Temperature lapse rate and methane in Titan's troposphere

We have reanalyzed the Voyager radio occultation data for Titan, examining two alternative approaches to methane condensation. In one approach, methane condensation is facilitated by the presence of nitrogen because nitrogen lowers the condensation level of a methane/nitrogen mixture. The resulting enhancement in methane condensation lowers the upper limit on surface relative humidity of methane obtained from the Voyager occultation data from 0.7 to 0.6. We conclude that in this case the surface relative humidity of methane lies between 0.08 and 0.6, with values close to 0.6 indicated. In the other approach, methane is allowed to become supersaturated and reaches 1.4 times saturation in the troposphere. In this case, surface humidities up to 100% are allowed by the Voyager occultation data, and thus the upper limit must be set by other considerations. We conclude that if supersaturation is included, then the surface relative humidity of methane can be any value greater than 0.08--unless a deep ocean is present, in which case the surface relative humidity is limited to less than 0.85. Again, values close to 0.6 are indicated. Overall, the tropospheric lapse rate on Titan appears to be determined by radiative equilibrium. The lapse rate is everywhere stable against dry convection, but is unstable to moist convection. This finding is consistent with a supersaturated atmosphere in which condensation-and hence moist convection-is inhibited.     

Evidence of space weathering in regolith breccias I: Lunar regolith breccias

Abstract— We have analyzed a suite of lunar regolith breccias in order to assess how well space weathering products can be preserved through the lithification process and therefore whether or not it is appropriate to search for space weathering products in asteroidal regolith breccia meteorites. It was found that space weathering products, vapor/sputter deposited nanophase‐iron‐bearing rims in particular, are easily identified in even heavily shocked/compacted lunar regolith breccias. Such rims, if created on asteroids, should thus be preserved in asteroidal regolith breccia meteorites. Two additional rim types, glass rims and vesicular rims, identified in regolith breccias, are also described. These rims are common in lunar regolith breccias but rare to absent in lunar soils, which suggests that they are created in the breccia‐forming process itself. While not “space weathering products” in the strictest sense, these additional rims give us insight into the regolith breccia formation process. The presence or absence of glass and/or vesicular rims in asteroidal regolith breccias will likewise tell us about environmental conditions on the surface of the asteroid body on which the breccia was created.     

Pristine stratospheric collection of interplanetary dust on an oil‐free polyurethane foam substrate

We performed chemical, mineralogical, and isotopic studies of the first interplanetary dust particles (IDPs) collected in the stratosphere without the use of silicone oil. The collection substrate, polyurethane foam, effectively traps impacting particles, but the lack of an embedding medium results in significant particle fragmentation. Two dust particles found on the collector exhibit the typical compositional and mineralogical properties of chondritic porous interplanetary dust particles (CP‐IDPs). Hydrogen and nitrogen isotopic imaging revealed isotopic anomalies of typical magnitude and spatial variability observed in previous CP‐IDP studies. Oxygen isotopic imaging shows that individual mineral grains and glass with embedded metal and sulfide (GEMS) grains are dominated by solar system materials. No systematic differences are observed in element abundance patterns of GEMS grains from the dry collection versus silicone oil‐collected IDPs. This initial study establishes the validity of a new IDP collection substrate that avoids the use of silicone oil as a collection medium, removing the need for this problematic contaminant and the organic solvents necessary to remove it. Additional silicone oil‐free collections of this type are needed to determine more accurate bulk element abundances of IDPs and to examine the indigenous soluble organic components of IDPs.     

Long-term (105) or short-term (103) δ13C excursion near the Palaeocene-Eocene transition: evidence from the Tethys

Expanded sedimentary records from the Tethys reveal unique faunal and isotopic changes across the Palaeocene-Eocene (P-E) transition. Unlike in the open oceans, the Tethys exhibits a gradual decrease of 1.5% in δ¹³C values prior to the rapid δ¹³C excursion. Associated with the 6¹³C excursion is a decrease in calcite burial, increase in detrital content and appearance of a unique opportunistic planktic foraminifera1 assemblage (e.g. compressed acarininids). The existence of a prelude decrease in δ¹³C values in the Tethys suggests that the P-E δ¹³C excursion may have occurred in two steps and over a few hundred thousand years, rather than as one step over a few thousand years as previously suggested. This slower excursion rate is readily explained by changing organic carbon weathering or burial rates and avoids the need of invoking ad hoc scenarios.     

Interpolation for geochemical surface reconstruction incorporating topographic catchment definitions

Geochemical surfaces are reconstructed by interpolating geochemical measurements obtained from stream-water and stream-sediment samples. The geographical region that influences (and therefore is represented by) the value of a geochemial sample is its topographic catchment area. However, standard convention is to treat and to record the stream sample in the database as a point location, and to reconstruct geochemical surfaces utilizing conventional point interpolation procedures. These interpolation procedures assume, generally, that a data point exerts geographical influence away from itself in all directions, and that influence declines with distance away from that data point. Conventional interpolation procedures are poorly suited for reconstructing geochemical surfaces from stream samples; they do not take into account the true geographic area that geochemical sample points represent (topographic catchments). In this paper we propose a method of interpolation which assumes that data points are representative of their topographic catchment areas. Experimental data indicates that a surface reconstruction procedure which preserves the areal character of geochemical samples provides results more meaningful than surfaces reconstructed using more conventional interpolation techniques.     

Near-K/T age of clastic deposits from Texas to Brazil: impact,volcanism and/or sea-level lowstand?

Near-K/T boundary clastic deposits from Texas, Mexico, Haiti, Guatemala and Brazil, often described as impact-generated tsunami deposits, are stratigraphically below well-defined K/T boundary horizons and appear not to be causally related to the K/T boundary event. Stratigraphic evidence indicates that their deposition began during the last 170–200 kyr of the Maastrichtian, coincident with a major eustatic sea-level lowstand that lowered sea level by as much as 70–100 m. Clastic deposition ended a few tens of thousands of years before the K/T boundary during a rapidly rising sea level. The presence of glass in clastic deposits in Haiti, northeastern Mexico and Yucatan suggests that the sea-level lowstand coincided with a time of major volcanism or pre-K/T boundary bolide impact.     

Representation of planar integral-transformations by 4-D wavelet decomposition

In one way or the other, numerical methods for the evaluation of integral operators can often be related to the solution of the so-called Galerkin equations. For convolution operators and exponentials with purely imaginary exponents as base functions the Galerkin matrix becomes diagonal and this fact is the core of the FFT techniques, used in Physical Geodesy. For non-convolution operators the FFT technique is not applicable. This paper aims at the development of a technique, which can also be applied for non-convolution operators. This technique is based on the use of wavelets as base functions. In this case the Galerkin matrix is not diagonal but (after thresholding) very sparse and this leads to methods, which are similarly efficient as FFT in the convolution case. The paper starts with the theoretical background for n-dimensional wavelet analysis and the representation of integral operators with respect to those wavelet bases. The resulting algorithm is tested for convolution and non-convolution operators.