Remplacements isomorphiques par synthèses hydrothermales dans les silicates fluores: Topaze et zunyite

The substituted topaz Al₂GeO₄(OH,F)₂, Al₂(Si_xGe_1-x)O₄(OH,F)₂ and Ga₂GeO₄(OH,F)₂, as well as the substituted zunyite Al₁₃Ge₅O₂₀(OH,F)₁₆F₂Cl have been synthetised. The unit-cell parameters of these artificial minerals, isomorphs of natural compounds, have been determined; the corresponding lists of d_hkl are given. The study by I.R. spectroscopy of these compounds with a total or a partial replacement of Si by Ge in the same way as Ga-Ge topaz suggests the assignment of certain absorption bands to characteristic structural groups. The thermal decomposition of AlSi and AlGe topaz into mullite has been studied.     

Synthese et etude morphologique,radiocristallographique et spectrometrique I.R. de la wadeite K2 ZrSi3 O9; domaine de formation; remplacements isomorphiques; application a la geochimie du zirconium

The first synthesis of wadeite, K₂ZrSi₃O₉, was realised by the authors in 1970 using a hydrothermal technique. These new data were the basis for further research works about the formation of this mineral by way of dry and hydrothermal synthesis, making use of various potassic compounds. The conditions for the formation of wadeite were explained as a function of the chemical environment. The pressure—temperature range of formation was investigated from 100 to 900°C and 100 to 2000 bar. The morphology of the wadeite crystals that were obtained is discussed. Starting from wadeite structure, various isomorphic substitutions were determined (Zr/Hf; K/Rb, Cs; Si/Ge); their study resulted in an interesting diagram of crystallographic parameters as a function of the ionic radius of the substituted alkaline elements: cryst. param. = f(R⁺_{alk. element}); the bands are linear. The infra-red investigations enabled us to establish the spectrum of (Si₃O₉)^6? and (Ge₃O₉)^6? in wadeite structure as well as the substitutions caused by alkalis and transition metals. Finally a comparative experimental investigation of the ZrSiO₄-K₂ZrSi₃O₉-K₂ZrSi₆O₁₅ system brought to light new data regarding the geochemical behaviour of zirconium in igneous rocks.     

A physical model of Titan's aerosols

Microphysical simulations of Titan's stratospheric haze show that aerosol microphysics is linked to organized dynamical processes. The detached haze layer may be a manifestation of 1 cm sec-1 vertical velocities at altitudes above 300 km. The hemispherical asymmetry in the visible albedo may be caused by 0.05 cm sec-1 vertical velocities at altitudes of 150 to 200 km, we predict contrast reversal beyond 0.6 micrometer. Tomasko and Smith's (1982, Icarus 51, 65-95) model, in which a layer of large particles above 220 km altitude is responsible for the high forward scattering observed by Rages and Pollack (1983, Icarus 55, 50-62), is a natural outcome of the detached haze layer being produced by rising motions if aerosol mass production occurs primarily below the detached haze layer. The aerosol's electrical charge is critical for the particle size and optical depth of the haze. The geometric albedo, particularly in the ultraviolet and near infrared, requires that the particle size be near 0.15 micrometer down to altitudes below 100 km, which is consistent with polarization observations (Tomasko and Smith 1982, West and Smith 1991, Icarus 90, 330-333). Above about 400 km and below about 150 km Yung et al.'s (1984, Astrophys. J. Suppl. Ser. 55, 465-506) diffusion coefficients are too small. Dynamical processes control the haze particles below about 150 km. The relatively large eddy diffusion coefficients in the lower stratosphere result in a vertically extensive region with nonuniform mixing ratios of condensable gases, so that most hydrocarbons may condense very near the tropopause rather than tens of kilometers above it. The optical depths of hydrocarbon clouds are probably less than one, requiring that abundant gases such as ethane condense on a subset of the haze particles to create relatively large, rapidly removed particles. The wavelength dependence of the optical radius is calculated for use in analyzing observations of the geometric albedo. The lower atmosphere and surface should be visible outside of regions of methane absorption in the near infrared. Limb scans at 2.0 micrometers wavelength should be possible down to about 75 km altitude.     

Stromboli Island (Italy): Scenarios of Tsunamis Generated by Submarine Landslides

Stromboli is an Italian volcanic island known for its persistent state of activity, which leads to frequent mass failures and consequently to frequent tsunamis ranging from large (and rare) catastrophic events involving the entire southern Tyrrhenian Sea to smaller events with, however, extremely strong local impact. Most of tsunamigenic landslides occur in the Sciara del Fuoco (SdF) zone, which is a deep scar in the NW flank of the volcano, that was produced by a Holocene massive flank collapse and that is the accumulation area of all the eruptive ejecta from the craters. Shallow-water bathymetric surveys around the island help one to identify submarine canyons and detachment scars giving evidence of mass instabilities and failures that may have produced and might produce tsunamis. The main purpose of this paper is to call attention to tsunami sources in Stromboli that are located outside the SdF area. Further, we do not touch on tsunami scenarios associated with gigantic sector collapses that have repeat times in the order of several thousands of years, but rather concentrate on intermediate size tsunamis, such as the ones that occurred in December 2002. Though we cannot omit tsunamis from the zone of the SdF, the main emphasis is on the elaboration of preliminary scenarios for three more possible source areas around Stromboli, namely Punta Lena Sud, Forgia Vecchia and Strombolicchio, with the aim of purposeful contributing to the evaluation of the hazard associated with such events and to increase the knowledge of potential threats affecting Stromboli and the nearby islands of the Aeolian archipelago. The simulations show that tsunami sources outside of the SdF can produce disastrous effects. As a consequence, we recommend that the monitoring system that is presently operating in Stromboli and that is focussed on the SdF source area be extended in order to cover even the other sources. Moreover, a synoptic analysis of the results from all the considered tsunami scenarios leads to a very interesting relation between the tsunami total energy and the landslide potential energy, that could be used as a very effective tool to evaluate the expected tsunami size from estimates of the landslide size.     

A test-bed implementation of an acquisition system for indoor positioning

Indoor GNSS signals are typically received with poor signal-to-noise ratio, which impairs the acquisition stage of common global positioning system (GPS) receivers. Extending the coherent integration time increases the acquisition sensitivity, but the data-bit-rate limits the maximum achievable performance. Non-coherent processing also improves the detection performance, but indoor signals require a large amount of accumulations resulting in significant squaring loss. Moreover, both strategies have high computational complexity which fixes demanding requirements for stand alone mass-market terminals operating in real time. A sensitivity–complexity trade-off is therefore mandatory. Assisted-GPS, which is included in 3GPP specifications, reduces the overall acquisition complexity and enhances sensitivity. In this paper we describe a low-complexity-assisted data-wipe-off technique that enables the high-sensitivity acquisition of GPS signals. The method is based on the acquisition of the strongest signal in order to obtain information that eases the acquisition of the weaker ones. The analysis also addresses sources of sensitivity loss, such as Doppler effects and local oscillator inaccuracies. A test campaign with real signals and integration times up to 2 s validates the method, demonstrating the effectiveness of the proposed technique in indoor environments.     

Non-invasive Geophysical Surveys in Search of the Roman Temple of Augustus Under the Cathedral of Tarragona (Catalonia,Spain): A Case Study

An integrated geophysical survey has been conducted at the Tarragona’s Cathedral (Catalonia, NE Spain) with the aim to confirm the potential occurrence of archaeological remains of the Roman Temple dedicated to the Emperor Augustus. Many hypotheses have been proposed about its possible location, the last ones regarding the inner part of the Cathedral, which is one of the most renowned temples of Spain (twelfth century) evolving from Romanesque to Gothic styles. A geophysical project including electrical resistivity tomography (ERT) and ground probing radar (GPR) was planned over 1 year considering the administrative and logistic difficulties of such a project inside a cathedral of religious veneration. Finally, both ERT and GPR have been conducted during a week of intensive overnight surveys that provided detailed information on subsurface existing structures. The ERT method has been applied using different techniques and arrays, ranging from standard Wenner–Schlumberger 2D sections to full 3D electrical imaging with the advanced Maximum Yield Grid array. Electrical resistivity data were recorded extensively, making available many thousands of apparent resistivity data to obtain a complete 3D image after a full inversion. In conclusion, some significant buried structures have been revealed providing conclusive information for archaeologists. GPR results provided additional information about shallowest structures. The geophysical results were clear enough to persuade religious authorities and archaeologists to conduct selected excavations in the most promising areas that confirmed the interpretation of geophysical data. In conclusion, the significant buried structures revealed by geophysical methods under the cathedral were confirmed by archaeological digging as the basement of the impressive Roman Temple that headed the Provincial Forum of Tarraco, seat of the Concilium of Hispania Citerior Province.     

On the growth of nitric and sulfuric acid aerosol particles under stratospheric conditions

We present a theory for the formation of frozen aerosol particles in the Antarctic stratosphere, the coldest region of the Earth's stratosphere. The theory is applied specifically to the formation of polar stratospheric clouds. We suggest that the condensed ices are composed primarily of nitric acid and water with small admixtures of other compounds such as H₂SO₄ and HCl in solid solution. Our assumed particle formation mechanism is in agreement with the magnitude and seasonal behavior of the optical extinctions observed in the winter polar stratosphere. Physical chemistry and thermodynamic considerations suggest that at temperatures between about 200 and 185 K, stratospheric particulates are composed primarily of frozen nitric acid solutions with a composition near that of the trihydrate. Available data suggest the particles are amorphous solid solutions and not in the crystalline hydrate form. At lower temperatures (i.e., below the forst point of pure water) cirrus-like ice clouds can form.