Methane stocks in tropical hydropower reservoirs as a potential energy source

Several studies over the last decade have shown that tropical reservoirs may constitute an appreciable source of methane (CH₄) to the atmosphere. Here, we show that the use of low-cost, innovative mitigation and recovery strategies is able not only to reduce these emissions, but also to transform existing biogenic methane stocks into a renewable energy source. Recovered gas may be pumped to large consuming centers or stored locally and burned by gas turbines to generate electricity during high-demand periods, or even purified for transport applications. Our analysis shows that the use of biogenic methane may increase considerably the energy supply in countries, like Brazil, which possess large tropical reservoirs.     

Estimating the redshift distribution of photometric galaxy samples – II. Applications and tests of a new method

In Lima et al. we presented a new method for estimating the redshift distribution,   N ( z )  , of a photometric galaxy sample, using photometric observables and weighted sampling from a spectroscopic subsample of the data. In this paper, we extend this method and explore various applications of it, using both simulations and real data from the Sloan Digital Sky Survey (SDSS). In addition to estimating the redshift distribution for an entire sample, the weighting method enables accurate estimates of the redshift probability distribution,   p ( z )  , for each galaxy in a photometric sample. Use of   p ( z )  in cosmological analyses can substantially reduce biases associated with traditional photometric redshifts, in which a single redshift estimate is associated with each galaxy. The weighting procedure also naturally indicates which galaxies in the photometric sample are expected to have accurate redshift estimates, namely those that lie in regions of photometric-observable space that are well sampled by the spectroscopic subsample. In addition to providing a method that has some advantages over standard photo- z estimates, the weights method can also be used in conjunction with photo- z estimates e.g. by providing improved estimation of   N ( z )  via deconvolution of   N ( z _phot)  and improved estimates of photo- z scatter and bias. We present a publicly available   p ( z )  catalogue for ∼78 million SDSS DR7 galaxies.     

The Remote Equatorial Nighttime Observatory of Ionospheric Regions Project and the International Heliospherical Year

We describe a new suite of instruments planned for deployment to Cape Verde as part of the International Heliospherical Year. The Remote Equatorial Nighttime Observatory of Ionospheric Regions (RENOIR) project consists of a bistatic Fabry–Perot interferometer system, an all-sky imaging system, a dual-frequency Global Positioning System (GPS) receiver, and an array of single-frequency GPS scintillation monitors. This instrumentation will allow for studying the low-latitude thermosphere/ionosphere (TI) system in great detail. Investigations to be conducted using this instrumentation while in Cape Verde include studying equatorial irregularity processes, the effects of neutral winds and gravity waves on irregularity development, the midnight temperature maximum, and ion-neutral coupling in the nighttime TI system. Initial observations from the RENOIR instrumentation during pre-deployment testing at the Urbana Atmospheric Observatory are presented, as is the deployment scenario for the project in Cape Verde.     

Trace elements and ions in Italian bottled mineral waters: Identification of anomalous values and human health related effects

Microbiological studies have always had an important role in the evaluation of drinking water quality. However, since geological processes are the most important factors controlling the source and distribution of chemical elements in natural waters, the importance of geochemical data must not be underestimated. This study presents data on pH, conductivity and concentrations of 69 elements and ions (Ag, Al, As, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, Br⁻, HCO₃⁻, Cl⁻, F⁻, NH₄⁺, NO₂⁻, NO₃⁻, PO₄³⁻, SO₄²⁻, SiO₂) from 186 bottled mineral waters of 158 different Italian name brands. Analyses show a large range in concentrations for most of these elements, with variations up to four orders of magnitude. Our data demonstrate that some elements (such as Be), generally considered unlikely to occur, can instead reach surprisingly high levels in drinking water, and also how packaging can release some trace elements to the bottled water. Data analysis shows that the implementation of an international database of bottled water geochemistry and of potential toxicological effects is of paramount importance to provide a robust data set which would be useful to set international action levels and guidelines to secure bottled water quality, whose consumption has steadily increased in the recent years. A new formula to calculate nitrate and nitrite tolerable concentration levels in waters intended for human consumption is proposed, to take into account that about 5% of dietary nitrate in humans is converted to nitrite.     

Chemical variations and significance of phosphates from the Fregeneda-Almendra pegmatite field, Central Iberian Zone (Spain and Portugal)

Granitic pegmatites are widespread within a schist-metagreywacke complex in the Fregeneda-Almendra area (Central Iberian Zone). They intrude pre-Ordovician metasedimentary rocks and show a zonal distribution relative to the Meda-Penedono-Lumbrales granitic complex, from barren bodies to those enriched in Li, F, Sn, Nb>Ta, P and Be. Based on mineralogical criteria, these pegmatites are classified into three main categories: barren, intermediate and rare-element pegmatites, with each type including various subtypes. Phosphates are present in many pegmatites that usually occur as fine-grained accessory minerals. The most complex association of such minerals includes numerous Fe–Mn phosphates that occur in intermediate pegmatites. Al-phosphates are characteristic of Li-rich pegmatites. Electron microprobe analyses of representative phosphates reflect compositional differences depending on the pegmatite type. The Fe/(Fe+Mn) ratio of phosphates tends to decrease as the evolution degree of the pegmatites increases.     

Effects of the middle Holocene high sea-level stand and climate on Amazonian mangroves

The high sea-level stand during the mid-Holocene is a benchmark in mangrove dynamics along the north-east/south-east coast of Brazil and provides a reference point for landward and seaward mangrove migrations corresponding to changes in relative sea level (RSL). However, evidence of the impacts associated with RSL fall on the northern Brazilian coast is scarce. Multi-proxy data from the highest tidal flats of the Bragança Peninsula in northern Brazil revealed modern herbaceous areas were occupied by mangroves Rhizophora and Avicennia from ~6250 to ~5850 cal a bp , and only Avicennia between ~5850 and ~5000 cal a bp . The same tidal flats were vegetation-free between ~5000 and ~4300 cal a bp . A combination of a high sea-level stand (0.6 ± 0.1 m) at ~5000 cal a bp and a dry early–middle Holocene in the Amazon probably caused an increase in porewater salinity of tidal flats, which resulted in a mangrove succession from Rhizophora to Avicennia dominance. RSL fall accentuated this process, contributing to mangrove degradation between ~5000 and ~4300 cal a bp . RSL fall, and a wetter period over the past ~4300 cal a bp caused a mangrove migration from highest to lowest flats, followed by expansion of herbaceous vegetation on the highest flats.     

Eutrophication and hypoxia in four streams discharging in Guanabara Bay, RJ, Brazil, a case study

Four streams in the city of São Gonçalo, were sampled to evaluate their potential as sources of nutrients to Guanabara Bay aiming to contribute with the government program to decrease the levels of pollution in this area. Imbuaçu, Guaxindiba, Marimbondo and Brandoas streams were sampled in 2007, 2008 and 2009. The streams revealed to be hipereutrophic with severe limitation of primary production by nitrogen, as shown by the N/P molar ratio. Phosphate levels were abnormally high varying between 4.35 and 130.82 μM, whereas nitrate and nitrite ranged from 0.06 to 54.05 μM and from 0.28 to 19.23 μM, respectively. The streams also presented severe hypoxia and anoxia, with oxygen values varying from non-detected to 3.72 ml l⁻¹. Heavy loads of particulate suspended material were recorded in the studied streams, ranging between 6.00 and 400.00 mg l⁻¹. The streams were considered inexorable sources of nutrients, enhancing the severe eutrophication process in Guanabara Bay.     

Paleomagnetism and rock magnetism of the Neoproterozoic Itajaí Basin of the Rio de la Plata craton (Brazil): Cambrian to Cretaceous widespread remagnetizations of South America

A detailed rock magnetic and paleomagnetic study was performed on samples from the Neoproterozoic Itajaí Basin in the state of Santa Catarina, Brazil, in order to better constrain the paleogeographic evolution of the Rio de la Plata craton between 600 and 550 Ma. However, rock magnetic properties typical of remagnetized rocks and negative response in the fold test indicated that these rocks carried a secondary chemical remanent magnetization. After detailed AF and thermal cleaning, almost all samples showed a normal polarity characteristic remanent magnetization component close to the present geomagnetic field. The main magnetic carriers are magnetite and hematite, probably of authigenic origin. The mean paleomagnetic pole of the Itajaí Basin is located at Plat = − 84°, Plong = 97.5° (A95 = 2°) and overlaps the lower Cretaceous segment of the apparent polar wander path of South America, suggesting a cause and effect with the opening of the South Atlantic Ocean. A compilation of remagnetized paleomagnetic poles from South America is presented that highlights the superposition of several large-scale remagnetization events between the Cambrian and the Cretaceous. It is suggested that some paleomagnetic poles used to calibrate the APWP of Gondwana at Precambrian times need to be revised; the indication of remagnetized areas in southern South America may offer some help in the selection of sites for future paleomagnetic investigations in Precambrian rocks.     

Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).