Palaeoenvironmental significance of rounded pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Basin: oxygen‐deficient atmosphere or hydrothermal alteration?

Petrographic and sulphur isotope studies support the long‐held contention that rounded grains of pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Supergroup originated as placer grains. The grains are concentrated at sites where detrital heavy minerals are abundant within quartz‐pebble conglomerates and quartzose sandstones. Depositional sites with abundant pyrite are: (1) within the matrix of bar‐type, clast‐supported conglomerates; (2) on scoured or winnowed surfaces; and (3) on stratification planes. The grains are internally compact or porous, with truncation of internal structure at outer margins indicating fragmentation and rounding of pyritic source‐rocks during erosion and sediment transport. A large range in textures reflects source‐rock lithologies, with known varieties linked to sedimentary‐hosted diagenetic pyrite, volcanic‐hosted massive sulphide deposits and hydrothermal pyrite. Laser ablation sulphur isotope analysis of pyrite reveals a broader range in δ³⁴S values (? 5·3 to + 6·7‰) than that of previously reported conventional bulk‐grain analyses (? 1 to + 4‰). Rounded pyrite from the Steyn Reef has significant variation in δ³⁴S values (? 4·7 to + 6·7‰) that establishes heterogeneous sulphur compositions, with even adjacent grains having diverse isotopic signatures. The heterogeneity supports a placer origin for rounded pyrite. Euhedral pyrite and pyrite overgrowths which are undoubtedly authigenic have restricted δ³⁴S values (? 0·5 to + 2·5‰), are chemically distinct from rounded pyrite and are probably the products of metamorphism or hydrothermal alteration. The placer origin of rounded pyrite indicates that pyrite was a stable heavy mineral during erosion and transport in the early atmosphere. Its distribution in three sequences (Witwatersrand Supergroup, Ventersdorp Contact Reef and Black Reef), and in other sequences not linked to Witwatersrand‐type Au‐U ore deposits, implies deposition of redox‐sensitive detrital heavy minerals during the Late Archaean. Consequently, rounded grains of detrital pyrite are strong indicators of an oxygen‐poor atmosphere. While not confirming a placer origin for gold in Witwatersrand Au‐U ore deposits, the palaeoenvironmental significance of rounded pyrite negates its link to hydrothermal mineralization.     

Evidence for pole switching in the magnetic cataclysmic variable BY Camelopardalis

An analysis of X-ray and optical light curves of the magnetic cataclysmic variable (MCV) BY Cam is presented. This system is one of three MCVs in which the spin period of the white dwarf and the binary orbital period differ by ∼1 per cent. As such these 'BY Cam' stars are important objects with which to probe the field structure of the magnetic white dwarf and ultimately the nature of synchronization of AM Her binaries. We confirm asynchronous rotation of the magnetic white dwarf with respect to the binary. We find evidence that the accretion stream accretes directly on to the white dwarf as in AM Her systems, but further, the stream impacts on to different magnetic poles over the course of the beat period. We present evidence that the optical and hard X-ray light curves modulate in phase, but together they are out of phase with the soft X-ray light curve. We confirm the spin down of the white dwarf which is expected to lead to the synchronization of the spin and orbital periods of BY Cam.     

Variation in the Sizes of Chthamalid ­Barnacle Post-Settlement Cyprids on European Shores

Abstract. As part of a wider study on the settlement and recruitment of Chthamalus spp. in Europe, this study investigated whether chthamalid cyprids can be separated by length on a European scale. Variation in cyprid length with latitude and temporal variation at selected localities were also examined. The lengths of cyprids collected between 1996 – 1999 on nine rocky shores in Europe are reported. Elminius modestus cyprids were found only at Roscoff, NW France and could be distinguished due to their carapace shape and length. They showed a unimodal length distribution, measuring between 450 and 625 µm, with no variation in length between the two sampling dates (1997 and 1998). Based on carapace shape and length, the remaining cyprids in the collections were identified as one of three chthamalid species, Chthamalus montagui, Chthamalus stellatus or Euraphia depressa. Bimodal length distributions of chthamalid cyprids were seen on some shores, while others had a single small‐sized modal group (representing C. montagui on Atlantic shores and/or E. depressa in the Mediterranean) separated from a few distinctly larger cyprids (C. stellatus). Metamorphs collected simultaneously with cyprid collections were identified as C. stellatus or C. montagui, except at Roscoff, where E. modestus were also found. In southern Portugal, where all metamorphs collected were C. montagui and adult C. montagui were the dominant barnacles, most cyprids measured between 350 and 550 µm long and this size distribution coincides with the distribution expected for C. montagui. Cyprids collected on these four more southerly Portuguese shores had the same modal length class (475 µm) and this remained constant between successive years at Luz and Albufeira, Algarve. The smallest (350 µm long) wild chthamalid cyprids found were from southern Portugal and Italy. In Spain, France and Ireland the smallest chthamalid cyprid was 425 µm long. The results from the present study support the hypothesis that on Atlantic shores cyprids of C. montagui can be separated from those of C. stellatus based on size, although there is some variation in cyprid length with latitude as well as temporal variation at selected localities.     

Field setting,mineralogy, chemistry,and genesis of arc picrites,New Georgia,Solomon Islands

The field setting, petrography, mineralogy, and geochemistry of a suite of picrite basalts and related magnesian olivine tholeiites (New Georgia arc picrites) from the New Georgia Volcanics, Kolo caldera in the active ensimatic Solomon Islands arc are presented. These lavas, with an areal extent in the order of 100² km and almost 1 km thick in places, are located close to the intersection of the Woodlark spreading zone with the Pacific plate margin. They contain abundant olivine (Fo_94-75) and diopside (Cr₂O₃ 1.1-0.4%, Al₂O₃ 1–3%), and spinels characterised by a large range in Cr/(Cr+Al) (0.85–0.46) and Mg/(Mg+ Fe⁺⁺) (0.65–0.1). The spinels are Fe⁺⁺⁺ rich, with Fe⁺⁺⁺/ (Fe⁺⁺⁺+Cr+Al) varying from 0.06 to 1.0. A discrete group of spinels with the highest Cr/(Cr+Al) (0.83–0.86) and lowest Fe⁺⁺⁺ contents are included in the most Mg-rich olivine (Fo_91–94) and both may be xenocrystal in origin.The lavas, which range between 10–28% MgO, define linear trends on oxide (element) — MgO diagrams and these trends are interpreted as olivine (0.9) clinopyroxene (0.1) control lines. For the reconstructed parent magma composition of these arc picrites, ratios involving CaO, Al₂O₃, TiO₂, Zr, V and Sc are very close to chondritic. REE patterns are slightly LREE — enriched ((La/Sm)^N 1.3–1.43) and HREE are flat. All lavas show marked enrichments in K, Rb, Sr, Ba, and LREE relative to MORB with similar MgO contents, but the TiO₂ content of the proposed parent magma is close to those of postulated primary MORB liquids. It is proposed that the arc parent magma was produced by partial melting of sub-oceanic upper mantle induced by the introduction of LILE — enriched hydrous fluids derived by dehydration and/or partial melting of subducted ocean crust and possibly minor sediments.     

The origin of biotite in Archaean meta-sediments near Yellowknife,N.W.T., Canada: A reply to E. H. Brown

Conclusion Dr. Brown's perceptive criticism has emphasised that problems of detail remain and pointed out some deficiencies of presentation in my paper. I hope these have now been rectified. I believe, however, that the above examination of the reaction in the light of his criteria has served only to substantiate its general validity.     

Metamorphic patterns in Zambia and their bearing on problems of Zambian tectonic history

Metamorphic mineral assemblages determined in thin-sections have been used to compile metamorphic maps showing the distribution of metamorphic facies and minerals in Zambia. These maps lead to the recognition of two non-parallel metamorphic belts. The Lufilian Belt curves along the southern margin of the Lufilian (structural) Arc, and the Luangwa—Kariba Belt covers the entire eastern and south-eastern borders of the country. Stratigraphic and mineralogical relationships, and radiometric data, indicate that the two belts are contemporaneous and their present major features are the result of a single tectonothermal episode which ended c. 500 m.y. ago. In particular, the Irumide fold belt is not recognisable as a metamorphic entity.     

(Re)thinking the dynamics between healthcare and place: therapeutic geographies in treatment and care practices

Although the concept of therapeutic landscapes has assisted health geographers to explore the intimate connections between well-being and place, arguably, after a decade of applications, the common interpretations and assumptions of commentators should be reviewed. Based on theoretical insights from psychoanalytic geographies and geographies of nursing, this paper makes two observations. First, that landscape has been almost exclusively interpreted in a physical sense with co-presence being a necessary condition. In turn, this assumption has led to the neglect of non-physical (imagined) places. Second, that therapeutic effects have been interpreted as experiences attained outside of clinical practices. Hence, healthcare workers and their direct treatments and care have also been neglected. To explore these omissions together, an interview survey of complementary therapists investigates the many ways in which imagined places are constructed and manipulated in therapy sessions. Arguably, beyond this example, extending the therapeutic landscape concept to both physical and non-physical features of treatments could provide fresh insights into the dynamics between healthcare and place. In disciplinary terms, the benefits are twofold. Whilst it could help develop a critical tradition in health geography, perhaps ironically, it could also provide a stronger disciplinary connection between qualitative health geography, various forms of medicine and their research traditions.     

Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine Carbonates

Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO₂ through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ¹¹B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ¹¹B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ¹¹B; and (c) to provide well‐constrained consensus δ¹¹B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.     

Characterizing uncertainties for quantifying bathymetry change between time-separated multibeam echo-sounder surveys

Changes of bathymetry derived from multibeam sonars are useful for quantifying the effects of many sedimentary, tectonic and volcanic processes, but depth changes also require an assessment of their uncertainty. Here, we outline and illustrate a simple technique that aims both to quantify uncertainties and to help reveal the spatial character of errors. An area of immobile seafloor is mapped in each survey, providing a common ‘benchmark’. Each survey dataset over the benchmark is filtered with a simple moving-averaging window and depth differences between the two surveys are collated to derive a difference histogram. The procedure is repeated using different length-scales of filtering. By plotting the variability of the differences versus the length-scale of the filter, the different effects of spatially uncorrelated and correlated noise can be deduced. The former causes variability to decrease systematically as predicted by the Central Limit Theorem, whereas the remaining variability not predicted by the Central Limit Theorem then represents the effect of spatially correlated noise. Calculations made separately for different beams can reveal whether problems are due to heave, roll, etc., which affect inner and outer beams differently. We show how the results can be applied to create a map of uncertainties, which can be used to remove insignificant data from the bathymetric change map. We illustrate the technique by characterizing changes in nearshore bed morphology over one annual cycle using data from a subtidal bay, bedrock headland and a banner sand bank in the Bristol Channel UK.