Vegetation-based bioindication of humus forms in coniferous mountain forests

Humus forms, especially the occurrence and the thickness of the horizon of humified residues(OH), provide valuable information on site conditions.In mountain forest soils, humus forms show a high spatial variability and data on their spatial patterns is often scarce. Our aim was to test the applicability of various vegetation features as proxy for OH thickness.Subalpine coniferous forests dominated by Picea abies(L.) H. Karst. and Larix decidua Mill. were studied in the Province of Trento, Italian Alps,between ca. 900 and 2200 m a.s.l. Braun-Blanquet vegetation relevés and OH thickness were recorded at152 plots. The vegetation parameters, tested for their suitability as indicators of OH thickness,encompassed mean Landolt indicator values of the herb layer(both unweighted and cover-weighted means) as well as parameters of vegetation structure(cover values of plant species groups) calculated from the relevés. To our knowledge, the predictive power of Landolt indicator values(LIVs) for humus forms had not been tested before. Correlations between OH thickness and mean LIVs were strongest for the soil reaction value, but indicator values for humus,nutrients, temperature and light were also significantly correlated with OH thickness. Generally,weighting with species cover reduced the indicator quality of mean LIVs for OH thickness. The strongest relationships between OH thickness and vegetation structure existed in the following indicators: the cover of forbs(excluding graminoids and ferns) and the cover of Ericaceae in the herb layer. Regression models predicting OH thickness based on vegetation structure had almost as much predictive power as models based on LIVs. We conclude that LIVs analysis can produce fairly reliable information regarding the thickness of the OH horizon and, thus,the humus form. If no relevé data are readily available,a field estimation of the cover values of certain easily distinguishable herb layer species groups is much faster than a vegetation survey with consecutive indicator value analysis, and might be a feasible way of quickly indicating the humus form.     

In Situ Trace Gas and Particle Measurements in the Summer Lower Stratosphere during STREAM II: Implications for O3 Production

In situ aircraft measurements of O₃, CO,HNO₃, and aerosol particles are presented,performed over the North Sea region in the summerlower stratosphere during the STREAM II campaign(Stratosphere Troposphere Experiments by AircraftMeasurements) in July 1994. Occasionally, high COconcentrations of 200-300 pbbv were measured in thelowermost stratosphere, together with relatively highHNO₃ concentrations up to 1.6 ppbv. The particlenumber concentration (at standard pressure andtemperature) between 0.018-1 m decreased acrossthe tropopause, from >1000 cm^-3 in the uppertroposphere to <500 cm^-3 in the lowermoststratosphere. Since the CO sources are found in thetroposphere, the elevated CO mixing ratios areattributed to mixing of polluted tropospheric air intothe lowermost extratropical stratosphere. Further wehave used a chemical model to illustrate that nitrogenoxide reservoir species (mainly HNO₃) determinethe availability of NO_x (=NO + NO₂) andtherefore largely control the total net O₃production in the lower kilometers of thestratosphere. Model simulations, applying additionalNO_x perturbations from aircraft, show that theO₃ production efficiency of NO_x is smallerthan previously assumed, under conditions withrelatively high HNO₃ mixing ratios, as observedduring STREAM II. The model simulations furthersuggest a relatively high O₃ productionefficiency from CO oxidation, as a result of therelatively high ambient HNO₃ and NO_xconcentrations, implying that upward transport of COrich air enhances O₃ production in the lowermoststratosphere. Analysis of the measurements and themodel calculations suggest that the lowermoststratosphere is a transition region in which thechemistry deviates from both the upper troposphere andlower stratosphere.     

Rare earth distributions in clay minerals and in the clay-sized fraction of the Lower Permian Havensville and Eskridge shales of Kansas and Oklahoma

The REE (rare earth element) content of a wide variety of clay mineral groups have been analyzed using radiochemical neutron activation and have been found to be quite variable in absolute REE content (range of ∑REE = 5.4–1732) and less variable in relative REE content (range of chondritenormalized La/Lu = 0.9–16.5). The variable REE content of the clay mineral groups is probably determined by the REE content of the source rock from which the clay mineral was derived and not from the separate minerals in the rock.The clay-sized fractions of the Havensville and Eskridge shales of Kansas and Oklahoma have similar relative REE distributions and identical negative Eu anomaly size as the composite of NAS (N. American shales), but an absolute REE content (range of ∑REE = 46–348) that may differ significantly from the composite of NAS. The clay-sized fraction of samples from any given outcrop did not vary much in absolute or relative REE content, but samples from northern Oklahoma, probably composed of continental to near-shore marine sediments, have higher absolute REE contents and higher La/Lu ratios than samples of marine deposits in Kansas (e.g. mean ∑REE in Oklahoma = 248; mean ∑REE in Kansas = 69–116). The differencess in the REE content between samples in Oklahoma and Kansas may be caused by chemical weathering processes in the source area, exchange reactions in the environment of deposition, or diagenesis and do not appear to be a result of the different clay minerals.Most samples have Eu anomalies relative to chondrites (range of Eu/Sm ratios of samples = 0.035–1.17; chondrites = 0.35). Some montmorillonites and kaolinites are anomalous in Eu relative to the NAS (range of Eu/Sm ratios of samples = 0.056–0.21; NAS = 0.22). These anomalies may be inherited from source rocks with Eu anomalies originally produced by igneous processes, or they may be produced by chemical weathering processes in the source area.     

Variability in dissolved organic matter fluorescence and reduced sulfur concentration in coastal marine and estuarine environments

Fluorescence characterization of dissolved organic matter (DOM) and measurements of Cr-reducible sulfide (CRS) are presented for 72 coastal marine and estuarine water samples obtained from the USA and Canada. Each sample is identified according to source: terrigenous, autochthonous, wastewater or mixed. Fluorescence data are resolved into contributions from humic, fulvic, tyrosine and tryptophan-like fluorophores. Humic and fulvic-like fluorophores correlate well with dissolved organic C (DOC) (r² = 0.73 and 0.71, respectively) but tyrosine and tryptophan-like fluorophores show no correlation with DOC. Quality factors are identified by normalization of fluorescence contributions to DOC. Humic and fulvic components show no statistical differences between sources but the amino acid-like fluorescence quality factors show significant variations between source, with highest values for autochthonous sources (0.07 ± 0.01 arbitrary fluorescence units per mg of C) versus low values (0.015 ± 0.005) for terrigenous source waters. CRS concentrations are highly variable from 0.07 ± 0.01 to 7703 ± 98 nM and do no correlate with DOC except when terrigenous source waters (n = 13) are separated out from the total sample set (r² = 0.55). There is an open question in the literature; does DOC source matter in terms of protective effects towards metal toxicity? Here is shown that DOC molecular-level quality does vary and that this variation is mostly in terms of the contributions of amino acids to total fluorescence.     

San Quirce (Palencia,Spain): new chronologies for the Lower to Middle Palaeolithic transition of south-west Europe

San Quirce is an open-air archaeological site situated on a fluvial terrace in the Duero basin (Palencia, northern Iberia). This paper presents new and consistent chronologies obtained for the sedimentary sequence using post-infrared infrared stimulated luminescence (pIR-IR) dating of K-feldspars and single-grain thermally transferred optically stimulated luminescence (TT-OSL) dating of quartz. The new dating results indicate that the sequence is older than ~200 000 years and place San Quirce Level III within marine isotope stages (MIS) 8 and 7, between 274 ± 13 ka and 238 ± 13 ka. The main lithic assemblage at San Quirce comes from Level III. The predominant tool types found in this level are hammerstones, manuports and flakes, with a small proportion of cores and a significant presence of denticulates. Adaptation to local environmental conditions resulted in distinctive cultural habits, which were embedded in the cultural tradition of hominins occupying the site during the final third of the Middle Pleistocene. San Quirce preserves a simple cultural tradition that was employed by local hominins to engage in a diverse array of activities, and highlights the cultural diversity that appears to have been a characteristic feature of the Lower to Middle Palaeolithic transition 300–200 ka.     

On the date of construction of Lechaion,western harbor of ancient Corinth,Greece

Lechaion, the western harbor of ancient Corinth, was an artificial harbor excavated in a marshy area and connected to the open sea through a channel with revetment walls. It was probably the most important harbor of this type in antiquity, and one of the most important harbors in Greece for more than one millennium. Yet, the date of construction of this harbor is a matter of debate; 600 B.C., ca. 44 B.C., and A.D. 350 are the most probable dates. Geomorphological and biological investigations, in combination with AMS radiocarbon dating of exposed marine shells found in the walls of the channel leading to the inner basin of the harbor indicate that the channel was open to the sea before a seismic land uplift that probably occurred sometime in the fifth to third century B.C. These data indicate that the construction of the harbor began in ca. 600 B.C., the period of Corinthian expansion to the Ionian Sea and southern Italy. © 1996 John Wiley & Sons, Inc.