The pre-Colombian footprint on terrestrial nutrient cycling in Costa Rica: insights from phosphorus in a lake sediment record

The impact of pre-Columbian subsistence agriculture on soil nutrient cycling in the American tropics is poorly quantified. Paleolimnological research can address this deficit by documenting the temporal evolution of nutrient cycling in lake watersheds over different time scales. Here we describe our use of a chemical sequential extraction technique adapted from soil fertility research to discern geochemical fractions of phosphorus (P) in lake sediments that serve as proxies for landscape-scale soil nutrient status. These P fractions are mineral P (the original lithic source of bioavailable P), occluded P (mainly bound to soil oxides), and organic P (remains of organic matter production by plants). We applied the P fractionation technique to a lake sediment core from a small lake in southern Costa Rica, Laguna Zoncho. Prior analyses of microfossils and stable carbon isotopes in this core documented an approximately 3,000 year history of human occupation and agricultural activity in the Zoncho watershed, and shifts in diatom communities in the lake associated both with human impacts and with climate-driven changes in lake level. Our P analyses revealed relatively constant P geochemistry during the first approximately 2,500 years of the record, when other sedimentary proxies reveal forest clearance and maize agriculture of varying intensity. However, the period from approximately 500 to 100 years BP is marked by a drastic shift toward a P geochemistry dominated by occluded forms, with a concomitant decrease in the relative content of both the organic and mineral P forms. This interval coincides with post-Conquest depopulation and forest regeneration at the site, and with an apparent deepening of the lake caused by a shift toward a wetter climate. The dominance of the occluded P fraction during this interval is the opposite of the trend expected with such a climate shift, implicating human dynamics as the principal driver of the changes in soil nutrient status indicated by the P fractions in the Zoncho core. We propose that the entire P geochemical record is dominated by human-induced alteration of the soil nutrient cycles via agriculture and occupation, and that the only interval that reveals the “natural” nutrient status in the region is the short interval when the site is abandoned and surrounding forests regrow. These results for Laguna Zoncho reveal the close connection between even relatively low-technology human activities and soil nutrient status.     

Nutrient dynamics at the sediment-water interface in a Mediterranean lagoon (Thau, France): influence of biodeposition by shellfish farming activities

The Thau Lagoon, a French Mediterranean shallow lagoon, is a site where extensive shellfish farming occurs. The aim of the present work is to evaluate the role of this activity on nutrient exchange at the sediment-water interface in relation to organic matter (OM) sedimentation and degradation. Two stations inside (C5) and outside (C4) of the shellfish farming areas were sampled at three seasons. Porewater chemistry surveys and calculated diffusive fluxes were used to evaluate the trophic status of the Thau lagoon. Quantitative (Particulate Organic Carbon) as well as qualitative OM (Hydrogen Index, Carbohydrates) analyses were performed on sediments to assess OM characteristics. Results emphasized that surficial sediments at C5 are always more enriched in OM. Porewater nutrient concentrations are 10-20 times higher at C5 than at C4. In June 2003, the porewater profiles exhibit a sharp gradient at the bottom waters, indicating a hypereutrophic status, leading to an anoxic crisis.     

Resuspension of urban soils as a persistent source of lead poisoning in children: A review and new directions

Urban soils act as the repository for a number of environmental burdens, including Pb. Significant attention has been devoted to reducing Pb burdens to children with outstanding success, but the fact that blood Pb levels above 10  μg/dL are disproportionately found in children living in many USA cities (15–20% in some cities compared to a national average of less than 2%) indicates that not all of the sources have been eliminated. Although the health risk of fine particulates has begun to raise concerns in cities, little attention has been paid to Pb associated with these particulates and the potential role of this pathway for continued Pb burdens of urban youth. This review summarizes recent work on particulate resuspension and the role of resuspension of Pb-enriched urban soils as a continued source of bio-available Pb both outside and inside homes, then presents recent efforts to model Pb burdens to children based on the atmospheric parameters that drive particulate resuspension. A strong seasonal relationship is found between atmospheric particulate loading and blood Pb levels in children, and new particulate loading models are presented for a range of US cities involved in the Interagency Monitoring of Protected Visual Environments (IMPROVE) program. These seasonal particulate loading models have implications for a number of respiratory health impacts, but can also be used to calculate seasonal patterns in bio-available Pb redistribution onto contact surfaces (the primary pathway for ingestion-related uptake in toddlers) and assist clinicians in interpreting time-specific blood Pb tests.     

Post-Last Glacial Maximum evolution of a “fjord-type” lake based on high-resolution seismic data: the Lago Roca/Acigami (southern Tierra del Fuego,Argentina/Chile)

Lago Roca/Acigami is a “fjord-type” lake located in the southernmost part of South America, in the proximity of the Beagle Channel. A high-resolution seismic survey was carried out to analyse the seismic stratigraphy of the lake and to shed some light on the post-Last Glacial Maximum history of the area. Six seismic units were recognised, and their nature and depositional context were interpreted using seismic stratigraphy and acoustic facies analysis. A buried large ridge was identified within the glacial unit (SU1), interpreted as a frontal moraine that indicates a stabilisation phase. After retreat of the glacier from the basin, the trough was flooded by meltwater and a lake developed (SU2). The seismic facies, from bottom to top, depict a transition from ice-contact (SU2; SU3) to ice-distal proglacial conditions (SU4). A thick draping unit (SU5) marks a marine transgressive event and the instauration of a fjord environment in the basin. The marine transgression was a rapid event preceded by a fall in the lake level that caused an erosional unconformity. During the fjord phase the sedimentation remained controlled by meltwater discharge. Sea level fall, and subsequent disconnection from the Beagle Channel was accompanied by a progradation of the glaciofluvial deltaic sediments and the occurrence of several mass-wasting deposits (SU6). © 2019 John Wiley & Sons, Ltd.     

Fluid-driven low-grade metamorphism in polydeformed rocks of Avalonia (Arisaig Group, Nova Scotia, Canada)

The Lower Silurian??Lower Devonian Arisaig Group (Antigonish Highlands) in the Canadian Appalachians is a sequence of shallow marine strata deposited after the accretion of Avalonia to Baltica during the closure of the Iapetus Ocean. Deformation of the strata is widely attributed to the Devonian Acadian orogeny and produced shallowly plunging regional folds and a cleavage of varying penetrativity. Phyllosilicate minerals from the finest-grained rocks exhibit very low-grade (diagenetic-anchizone) metamorphic conditions. X-ray diffraction study reveals that the sampled rocks contain quartz, K-white mica, chlorite, and feldspars; illite?Csmectite and chlorite?Csmectite mixed-layers are common but Na?CK mica and kaolinite occur only in some samples. The identification of illite?Csmectite mixed-layers in diagenetic samples, with Kübler Index >0.50 ??°2?? and the highly heterogeneous b-cell dimension of the K-white micas are in agreement with the variable chemical composition of dioctahedral micas, which present low illitic substitution and variable phengitic content. The spatial variation in the above crystal-chemical parameters was plotted along a NW?CSE composite cross section across the regional folds. No correlation was found between the metamorphic conditions and either the stratigraphic depth or the strain values measured by phyllosilicates orientation analyses, as a function of the penetrativity of the cleavage. However, the metamorphic grade generally increases towards the Hollow Fault, and is highest in samples located within a 1?km corridor from the fault surface. Incipient cleavage is observed in the anchizonal samples located in the vicinity of the Hollow Fault and in some of the diagenetic samples, indicating cleavage development under low temperatures (<200?oC). These relationships, together with regional syntheses, suggest low-grade metamorphism post-dated regional folding and was coeval with Late Carboniferous dextral movement along the Hollow Fault. Fluid circulation associated with movement along this major fault may be the driving mechanism for the increasing metamorphism towards it.     

Trace metal behaviour in riverine sediments: Role of organic matter and sulfides

Three sediment cores were collected in the Scheldt, Lys and Spiere canals, which drain a highly populated and industrialized area in Western Europe. The speciation and the distribution of trace metals in pore waters and sediment particles were assessed through a combination of computational and experimental techniques. The concentrations of dissolved major and trace elements (anions, cations, sulfides, dissolved organic C, Cd, Co, Fe, Mn, Ni, Pb and Zn) were used to calculate the thermodynamic equilibrium speciation in pore waters and to evaluate the saturation of minerals (Visual Minteq software). A sequential extraction procedure was applied on anoxic sediment particles in order to assess the main host phases of trace elements. Manganese was the most labile metal in pore waters and was mainly associated with carbonates in particles. In contrast, a weak affinity of Cd, Co, Ni, Pb and Zn with carbonates was established because: (1) a systematic under-saturation was noticed in pore waters and (2) less than 10% of these elements were extracted in the exchangeable and carbonate sedimentary fraction. In the studied anoxic sediments, the mobility and the lability of trace metals, apart from Mn, seemed to be controlled through the competition between sulfidic and organic ligands. In particular, the necessity of taking into account organic matter in the modelling of thermodynamic equilibrium was demonstrated for Cd, Ni, Zn and Pb, the latter element exhibiting the strongest affinity with humic substances. Consequently, dissolved organic matter could favour the stabilization of trace metals in the liquid phase. Conversely, sulfide minerals played a key role in the scavenging of trace metals in sediment particles. Finally, similar trace metal lability rankings were obtained for the liquid and solid phases.     

An Innovative Post Grouting Technique for Soil Nails

This study presents an innovative technique of executing soil nails called sectorized post grouting (SPG). The most utilized technique of soil nail grouting is gravity grouting, with the literature reporting advances in pressurized grouting. Although obtaining higher pullout resistance of soil nails, pressurized grouting, mostly done in single-stage grouting, does not compensate for exudation and its use in higher nail lengths is difficult. Thus, a technique has been developed that compensates for exudation, with easier application in lengthier nails. The technique was qualitatively assessed to evaluate its surface roughness and later applied in seven real soil nailing works, where it could be quantitatively assessed. The results show that sectorized post-grouted nails obtained greater pullout resistances than gravity grouted and single-stage grouted nails. Although similar improvement was found in tube-à-manchette (TAM) grouted nails, this method presents lower economic efficiency than sectorized post grouting. The pullout resistance results obtained in this study can be utilized in future soil nailing works executed utilizing SPG.

     

Aspartic acid racemization in teeth from Ketef Hinnom,a late Holocene burial cave in Jerusalem: Evidence for reuse

The Ketef Hinnom tombs, lying just outside the walls of the old city of Jerusalem, were carved out of bedrock during the 7th–5th century B.C. Several artefacts dating to the Late Hellenistic Period (ca. 100 B.C.) have also been found within the tombs. Aspartic acid (Asp) racemization in 31 samples of human tooth dentine from these tombs was analyzed in order to evaluate the possible reuse of the tombs during this later period. A range of D/L Asp values was found: a group with values averaging 0.062 and another group averaging 0.043. These D/L values are close to those expected for the two archeological age groups as calculated from (1) the kinetics of Asp racemization as established from experimental studies at higher temperatures and in vivo racemization rates, and (2) the effective annual temperature in the tombs, as measured using the Pallman method. These results thus support the later reuse of the tombs for burials. Several factors contribute to the accuracy of Asp racemization dating, including the age of the individual at death, uncertainties concerning Asp racemization kinetics, and effects of temperature history. © 1999 John Wiley & Sons, Inc.     

Turbulent Pressure and Velocity Perturbations Induced by Gentle Hills Covered with Sparse and Dense Canopies

How the spatial perturbations of the first and second moments of the velocity and pressure fields differ for flow over a train of gentle hills covered by either sparse or dense vegetation is explored using large-eddy simulation (LES). Two simulations are investigated where the canopy is composed of uniformly arrayed rods each with a height that is comparable to the hill height. In the first simulation, the rod density is chosen so that much of the momentum is absorbed within the canopy volume yet the canopy is not dense enough to induce separation on the lee side of the hill. In the second simulation, the rod density is large enough to induce recirculation inside the canopy on the lee side of the hill. For this separating flow case, zones of intense shear stress originating near the canopy-atmosphere interface persist all the way up to the middle layer, ‘contaminating’ much of the middle and outer layers with shear stress gradients. The implications of these persistent shear-stress gradients on rapid distortion theory and phase relationships between higher order velocity statistics and hill-induced mean velocity perturbations (Δu) are discussed. Within the inner layer, these intense shear zones improve predictions of the spatial perturbation by K-theory, especially for the phase relationships between the shear stress (~ ?Δu/?z) and the velocity variances, where z is the height. For the upper canopy layers, wake production increases with increasing leaf area density resulting in a vertical velocity variance more in phase with Δu than with ?Δu/?z. However, background turbulence and inactive eddies may have dampened this effect for the longitudinal velocity variance. The increase in leaf area density does not significantly affect the phase relationship between mean surface pressure and topography for the two simulations, though the LES results here confirm earlier findings that the minimum mean pressure shifts downstream from the hill crest. The increase in leaf area density and associated flow separation simply stretches this difference further downstream. This shift increases the pressure drag, the dominant term in the overall drag on the hill surface, by some 15%. With regards to the normalized pressure variance, increasing leaf area density increases ${\sigma_p/u_{*}^{2}}$ near the canopy top, where u _* is the longitudinally averaged friction velocity at the canopy top and σ _p is the standard deviation of the pressure fluctuations. This increase is shown to be consistent with a primitive scaling argument on the leading term describing the mean-flow turbulent interaction. This scaling argument also predicts the spatial variations in σ _p above the canopy reasonably well for both simulations, but not inside the canopy.     

Regional crop water use assessment using Landsat-derived evapotranspiration

Reliable information on water use and availability at basin and field scales are important to ensure the optimized constructive uses of available water resources. This study was conducted with the specific objective to estimate Landsat-based actual evapotranspiration (ETa) using the Operational Simplified Surface Energy Balance (SSEBop) model across the state of South Dakota (SD), USA for the 1986–2018 (33-year) period. Validated ETa estimations (r² = 0.91, PBIAS = −4%, and %RMSE = 11.8%) were further used to understand the crop water-use characteristics and existing historic mono-directional (increasing/decreasing) trends over the eastern (ESD) and western (WSD) regions of SD. The crop water-use characteristics indicated that the annual cropland water uses across the ESD and WSD were more or less met by the precipitation amounts in the area. The ample water supply and distribution have led to high rainfed and low percentage of irrigated cropland (~2.5%) in the state. The WSD faced greater crop-water use reductions than the ESD during drought periods. The landscape ETa responses across the state were found to be more sensitive than precipitation for the drought impact assessments. The Mann Kendall trend analysis revealed the absence of a significant trend (p > 0.05) in annual ETa at a regional scale due to the varying weather conditions in the state. However, about 12% and 9% cropland areas in the ESD and WSD, respectively, revealed a significant mono-directional trend at pixel scale ETa. Most of the pixels under significant trend showed an increasing trend that can be explained by the shift in agricultural practices, increased irrigated cropland area, higher productions, moisture regime shifts, and decreased risk of farming in the dry areas. The decreasing trend pixels were clustered in mid-eastern SD and could be the result of dynamic conversion of wetlands to croplands and decreased irrigation practices in the region. This study also demonstrates the tremendous potential and robustness of the SSEBop model, Landsat imagery, and remote sensing-based ETa modelling approaches in estimating consistent spatially distributed evapotranspiration.