Changes in Venice Lagoon dynamics due to construction of mobile barriers

The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios.     

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.     

A cross-ecosystem comparison of spatial and temporal patterns of covariation in the recruitment of functionally analogous fish stocks

Temporal and spatial patterns of recruitment (R) and spawning stock biomass (S) variability were compared among functionally analogous species and similar feeding guilds from six marine ecosystems. Data were aggregated into four regions including the Gulf of Maine/Georges Bank, the Norwegian/Barents Seas, the eastern Bering Sea, and the Gulf of Alaska. Variability was characterized by calculating coefficients of variation and anomalies for three response variables: ln(R), ln(R/S), and stock–recruit model residuals. Patterns of synchrony and asynchrony in the response variables were examined among and between ecosystems, between- and within-ocean basins and among functionally analogous species groups using pair-wise correlation analysis corrected for within-time series autocorrelation, multivariate cross-correlation analyses and regime shift detectors. Time series trends in response variables showed consistent within basin similarities and consistent and coherent differences between the Atlantic and Pacific basin ecosystems. Regime shift detection algorithms identified two broad-scale regime shift time periods for the pelagic feeding guild (1972–1976 and 1999–2002) and possibly one for the benthic feeding guild (1999–2002). No spatial patterns in response variable coefficients of variation were observed. Results from multivariate cross-correlation analysis showed similar trends. The data suggest common external factors act in synchrony on stocks within ocean basins but temporal stock patterns, often of the same species or functional group, between basins change in opposition to each other. Basin-scale results (similar within but different between) suggest that the two geographically broad areas are connected by unknown mechanisms that, depending on the year, may influence the two basins in opposite ways. This work demonstrates that commonalities and synchronies in recruitment fluctuations can be found across geographically distant ecosystems but biophysical causes of the fluctuations remain difficult to identify.     

The constancy of galactic cosmic rays as recorded by cosmogenic nuclides in iron meteorites

We measured the He, Ne, and Ar isotopic concentrations and the ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From ⁴¹Ca and ³⁶Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The ³⁶Cl‐³⁶Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The ³⁶Cl‐³⁶Ar CRE ages are on average 40% lower than the ⁴¹K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the ⁴¹K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined ⁴¹K‐K CRE age system the most likely explanation. Finally, we present new ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.     

Development and validation of a finite element morphological model for shallow water basins

Recognising the importance of understanding sediment dynamics to evaluate the status of a coastal lagoon environment, this work has been focused on the investigation of the hydrodynamic and sediment transport processes occurring in such basins. In order to describe the lagoon system, a modelling approach combining hydrodynamics, waves and sediment dynamics has been developed. The framework of the numerical model consists of a finite element hydrodynamic model, a third generation finite element spectral wave model and a sediment transport and morphodynamic model for both cohesive and non-cohesive sediments. The model adopts the finite element technique for spatial integration, which has the advantage to describe more accurately complicated bathymetry and irregular boundaries for shallow water areas. The developed model has been applied to test cases and to a very shallow tidal lagoon, the Venice Lagoon, Italy. Numerical results show good agreement with water level, waves and turbidity measurements collected in several monitoring stations inside the Lagoon of Venice. Such a model represents an indispensable tool in analysing coastal problems and assessing morphological impacts of human interference.     

The meteorite collection sites of Antarctica

Abstract— Antarctic meteorites have been and are being well studied but the potential for glaciological and climatological information in the sites where they are found is only beginning to be realized. To date, meteorite stranding surfaces have been identified only in East Antarctica: (1) The MacKay Glacier/David Glacier region contains the Allan Hills and the Reckling Moraine/Elephant Moraine stranding surfaces. Because the Allan Hills Main Icefield has a large proportion of meteorites with long terrestrial ages, these concentrations of meteorites must have had catchment areas extending well inland, in contrast to the present. Where known, bedrock topography is mesa-like in form and influences ice flow directions. Ice levels at the Allan Hills may have been higher by 50–100 m in the past. Reckling Moraine and Elephant Moraine are located on a long patch of ice running westward from Reckling Peak; the ice appears to be pouring over a bedrock escarpment. (2) In North Victoria Land, ice diverges around Frontier Mountain and flows into a site behind the barrier where ablation occurs extensively. It is proposed that meteorites and rocks were dumped by ice flow at the mouth of a valley in the lee of the mountain at the site where a meltwater pond existed, in a depression produced by ablation. Later, the pond migrated headward along the valley to a point where it is today, leaving a morainal deposit with the meteorites at a higher level. (3) Between the Beardmore and Law Glaciers, ice flows sluggishly into the southwestern margin of the Walcott Névé. Northeastern sections of the Walcott are virtually barren of meteorites. The entering Plateau ice is diverted northward to flow along the base of Lewis Cliff. This flow apparently terminates in an ice tongue protruding into a vast moraine, where a very large concentration of meteorites was found on the ice. This final segment of flowing ice is called the Lewis Cliff Ice Tongue. Meteorite Moraine, a subsidiary occurrence 2 km to the northeast, is also found against morainal deposits. The origin of the moraines and the history of meteorite concentration at this site is the subject of some debate. (4) The Transantarctic Mountains are submerged along one segment many hundreds of km in length by ice flowing off the Polar Plateau. The Thiel Mountains, Pecora Escarpment and Patuxent Range are the only surface indications of the underlying mountains along this interval, and meteorite stranding surfaces are found at each of these sites. Little is yet known about ice dynamics at these sites. (5) The immense Yamato Mountains meteorite stranding surface covers an area of about 4000 km². So far, most meteorites have been recovered in the upper reaches of this blue ice field, where ice flow is slowed by outlying subice barriers of the Yamato Mountains. Individual massifs in this range extend northward over 50 km, and the Yamato Meteorite Icefield loses 1100 m in elevation over this distance. (6) The Sør Rondane Mountains form a barrier to ice flow off the Polar Plateau. The major meteorite stranding surface associated with this barrier is the Nansenisen Icefield, a large ablation area about 50 km upstream of the mountains. The existence of a meteorite stranding surface at this site has not been explained so far. Most meteorite stranding surfaces have been functioning for a long time. They are sites where net ablation of the surface is occurring; the ice at these sites is stagnant or flowing only slowly, and the numbers of meteorites with great terrestrial ages decrease exponentially. Concentration mechanisms operating at these sites involve ablation, direct infall, time, low temperatures, moderate weathering and wind ablation. Detrimental to concentration are ice flow out of the area and extreme weathering. In spite of the fact that the Antarctic Ice Sheet is thought to be over 10 Ma old, we do not find stranding surfaces with meteorites having greater terrestrial ages than 1 Ma. This suggests that stranding surfaces are transient features, affected on a continental scale by possible extreme warming during late Pliocene and on a smaller scale by regional changes that produce differential effects between icefields. The latter effect is suggested by differences in the average terrestrial age of meteorites at different stranding surfaces. In either case, these sites seem to appear as a result of thinning near the edges of the ice sheet, and stratigraphic sequences may be exposed in the ice at stranding surfaces. We review five models for the production of meteorite stranding surfaces: (1) simple deflation of the ice sheet, in which ablation removes great thicknesses of overlying ice, exposing the contained meteorites while allowing direct falls to accumulate, (2) simple accumulation of direct falls on a bare ice surface that is not deflating, (3) ablation of ice trapped against a barrier, in which meteorites accumulate by direct infall while inflowing ice contributes meteorites by ablation discovery, (4) deceleration of ice by a subice barrier, which allows ablation discovery of meteorites in incoming ice and accumulation of other meteorites on the surface by direct infall and (5) stagnation of ice by encounter with an ice mass able to produce an opposing flow vector, in which ablation discovery and direct infall accumulation processes operate to build the meteorite concentration.     

Verteilung ausgewählter toxischer Spurenelemente im Sediment des Breitlingsees bei Brandenburg

Distribution of Selected Toxic Trace Elements in the Sediment of Lake Breitling near Brandenburg. Considerable enrichments of several heavy metals in relation to the local geological background were found in the surface sediments of Lake Breitling (Havel lake system) (Zn: 50-fold, Cd: 25-fold, Cu: 14-fold, Pb: 13-fold), whereas Be, Co and V are remarkably unchanged if the increased clay mineral content in the more recent sediments is considered. – The heavy metal distribution patterns indicate a high percentage of atmospheric input of these elements, and according to geochemical profiles heavy metal deposition has been constant on a high level for years. – Especially the most enriched Zn which was found to some extent NH₄Ac-exchangeable deserves ecotoxic attention.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.     

Review: The state-of-art of sparse channel models and their applicability to performance assessment of radioactive waste repositories in fractured crystalline formations

Laboratory and field experiments done on fractured rock show that flow and solute transport often occur along flow channels. ‘Sparse channels’ refers to the case where these channels are characterised by flow in long flow paths separated from each other by large spacings relative to the size of flow domain. A literature study is presented that brings together information useful to assess whether a sparse-channel network concept is an appropriate representation of the flow system in tight fractured rock of low transmissivity, such as that around a nuclear waste repository in deep crystalline rocks. A number of observations are made in this review. First, conventional fracture network models may lead to inaccurate results for flow and solute transport in tight fractured rocks. Secondly, a flow dimension of 1, as determined by the analysis of pressure data in well testing, may be indicative of channelised flow, but such interpretation is not unique or definitive. Thirdly, in sparse channels, the percolation may be more influenced by the fracture shape than the fracture size and orientation but further studies are needed. Fourthly, the migration of radionuclides from a waste canister in a repository to the biosphere may be strongly influenced by the type of model used (e.g. discrete fracture network, channel model). Fifthly, the determination of appropriateness of representing an in situ flow system by a sparse-channel network model needs parameters usually neglected in site characterisation, such as the density of channels or fracture intersections.     

How appropriate is the Thiem equation for describing groundwater flow to actual wells?

The Thiem equation of radial groundwater flow to a well is more than 100 years old and is still commonly used. Here, deviations caused by some of its simplifications are quantified by comparing the analytical to a numerical model that allows the implementation of more complex geometries. The assumption of horizontal flow in the Thiem equation, which necessitates uniform inflow over the entire screen length of the fully penetrating well, was found to cause deviations from actual pumping wells where the pump is placed above the screen, resulting in non-uniform inflow and additional drawdown. The same applies to partially penetrating wells, where inflow peaks and additional drawdown occur, especially when the well is screened in the lower part of the aquifer. The use of the Thiem equation in the near-field of a well should thus be restricted to situations where the screen inflow is relatively uniformly distributed, e.g. when it covers large portions of the aquifer thickness. The presence of a gravel pack and a background gradient, on the other hand, are of limited importance.