Long-Term Changes in Water Quality and Productivity in the Patuxent River Estuary: 1985 to 2003

We conducted a quantitative assessment of estuarine ecosystem responses to reduced phosphorus and nitrogen loading from sewage treatment facilities and to variability in freshwater flow and nonpoint nutrient inputs to the Patuxent River estuary. We analyzed a 19-year dataset of water quality conditions, nutrient loading, and climatic forcing for three estuarine regions and also computed monthly rates of net production of dissolved O₂ and physical transport of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) using a salt- and water-balance model. Point-source loading of DIN and DIP to the estuary declined by 40–60% following upgrades to sewage treatment plants and correlated with parallel decreases in DIN and DIP concentrations throughout the Patuxent. Reduced point-source nutrient loading and concentration resulted in declines in phytoplankton chlorophyll-a (chl-a) and light-saturated carbon fixation, as well as in bottom-layer O₂ consumption for upper regions of the estuary. Despite significant reductions in seaward N transport from the middle to lower estuary, chl-a, turbidity, and surface-layer net O₂ production increased in the lower estuary, especially during summer. This degradation of water quality in the lower estuary appears to be linked to a trend of increasing net inputs of DIN into the estuary from Chesapeake Bay and to above-average river flow during the mid-1990s. In addition, increased abundance of Mnemiopsis leidyi significantly reduced copepod abundance during summer from 1990 to 2002, which favored increases in chl-a and allowed a shift in total N partitioning from DIN to particulate organic nitrogen. These analyses illustrate (1) the value of long-term monitoring data, (2) the need for regional scale nutrient management that includes integrated estuarine systems, and (3) the potential water quality impacts of altered coastal food webs.     

Tracing the exhumation of the Eclogite Zone (Tauern Window,Eastern Alps) by <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of white mica in eclogites

New radiometric ages from the Subpenninic nappes (Eclogite Zone and Rote Wand – Modereck Nappe, Tauern Window) show that phengites formed under eclogite-facies metamorphic conditions retain their initial isotopic signature, even when associated lithologies were overprinted by greenschist- to amphibolite-facies metamorphism. Different stages of the eclogite-facies evolution can be dated provided ⁴⁰Ar/³⁹Ar dating is combined with micro-structural analyses. An age of 39 Ma from the Rote Wand – Modereck Nappe is interpreted to be close to the burial age of this unit. Eclogite deformation within the Eclogite Zone started at the pressure peak along distinct shear zones, and prevailed along the exhumation path. An age of ca. 38 Ma is only observed for eclogites not affected by subsequent deformation and is interpreted as maximum age due to the possible influence of homogenously distributed excess argon. During exhumation deformation was localised along distinct mylonitic shear zones. This stage is mainly characterised by the formation of dynamically recrystallized omphacite2 and phengite. Deformation resulted in the resetting of the Ar isotopic system within the recrystallized white mica. Flat argon release spectra showing ages of 32 Ma within mylonites record the timing of cooling along the exhumation path, and the emplacement onto the Venediger Nappe. Ar-release patterns and ³⁶Ar/⁴⁰Ar vs.³⁹Ar/⁴⁰Ar isotope correlation analyses indicate no significant ⁴⁰Ar-loss after initial closure, and only a negligible incorporation of excess argon. From the pressure peak onwards, eclogitic conditions prevailed for almost 8–10 Ma.     

Probabilistic modeling of seismically triggered landslides using Monte Carlo simulations

The 2004 Chuetsu earthquakes of Niigata (Japan) triggered numerous landslides, and the most widespread types of landslides were highly disrupted, relatively shallow slides and soil (debris) flows. This paper presented a method to evaluate slope instability using Newmark displacement on a pixel-by-pixel basis in a given area. The proposed method was able to integrate Newmark displacement modeling and Monte Carlo simulations within geographical information systems. In the modeling, an empirical attenuation relationship was utilized to calculate Arias intensity over this study area, and the variability of geotechnical parameters was taken into account to calculate coseismic landslide displacement. Before deriving the displacement from related inputs, the Monte Carlo simulations ran 1,500 times and generated 1,500 displacement values for each grid cell, and then means and standard deviations of displacement were calculated and probabilistic distributions can be obtained. Finally, given 10 cm as a threshold value of displacement, estimated probabilities of displacement exceeding 10 cm were shown as a map of seismic landslide hazards. The resulting hazard map was classified into four categories from very low to high level.     

Slope inclinometers for landslides

Slope inclinometers/indicators are used to determine the magnitude, rate, direction, depth, and type of landslide movement. This information is usually vitally important for understanding the cause, behavior, and remediation of a landslide. However, many inclinometer measurements fail to achieve these intended aims because of lack of appreciation of the many factors that need to be correctly implemented during installation, monitoring, and data reduction to yield useful data. This paper presents some guidelines for understanding, installing, and interpreting slope inclinometers and presents three case histories that illustrate some of the pitfalls that can develop if these guidelines are not followed.     

Groundwater flow modeling for effective implementation of landslide stability enhancement measures

This paper deals with groundwater hydrology at a prominent fracture zone landslide slope (Nuta–Yone landslides) in Japan with an objective to explore an efficient method for the application of landslide stability enhancement measures. The correlation analyses between the hydrological parameters and ground surface movement data at this landslide resulted in low correlation values indicating that the geological formation of the area is extremely complex. For the purpose of understanding the groundwater flow behavior in the landslide area, a three-dimensional transient groundwater flow model was prepared for a part of the landslide slope, where the levels of effectiveness of applied landslide stability enhancement measures (in the form of multilayered deep horizontal drains) are different, and was calibrated against the measured water surface elevations at different piezometer locations. The parameter distributions in the calibrated model and the general directions of the groundwater flow in terms of flow vectors and the results of particle tracking at the model site were interpreted to understand the reasons for variations in effectiveness of existing landslide stability enhancement measures and to find potentially better locations for the implementation of future landslide stability enhancement measures. From the modeling results, it was also understood that groundwater flow model can be effectively used in better planning and locating the landslide stability enhancement measures.     

An implementation of rock engineering system for ranking the instability potential of natural slopes in Greek territory. An application in Karditsa County

This paper presents an application of rock engineering system (RES) in an attempt to reveal and assess the inherent instability potential of 388 sites where equivalent landslides have been manifested and recorded in the region of Karditsa County, Greece. The main objective has been defining the principal causative and triggering factors responsible for the manifestation of landslide phenomena, quantify their interactions, obtain their weighted coefficients, and calculate the instability index, which refers to the inherent potential instability of each natural slope of the examined region. From the statistical interpretation of the data reported in a well-documented database and concerning the examined failure sites, a clear correlation between the instability index and the area affected by a single landslide event has been revealed. Almost the entire failure sites, 98% of the examined slope sites, exhibit an instability index value over 55, a value which is thought to be a critical threshold for landslide manifestation concerning natural slopes in Karditsa County. It is argued that the presented RES methodology, engaging the selected set of parameters, could be considered as an effective expert's tool for ranking, in an objectively optimal and simple way, the instability potential of natural slopes in Karditsa County, and thus providing a tool for sound zoning landslide hazard.     

An essay on the interactions between climate and society

There has been increasing concern about the lack of involvement by social scientists and humanists in a global change program, although many social scientists are already directly involved in various aspects of research on environmental change, and their research interests are clearly central to a global change research agenda. Based on a historical review, the role of social science disciplines as well as social science institutes in an emerging multidecadal global change program is discussed. Both “plan of action” and “plan of inaction” are suggested to avoid potential pitfalls due to the rush development of a social science program into the existing global climate change problem.     

Application of an environmentally optimum cooling water system design in water and energy conservation

Recirculating cooling water systems are consist of a cooling tower and heat-exchanger network which conventionally have a parallel configuration. However, reuse of water between different cooling duties enables cooling water networks to be designed with series arrangements. This will results in performance improvement and increased cooling tower capacity. Research on recirculating cooling water systems has mostly focused on the individual components. However, a particular design method represented by Kim and Smith accounts for the whole system interactions. In this study, the Kim and Smith design method is expanded and a comprehensive simulation model of recirculating cooling system was developed to account for the interaction between the cooling tower performance and the heat-exchanger network configuration. Regarding this model and considering cycle water quality through introducing ozone treatment technology, a modern methodology of recirculating cooling water system design was established and developed. This technique, called the integrated ozone treatment cooling system design, is a superior designed tool based on pinch analysis and mathematical programing. It also ensures maximum water and energy conservation, minimum cost and environmental impacts. Related coding in MATLAB version 7.3 was used for the illustrative example to get optimal values in cooling water design method computations. The result of the recently introduced design methodology was compared with the Kim and Smith design method.     

Ability of indigenous Bacillus licheniformis and Bacillus subtilis in microbial enhanced oil recovery

Microbially produced lipopeptide have been isolated and studied for microbial enhanced oil recovery. About 60 gram positive bacteria isolated from soil contaminated with crude oil, near the crude oil storage tank in Tehran Refinery, Tehran, Iran. However, most of these studies have produced lipopeptide by one of the pure-culture microbes isolated in a laboratory. Among the isolates, heamolytic tests revealed two biosurfactant producers. The isolated strains were designated as C2, E1. By using morphological, biochemical and molecular biology tests (16 SrRNA), the strains identified as Bacillus licheniformis and Bacillus subtitlis, respectively. Emulsification activity and measurement of surface tension indicated that, the isolates were high producers of biosurfactant. The product of C2 and E1 is mainly lipopeptide. This product reduce surface tension from 65 to 30 mN/m. Emulsified activity of crude oil was 92% for C2 and 90 % in case of E1. This is the first report of indigenous Bacillus licheniformis and Bacillus subtilis from a soil contaminated with oil in an Iranian refinery with ability to produce biosurfactant.     

Particle size distribution and dissolution properties of metals in cyclone fly ash

The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution.