Surface-sediment and epilithic diatom pH calibration sets for remote European mountain lakes (AL:PE Project) and their comparison with the Surface Waters Acidification Programme (SWAP) calibration set

A modern diatom-pH calibration data-set consisting of surface-sediment diatom assemblages from 118 lakes and 530 taxa is presented. The AL:PE data-set is from high-altitude or high-latitude lakes in the Alps, Norway, Svalbard, Kola Peninsula, UK, Slovenia, Slovakia, Poland, Portugal, and Spain (pH range = 4.5-8.0; DOC range = 0.2-3.2 mg l^-1). In addition, 92 epilithon samples from 22 high-altitude or high-latitude lakes comprise an AL:PE epilithon diatom-pH data-set. Weighted averaging partial least squares regression is used to develop pH-inference models. The AL:PE data-set has a root-mean-square-error of prediction (RMSEP) of 0.33 and a maximum bias of 0.36 pH units and r² of 0.82, as assessed by leave-one-out cross-validation. The epilithon data-set has, after data-screening and the deletion of one very obvious outlier, a RMSEP of 0.23 and a maximum bias of 0.18 pH units and r² of 0.88. The 167 sample SWAP diatom-pH data-set from lowland or upland lakes in the UK, Norway, and Sweden has a RMSEP of 0.29 and a maximum bias of 0.23 pH units and r² of 0.86.The pH optima, as estimated by weighted averaging and Gaussian regression, are compared for the three data-sets (AL:PE, SWAP, AL:PE epilithon). There is a good correspondence between the AL:PE and the AL:PE epilithon optima, but a consistent bias between the AL:PE and SWAP optima, with the SWAP optima being lower than the AL:PE estimates.The predictive performances of the AL:PE and SWAP calibration data-sets are compared using independent test samples and six core sequences, all from high-altitude lakes, one in south-east Siberia and five in eastern Scotland. The results show the importance of using the AL:PE data-set for inferring lake-water pH from diatom assemblages in high-altitude or high latitude lakes with low DOC concentrations.     

Anisotropy in multi-offset deep-crustal seismic experiments

Modelling of deep-seismic wide-angle data commonly assumes that the Earth is heterogeneous and isotropic. It is important to know the magnitudes of errors that may be introduced by isotropic-based wide-angle models when the Earth is anisotropic. It is equally important to find ways of detecting anisotropy and determining its properties.
  This paper explores the errors introduced by interpreting anisotropic seismic data with isotropic models. Errors in P -wave reflector depths are dependent on the magnitude of the velocity anisotropy and the direction of the fast axis. The interpreted, isotropic, model velocity function is found to correspond closely to the horizontal velocity of the anisotropic medium. An additional observed parameter is the time mismatch , which we define to be the difference between the vertical two-way traveltime to a reflector and the time-converted wide-angle position of the reflector. The magnitude of the time mismatch is typically <1.0  s (when the whole crust is anisotropic) and is found to be closely related to the magnitude and sign of the anisotropic anellipticity. The relationships are extendible to more complicated models, including those with vertical velocity gradients, crustal zonation, and lower symmetry orders.
  A time mismatch may be symptomatic of the presence of anisotropy. We illustrate the observation of a time mismatch for a real multi-offset seismic data set collected north of Scotland and discuss the implications for crustal anisotropy in that region.     

Researching local elites: reflexivity, ‘situatedness’ and political-temporal contingency

Since the late 1970s, the UK has experienced a series of changes in the mechanisms of governing local economic development. This paper considers the methodological consequences of these recent changes. Drawing on two local elite-based case studies, involving semi-structured interviews, we reflect on our acquired ‘situated knowledge’ and argue that this is related to the contingent nature of our respective research access. We advocate that an approach sensitive to ‘research situatedness’ (with respect to the politics of time as a ‘research moment’) is essential to avoid over generalising from our experiences. To address this concern, the paper offers two concepts for debate – political-temporal contingency and the mode of entry.     

Diatom responses to late-glacial and early-Holocene environmental changes at Kråkenes, western Norway

A stratigraphic diatom sequence is presented for the period from 13,870-9,170 cal BP from Kråkenes Lake, western Norway. Changes in species assemblages are discussed with reference to the changing environmental conditions in the Allerød, Younger Dryas, and the early Holocene and to the development of the aquatic ecosystem. The site is sensitive to acidification, and diatom-based transfer functions are applied to estimate the past pH status. The combination of rapid sediment accumulation together with an excellent calibrated radiocarbon chronology means that the rate of inferred pH change and associated increase in [H⁺] can be assessed and compared with recent, anthropogenically acidified situations.The Allerød diatom assemblages are dominated by benthic taxa particularly Fragilaria species, indicating an unproductive, alkaline, turbid, and immature system. Diatoms are absent in the early part of the Younger Dryas, but subsequently a sparse planktonic flora develops reflecting decreased turbidity and/or increased nutrient supply. A clear sequence of diatom assemblages is seen in the early Holocene. A short-lived peak of Stephanodiscus species indicating a period of increased nutrient availability occurred at ca. 11,500 cal BP. Throughout the early Holocene, acid-tolerant species increasingly replaced less acidophilous, circumneutral taxa.The lake became slightly more acid during the Allerød, but this was statistically insignificant in a trend test involving regression of pH or [H⁺] in relation to age. Diatom-inferred pH declined rapidly during the early Holocene period investigated (9,175-11,525 cal BP) with a statistically significant overall rate of 0.024 pH units per 100 yrs. This consisted of an older (ca. 11,525-10,255 cal BP) phase, where pH fell more rapidly at up to 0.095 pH units per 100 yrs; and a younger phase after ca. 10,500 cal BP where the pH fall was extremely slow (0.008 pH units per 100 yrs) and was not statistically significant.In the Allerød a combination of low catchment productivity together with disturbance, weathering, and minerogenic inwash ensured that the base-cation status remained relatively high. In the Holocene the catchment soils stabilised and base cations were sequestered by terrestrial vegetation and soil. This resulted in reduced base-cation leaching and this, together with the production of organic acids caused the lake to acidify, reaching an equilibrium by ca. 10,000 cal BP.     

Multiscale Terrain and Topographic Modelling with the Implicit TIN

It is often assumed that real land surfaces demonstrate the statistically self-affine scaling behaviour of fractional Brownian surfaces. Tests of this assumption against empirical data, however, show many deviations. Estimates of fractal properties vary between methods and over different scale ranges. So far, this empirical evidence has come from the analysis of variograms for DEMs representing areas up to tens of kilometres in diameter. Here we report results obtained by using variograms to analyse land surface DEMs at the continental scale, with a grid resolution of 30 arc seconds. Results reveal variogram curvature and breaks of slope, but also linear sections over distance lags of hundreds of kilometres. The estimated mean fractal dimension calculated from these sections is 2.66, substantially higher for all continents at these broad scales (around 200 km) than values calculated at the erosional landscape scale (around 200 m). Thus the land surface is not self-affine, and it is not clear that it follows any simple multifractal model. At the longest wavelengths, patterns found in the variograms appear to be related to broad tectonic features of the Earth's surface. For the reader to assess their quality and generality, estimates of fractal dimension should always be accompanied by statements of the scale range covered and the goodness of fit to a log-linear relationship.     

Multiwavelength observations of an evolved galaxy group: an end-point of galaxy merging?

The group of galaxies RXJ1340.6+4018 has approximately the same bolometric X-ray luminosity as other bright galaxy groups and poor clusters such as the Virgo cluster. However, 70 per cent of the optical luminosity of the group comes from a dominant giant elliptical galaxy, compared with 5 per cent from M87 in Virgo.The second brightest galaxy in RXJ1340.6+4018 is a factor of 10 fainter (Δ m ₁₂=2.5 mag) than the dominant elliptical, and the galaxy luminosity function has a gap at about L *.
We interpret the properties of the system as a result of galaxy merging within a galaxy group. We find that the central galaxy lies on the Fundamental Plane of ellipticals, has an undisturbed, non-cD morphology, and has no spectral features indicative of recent star formation, suggesting that the last major merger occurred ≳4 Gyr ago. The deviation of the system from the cluster L _X− T relation in the opposite sense to most groups may be caused by an early epoch of formation of the group or a strong cooling flow.
The unusual elongation of the X-ray isophotes and the similarity between the X-ray and optical ellipticities at large radii (∼230 kpc) suggest that both the X-ray gas and the outermost stars of the dominant galaxy are responding to an elongated dark matter distribution. RXJ1340.6+4018 may be part of a filamentary structure related to infall in the outskirts of the cluster A1774.     

Book Review: Regression Analysis of Count Data. By A. Colin Cameron and Pravin K. Trivedi Cambridge University Press,Cambridge, UK, 1998, 411 p., US$64.95/US$24.95, ISBN 0-521-63201-3 (hardbound), ISBN 0-521-63567-5 (paperbound)

Mathematical Geosciences -     

Late quaternary sediment sources, storage and transfers within mountain basins using clast lithological analysis: Pineta Basin, central Pyrenees, Spain

Understanding basin-wide sediment dynamics, both spatially and temporally, is an important antecedent to eventual quantitative interpretation of sediment transfer within mountain fluvial systems. This paper describes an attempt to trace sediment transfer modes and pathways using clast lithological analysis in a small mountain basin strongly influenced by glaciation: the Pineta Basin in the central Pyrenees of Spain. The paper interprets slope–channel interaction by encompassing the whole basin, enabling staged sedimentary pathways to be revealed. Additionally, bed-material textures of the modern rivers and youngest La Sarra Terrace were investigated to provide further information on the geomorphic coupling of the system. Relatively few studies have taken this approach. Glacial and later, fluvial systems transferred the sediments creating laterally extensive, polylithological sediment stores. Local depositional systems overprint this inherited signature. To what extent depends on the size and energy of the local system. Significant impacts are made by conduits, such as large-scale fluvially dominated fans and waterfalls, which deliver local lithologies to the main river. Conduits may be part of the main river system or part of the tributary system. Conduits are the most important elements when considering provenance studies and theoretical modelling.     

Controls on the evolution and demise of Lower Carboniferous carbonate platforms,northern margin of the Dublin Basin,Ireland

Shallow water platform limestones of the Chadian–Asbian Milverton Group are restricted to the north-eastern part of the Lower Carboniferous (Dinantian) Dublin Basin. Here, they are confined to two granite-cored fault blocks, the Kentstown and Balbriggan Blocks, known to have been active during the late Dinantian. Three areas of platform sedimentation are delimited (the Kentstown, Drogheda and Milverton areas), although in reality they probably formed part of a single carbonate platform. Resedimented submarine breccias and calciturbidites (Fingal Group) composed of shallow water allochems and intraclasts sourced from the platform accumulated, along with terrigenous muds, in the surrounding basinal areas. Sedimentological evidence suggests that the Kentstown and Balbriggan Blocks possessed tilt-block geometries and developed during an episode of basin-wide extensional faulting in late Chadian time. Rotation of the blocks during extension resulted in the erosion of previously deposited sequences in footwall areas and concomitant drowning of distal hangingwall sequences. Antithetic faults on the northern part of the Balbriggan Block aided the preferential subsidence of the Drogheda area and accounts for the anomously thick sequence of late Chadian platform sediments present there. Continued subsidence and/or sea-level rise in the late Chadian–early Arundian resulted in transgression of the Kentstown and Balbriggan Blocks; carbonate ramps developed on the hangingwall dip slopes and transgressed southward with time. Subsequent progradation and aggradation of shallow water sediments throughout the Arundian to Asbian led to the development of carbonate shelves. Several coarse conglomeratic intervals within the contemporaneous basinal sequences of the Fingal Group attest to periodic increases of sediment influx associated with the development of the shelves. Sedimentological processes controlled the development of the carbonate platforms on the hangingwall dip slopes of the Kentstown and Balbriggan Blocks, though periodic increases of sediment flux into the basinal areas may have been triggered by eustatic falls in sea level. In contrast, differential subsidence along the bounding faults of these blocks exerted a strong control on the margins of the late Dinantian shelves, maintaining relatively steep slopes and inhibiting the progradation of the shelves into the adjacent basins. Tectonically induced collapse and retreat of the platform margins occurred in the late Asbian–early Brigantian. Platform sediments are overlain by coarse-grained proximal basinal facies which fine upwards before passing into a thick shale sequence, indicating that by the late Brigantian carbonate production had almost stopped as the platforms were drowned.     

Changes in timber haul emissions in the context of shifting forest management and infrastructure

The issues surrounding 'Reduced Emissions from Deforestation and Forest Degradation' (REDD) have become a major component of continuing negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). This paper aims to address two key requirements of any potential REDD mechanism: first, the generation of measurable, reportable and verifiable (MRV) REDD credits; and secondly, the sustainable and efficient provision of emission reductions under a robust financing regime. To ensure the supply of MRV credits, we advocate the establishment of an 'International Emission Reference Scenario Coordination Centre' (IERSCC). The IERSCC would act as a global clearing house for harmonized data to be used in implementing reference level methodologies. It would be tasked with the collection, reporting and subsequent processing of earth observation, deforestation- and degradation driver information in a globally consistent manner. The IERSCC would also assist, coordinate and supervise the computation of national reference scenarios according to rules negotiated under the UNFCCC. To overcome the threats of "market flooding" on the one hand and insufficient economic incentives for REDD on the other hand, we suggest an 'International Investment Reserve' (IIR) as REDD financing framework. In order to distribute the resources of the IIR we propose adopting an auctioning mechanism. Auctioning not only reveals the true emission reduction costs, but might also allow for incentivizing the protection of biodiversity and socio-economic values. The introduced concepts will be vital to ensure robustness, environmental integrity and economic efficiency of the future REDD mechanism.