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531.
U-Pb isotopic analyses are reported for zircons of nine igneous rocks and high grade metamorphic paragneisses from the Silvretta nappe and the Gotthard massif, Switzerland.Following Silver and Deutsch (1961) the zircon populations isolated from six of these rocks were devided into series of size fractions with varying uranium content. An extensive Rb-Sr investigation has been made on some of these rock samples and their minerals (Arnold and Jäger, 1965: Gotthard massif, Grauert, 1966: Silvretta nappe). Rb-Sr measurements on biotites and mineral isochrons of individual gneiss samples yield ages which indicate the end of the Alpine and the Hercynian (=Variscan) metamorphism. Other measurements give mixed ages between these events. The U-Pb investigation of zircons, however, yield criteria for an even older event, 400 to 500 m.y. ago.The isotopic relationship indicates a strong episodic disturbance of the U-Pb systems in the paragneiss zircons with high losses of radiogenic lead. In a Concordia diagram the best fit lines to the data points of the paragneiss zircons from the Gotthard massif as well as from the Silvretta nappe trend both toward the data points of the orthogneiss zircons and intersect the Concordia at approximately 440 m.y. Rb-Sr analyses of the granitic orthogneisses from the Silvretta nappe (Flüela granite gneisses) gave a well defined isochron of 428 m.y. (=1.47×10–11y–1). This value agrees rather well with the age given by the intersection of the best fit lines to the paragneiss zircons with the Concordia.Considering the geological and petrographical observations we interpret this disturbance of the U-Pb systems in the paragneiss zircons as the result of an influence of regional high grade metamorphism and anatectic melting together with the formation of igneous rocks during the Caledonian petrogenesis.In the Silvretta the uranium rich zircons from the Flüela granite gneisses reflect a disturbance and lead loss probably during the Hercynian metamorphism. In the Gotthardmassif the zircons from a quartz diorite and an ultrabasic inclusion in this diorite, however, show no or only a slight influence of the later Hercynian and Alpine metamorphisms. The apparent ages of the zircons in the ultrabasic inclusion are nearly concordant (Pb206/U238: 448 m.y., Pb207/ U235: 452 m.y., Pb207/Pb206: 472 m.y.). There is in all orthogneiss zircons some evidence of older inhereted U-Pb components besides new zircon growth.If we assume an episodic model for the lead loss and a disturbance 450 m.y. ago the minimum primary age of the detrital zircon components in the paragneisses would be 1500 m.y.

Der eine von uns (B.G.) möchte den Herren Prof. Dr. M. Grünenfelder und Prof. Dr. P. Signer vom Labor für Geochronologie des Instituts für Kristallographie und Petrographie der Eidgenössischen Technischen Hochschule Zürich seinen Dank für ihr Interesse und die großzügige Unterstützung bei der Durchführung dieser Arbeit aussprechen. Herr Prof. Dr. M. Grünenfelder und Herr Dr. R. Pidgeon haben ihn in die Arbeitsweise der U-Pb-Isotopenanalyse eingeführt. Herr Dr. V. Köppel sowie alle oben genannten Herren haben durch ihre wertvollen Ratschläge und kritischen Diskussionen diese Arbeit wesentlich gefördert. Ihnen und auch allen anderen Angehörigen des Labors für Geochronologie, die zum Gelingen der Arbeit beigetragen haben, sei herzlichst gedankt.

Herr Dr. L. Rybach hat in dankenswerter Weise von vier Zirkonfraktionen die Urankonzentration durch Gamma-Spektrometrie bestimmt.

Wir beide möchten Frau Prof. Dr. E. Jäger und Herrn Prof. Dr. E. Niggli vom Mineralogisch-Petrographischen Institut der Universität Bern für ihr wohlwollendes Interesse und die kritische Durchsicht des Manuskriptes danken.  相似文献   
532.
We have conducted detailed studies of the behavior of carbon on the surfaces of MgO and olivine single crystals using various surface analytical techniques: viz. secondary ion mass spectrometry (SIMS), Auger electron spectrometry (AES) and X-ray photoelectron spectrometry (XPS). In order to distinguish without ambiguity the effect of diffusion of carbon from the bulk to the surface and the effect of surface contamination by carbon-containing species, the experiments were conducted in ultrahigh vacuum, i.e. 10?11–10?9 torr. In addition to MgO and olivine single crystals, we have conducted the same studies on TiO2, MnO, SiO2 and Ta2O5 which serve as blank samples. The MgO and olivine samples were also intentionally implanted with known doses of carbon and the mobility of this particular carbon was investigated in detail. Our results show that the bulk carbon content in MgO is around 40 wt. ppm, considerably lower than the quantities quoted by Freund and co-workers in the past. We also show that the carbon in both MgO and olivine does not display any rapid diffusion behaviour leading to surface segreation in the temperature range 78–723 K, in contrast to the previous findings of Freund and co-workers.  相似文献   
533.
Quartz, SiO2, a pure mineral with tight crystal structure, is widespread in rocks and soil. Cosmic rays produce10Be (t 1/2=1·5×106, yr) and26Al (t 1/2=7·05×105 yr) in quartz exposed at or near the earth’s surface. The use of accelerator mass spectrometry permits measurement of these nuclides in samples exposed at sea level for typical periods.In situ production makes interpretation relatively straightforward. Potential applications include age determination, measurement of erosion and deposition rates, and use as a tracer for continental weathering processes.  相似文献   
534.
Außerordentlich große Wassermengen werden bei der Entwässerung der Tagebaue gehoben, aber bisher nur zu einem geringen Teil unmittelbar für die Wasserversorgung genutzt. Die planmäßige und abgestimmte Nutzung der Naturressourcen verlangt die Prüfung der Möglichkeiten zur Nutzbarmachung zumindest eines Teiles dieser Wässer für die Trinkwasserversorgung besonders in Ballungsgebieten. Auf Grund der besonderen geologischen Gegebenheiten im Raum nördlich Leipzigs bestehen günstige Voraussetzungen. Maßnahmen zum Schutze und der Nutzung dieser Wässer sind eingeleitet. Bauaufwand und technische Ausrüstungen für die Wasserversorgung sind den Besonderheiten der Tagebauwasserbereitstellung anzupassen.  相似文献   
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As part of an integrated study of the hydrology, meltwater quality and dynamics of the Haut Glacier d'Arolla, Switzerland, the glacier's drainage network structure was determined from patterns of dye recovery in 342 injection experiments conducted from 47 moulins distributed widely across the glacier. This structure was compared with theoretical predictions based upon reconstructed patterns of water flow governed by (a) the subglacial hydraulic potential surface, and (b) the subglacial bedrock surface. These reconstructions were based on measurements of ice surface and bedrock topography obtained by a combination of ground survey and radio-echo sounding techniques. The two reconstructions simulate the drainage system structures expected for (a) closed channels, in which water is pressurized by the overlying ice, and (b) gravity-driven, open-channel flow. The closed-channel model provides the best fit to the observed structure, even though theoretical calculations suggest that, under summer discharge conditions, open-channel flow may be widespread beneath the glacier. Possible reasons for this apparent discrepancy are discussed.  相似文献   
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