Rapid evaluation of an indicator of seismic vulnerability in small urban nuclei

The expected fraction of buildings lost in the event of an earthquake of a given intensity can be considered as a useful indicator of the seismic vulnerability of a small urban nucleus and can be used for the evaluation of seismic risk on a regional scale. This work describes a procedure for quantifying this indicator through data obtained from the buildings which constitute the nucleus during rapid on-site surveys. The knowledge on which the procedure is based is that given by the observed vulnerability of old Italian centres.     

First Ar/Ar age of the Ceprano man (central Italy)

The Ceprano calvarium, found in 1994 in Italy and attributed to Homo cepranensis, is one of the most celebrated hominin remains of Europe. It was considered at least 700 ka-old until a recent investigation incorporating magnetostratigraphy and K-Ar ages from the literature assigned to the calvarium an age of ∼450 (+50, −100) ka. Here we pin down the age of the Ceprano calvarium to 353 ± 4 ka (±1σ external) by means of new ⁴⁰Ar/³⁹Ar dating on K-feldspars retrieved from the sediments that hosted the skull. In absence of evidence of reworking, this refined age sinks the conviction that H. cepranensis belonged to human evolution at the Brunhes–Matuyama boundary (c.a. 781 ka). Our refined age indicates that H. cepranensis lived in central Italy probably during the cold period of marine isotope stage (MIS) 10, and that despite his archaic morphology and lack of Neanderthal traits, he was contemporaneous with more advanced species such as H. heidelbergensis.     

A baroclinic coastal trapped wave event in the Gulf of Naples (Tyrrhenian Sea)

In this study, a baroclinic coastal trapped wave, with period ~?4.5 days and cross-shore scale ~?3 km, is identified in the outputs of a very-high-resolution ocean circulation model of the Campania coastal system (central Tyrrhenian Sea; including the Gulfs of Salerno, Naples, and Gaeta). The outputs are from a simulation spanning June 2003, a month in which the surface winds were always weak, except for a strong northeasterly wind event that lasted 1 day (20 June). This event is found to generate a strong upwelling along the Campania coasts, whose relaxation—virtually free, because of the weakness of the winds—produces coastal current fluctuations that propagate to the north, spanning the three gulfs. The dynamics (analyzed with a focus on the Gulf of Naples) is found to share important features with baroclinic Kelvin waves in a two-layer model, such as the sharp cross-shore decrease of the perturbation amplitude and the vertical reversal of the long-shore current velocities. The simulated phase speed, cross-shore extension, and wavelength of the perturbation are also close to those obtained using a two-layer approximation of the dynamics. Moreover, the propagation described by the models is shown to be compatible with current measurements that were made in June 2003 at the southern entrance of the Gulf of Naples. Experimental implications related to the specific oceanographic problem are finally discussed, and an experimental strategy—inspired by our modeling approach—aimed at identifying the phenomenon is proposed.     

Analysing the influence of upslope bedrock outcrops on shallow landsliding

A model for the prediction of topographic and climatic control on shallow landsliding in mountainous terrain is enhanced to analyse the impact of upslope rocky outcrops on downslope shallow landsliding. The model uses a ‘generalised quasi-dynamic wetness index’ to describe runoff propagation on bare rock surfaces connected to downslope soil-mantled topographic elements. This approach yields a simple enhanced model capable of describing the influence of upslope bedrock outcrops on the pattern of downslope soil saturation. The model is applied in both diagnostic and predictive modes to a small catchment in the eastern Italian Alps for which a detailed inventory of shallow landslides in areas dominated by rocky outcrops is available. In the diagnostic mode, the model is used with satisfactory results to reproduce the pattern of instability generated by an intense short-duration storm occurred on 14 September 1994, which triggered a large percentage of the surveyed landslides. In the predictive mode, the model is used for hazard assessment, and the return time of the critical rainfall needed to cause instability for each topographic element is determined. Modelling results obtained in the predictive mode are evaluated against all the surveyed landslides. It is revealed that the generalised quasi-dynamic model offers considerable improvement over the non-generalised quasi-dynamic model and the steady-state model in predicting existing landslides as represented in the considered landslide inventory.     

Human influence on seagrass habitat fragmentation in NW Mediterranean Sea

Habitat fragmentation in meadows of Posidonia oceanica, the most important and abundant seagrass in the Mediterranean Sea, was investigated at a region-wide spatial scale using a synthetic ecological index, the Patchiness Index (PI). We tested the hypothesis that human impacts are the major factor responsible for habitat fragmentation in P. oceanica meadows contrasting fragmentation of meadows located in “anthropized” areas with that of meadows located in areas with low anthropization and considered as virtually “natural”. We also related fragmentation of meadow with the morphodynamic state of the submerged beach (i.e. distinctive types of beach produced by the topography, the wave climate and the sediment composition) in order to investigate the influence of one natural component on the seagrass meadow seascape. Results demonstrated that fragmentation in the P. oceanica meadows is strongly influenced by the human component, being lower in natural meadows than in anthropized ones, and that it is little influenced by the morphodynamic state of the coast. The use of landscape approaches to discriminate natural disturbance from human impacts that affect seagrass meadows is thus recommended for the proper management of coastal zones.     

Joint analysis of Rayleigh- and Love-wave dispersion: Issues, criteria and improvements

Joint analysis of Rayleigh- and Love-wave dispersion is performed with the aim of evaluating how their joint use can improve retrieved vertical V_S profiles. In fact, non-uniqueness of the solution and complex energy distribution among different modes represent problems which, if not properly considered, can eventually lead to ambiguous or erroneous subsurface models.Some tests performed on synthetic datasets show that for the deepest layers the improvements obtained by the joint inversion cannot be considered as fully decisive in terms of ultimate solution of non-uniqueness. Nevertheless joint analysis of dispersive properties of Rayleigh and Love waves reveals as a highly valuable tool able to clarify possible interpretation issues of the single components. Under some stratigraphical circumstances, velocity spectra of Rayleigh waves can in fact be extremely complex in terms of energy distribution among different modes and erroneous interpretations of dispersion curves can thus occur. Beneficial aspects of the joint analysis is shown in the light of possible inconsistencies of the Pareto front, since major interpretative errors can be revealed in the outcomes of the proposed inversion procedure. Two field datasets are analysed also suggesting some improvements in the field acquisition procedures aimed at the acquisition of both Rayleigh and Love waves.     

Quantitative analysis of H2O and CO2 in cordierite using polarized FTIR spectroscopy

We report a FTIR (Fourier transform infrared) study of a set of cordierite samples from different occurrence and with different H₂O/CO₂ content. The specimens were fully characterized by a combination of techniques including optical microscopy, single-crystal X-ray diffraction, EMPA (electron microprobe analysis), SIMS (secondary ion mass spectrometry), and FTIR spectroscopy. All cordierites are orthorhombic Ccmm. According to the EMPA data, the Si/Al ratio is always close to 5:4; X _Mg ranges from 76.31 to 96.63, and additional octahedral constituents occur in very small amounts. Extraframework K and Ca are negligible, while Na reaches the values up to 0.84 apfu. SIMS shows H₂O up to 1.52 and CO₂ up to 1.11 wt%. Optically transparent single crystals were oriented using the spindle stage and examined by FTIR micro-spectroscopy under polarized light. On the basis of the polarizing behaviour, the observed bands were assigned to water molecules in two different orientations and to CO₂ molecules in the structural channels. The IR spectra also show the presence of small amounts of CO in the samples. Refined integrated molar absorption coefficients were calibrated for the quantitative microanalysis of both H₂O and CO₂ in cordierite based on single-crystal polarized-light FTIR spectroscopy. For H₂O the integrated molar coefficients for type I and type II water molecules (ν₃ modes) were calculated separately and are ^[I]ε?=?5,200?±?700?l?mol^?1?cm^?2 and ^[II]ε?=?13,000?±?3,000?l?mol^?1?cm^?2, respectively. For CO₂ the integrated coefficient is $ \varepsilon_{{{\text{CO}}_{ 2} }} $ ?=?19,000?±?2,000?l?mol^?1?cm^?2.     

A Reliable Method for Determining the Oxidation State of Manganese at the Microscale in Mn Oxides via Raman Spectroscopy

Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn²⁺ is recognised by a band around 530 cm^?1, Mn³⁺ by a band around 580 cm^?1 and Mn⁴⁺ by a band around 630 cm^?1, while tetrahedrally co‐ordinated Mn²⁺ is recognisable by a band around 650 cm^?1. Strongly distorted Mn³⁺ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes.