chemical modeling shows that the sulfur vapor is rich in short-chain allotropes such as S₃ and S₄. These allotropes have absorption bands centered near 4000 and 5300 Å, respectively. We suggest that the sulfur particles on Venus are largely composed of S₈, but also contain a few percent of S₃ and S₄. Such particles could account for the wavelength dependence of the albedo of Venus and for the solar energy deposition profile in the clouds. These allotropes are metastable and relax to S₈ over periods of hours to days, providing a simple explanation for the relatively short lifetime of the uv absorber.     

A time-dependent extension of the projected normal regression model for longitudinal circular data based on a hidden Markov heterogeneity structure

The modelling of animal movement is an important ecological and environmental issue. It is well-known that animals change their movement patterns over time, according to observable and unobservable factors. To trace the dynamics of behaviors, to identify factors influencing these dynamics and unobserved characteristics driving intra-subjects correlations, we introduce a time-dependent mixed effects projected normal regression model. A set of animal-specific parameters following a hidden Markov chain is introduced to deal with unobserved heterogeneity. For the maximum likelihood estimation of the model parameters, we outline an expectation–maximization algorithm. A large-scale simulation study provides evidence on model behavior. The data analysis approach based on the proposed model is finally illustrated by an application to a dataset, which derives from a population of Talitrus saltator from the beach of Castiglione della Pescaia (Italy).     

Synthetic ANaB(Na x Li1 − x Mg1)CMg5Si8O22(OH)2 (with x = 0.6, 0.2 and 0) P21/m amphiboles at high pressure: a synchrotron infrared study

The high-pressure behavior of three synthetic amphiboles crystallized with space group P2₁/m at room conditions in the system Li₂O–Na₂O–MgO–SiO₂–H₂O has been studied by in situ synchrotron infrared absorption spectroscopy. The amphiboles have compositions ^ANa ^B(Na _x Li_1 − x Mg₁) ^CMg₅ Si₈ O₂₂(OH)₂ with x = 0.6, 0.2 and 0.0, respectively. The high-P experiments up to 32 GPa were carried out on the U2A beamline at Brookhaven National Laboratory (NY, USA) using a diamond anvil cell under non-hydrostatic or quasi-hydrostatic conditions. The two most intense absorption bands in the OH-stretching infrared spectra can be assigned to two non-equivalent O–H dipoles in the P2₁/m structure, bonded to the same local environment ^M1M3Mg₃–OH–^ANa, and pointing toward two differently kinked tetrahedral rings. In all samples these bands progressively merge to give a unique symmetrical absorption with increasing pressure, suggesting a change in symmetry from P2₁/m to C2/m. The pressure at which the transition occurs appears to be linearly correlated to the aggregate B-site dimension. The infrared spectra collected for amphibole ^B(Na_0.2Li_0.8Mg₁) in the frequency range 50 to 1,400 cm⁻¹ also show a series of changes with increasing pressure. The data reported here support the inference of Iezzi et al. (Am Miner 91:479–482, 2006a) regarding a new high-pressure amphibole polymorph.     

Framing the use of geo-information in government: a tale of two perspectives

While commercial virtual globes (e.g. Google Earth) and global scientific cyber-infrastructures (e.g. Digital Earth) are revolutionizing the way we use and produce geo-information, we still lack a rich conceptual understanding of how genuine human actors use geo-information and associated technologies in real work settings. In this paper, we conceptualize the use of geo-information as encompassing people’s actual use practices, the values to which people aspire through geo-information use, and the rules that either legally prescribe or just encourage optimal use. Values, practices and rules can be illuminated from two perspectives (or lenses), the market and the polis, resulting in radically different insights on the use of geo-information as a social phenomenon. We argue that with a polis lens we stand a chance to explain how authentic human actors, groups and communities with different values, interests and motivations use geo-information, and how societal benefits materialize or not as a result. Seen from a polis lens, values are not easily measurable standards of goodness, dominant public management ideas can be the source of technical-organizational change in government while policies can be fruitfully examined as persuasive arguments to target audiences. With a polis lens, we are more likely to understand the emergence of new practices, value contests and global rules underpinning commercial virtual globes and scientific cyber-infrastructures.