Water pollution in gold mining industry: a case study in Roşia Montană district, Romania

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.     

Basement structure and sedimentary cover seismostratigraphy in the northern part of the Japan Basin in the region of the Tarasov Rise (Sea of Japan)

The results of continuous seismic profiling thermodynamics performed in the northern part of the Japan Basin in the region of the Tarasov Rise and the data of a micropaleontological examination of the diatom remains encountered in the sediment samples from the rise and continental slope are presented. In the area studied, the topography of the acoustic basement features a vast rise (plateau) buried under the sedimentary cover outlined by the depth contour 5.8 s. The plateau has a relatively smooth top surface crossed by a series of rises of the acoustic basement. The two largest rises are represented by the ridges of the Tarasov Rise. The plateau is separated from the continental slope by a depression in the acoustic basement with a depth up to 6.8 s. From the end of the Middle Miocene up to the beginning of the Paleocene, the region of the plateau represented an area of active volcanism; it coincided in time with the stage of subsidence of the floor of the acoustic basement depression. At the end of the Late Miocene, the ridges of the Tarasov Rise started to sink. In the Pliocene, this process accelerated, and, at the beginning of the Pleistocene, it stopped. In the Middle Miocene-Early Pleistocene time, the portion of the continental slope adjacent to the plateau remained stable and suffered no significant vertical movements.     

Field observations of waves generated by passing ships: A note

This short contribution reports the results of a field study on the nearshore characteristics of waves generated by both conventional and high speed passenger ferries. The field observations took place in the late summer of 2005, at a beach close to the port of Mytilene (Island of Lesbos, Greece), and involved the visual observation of ship waves, using digital video recordings and image processing techniques. The results showed that passage of the fast ferry was associated with a longer, more complex and energetic nearshore event; this event not only did include higher nearshore waves (up to 0.74 m) and was organised in different wave packets, but it was also an order of magnitude longer (∼ 680 s) than the conventional ferry event. Regarding the effects on beach sediment dynamics, the fast ferry waves were estimated to be very efficient in mobilising the nearshore sediments in contrast to those of the conventional ferry. The fast ferry service appears to generate daily prolonged nearshore events, which contain waves with higher energy than those expected from the normal summer wind wave regime of the area; these events also include some high and very steep waves, which can be particularly erosive. Therefore, fast ferry wakes may have considerable impacts on the seasonal beach sediment dynamics/morphodynamics and the nearshore benthic ecology, as well as they may pose significant risks to bathers, affecting the recreational use of the beaches exposed to fast ferry traffic. Finally, the study has shown that satisfactory field observations of the nearshore characteristics of ship-generated (and wind) waves can be obtained using inshore deployments of calibrated poles, digital video cameras and appropriate image processing algorithms.     

Toxicity assessment of sediments associated with various land-uses in coastal South Carolina, USA, using a meiobenthic copepod bioassay

Coastal urbanization supplies surrounding estuarine environments with urban-related contaminants such as polycyclic aromatic hydrocarbons (PAHs), metals and pesticide mixtures. In our study, adult female and male copepods (Amphiascus tenuiremis) were chronically exposed to 18 sediment samples collected from sites influenced by different land-uses. Sediment samples were collected from three major suburban areas (Hilton Head, Kiawah Island and the Okatee River watershed) and a pristine site (North Inlet) in coastal South Carolina. Three-sediment bioassays (six sites per bioassay) were conducted by culturing copepods for 14 days in quadruplicate test sediments under flow-through conditions at 20 degrees C and 12:12 LD cycles. Adult survival and copepod reproductive output were quantified. Sediment samples were also analyzed by GC-MS for low and high molecular weight PAHs. Minimal adult mortality was observed in most sediment samples. However, sediments from Hilton Head Island and the Okatee River showed significant effects on copepod reproductive output (i.e., nauplii, copepodites and clutch size). Thus, we determined that reproductive endpoints rather than adult copepod survivorship were more sensitive to effects of contaminated sediments on A. tenuiremis. Furthermore, six (33%) of the 18 sites had a >25% reduction in copepod bioassay endpoints relative to controls, suggesting a high risk to long term A. tenuiremis population maintenance.     

Reflection of equatorial Kelvin waves at eastern ocean boundaries Part I: hypothetical boundaries

A baroclinic shallow-water model is developed to investigate the effect of the orientation of the eastern ocean boundary on the behavior of equatorial Kelvin waves. The model is formulated in a spherical polar coordinate system and includes dissipation and non-linear terms, effects which have not been previously included in analytical approaches to the problem. Both equatorial and middle latitude response are considered given the large latitudinal extent used in the model. Baroclinic equatorial Kelvin waves of intraseasonal, seasonal and annual periods are introduced into the domain as pulses of finite width. Their subsequent reflection, transmission and dissipation are investigated. It is found that dissipation is very important for the transmission of wave energy along the boundary and for reflections from the boundary. The dissipation was found to be dependent not only on the presence of the coastal Kelvin waves in the domain, but also on the period of these coastal waves. In particular the dissipation increases with wave period. It is also shown that the equatorial β-plane approximation can allow an anomalous generation of Rossby waves at higher latitudes. Nonlinearities generally have a small effect on the solutions, within the confines of this model.     

Post-earthquake investigation on several geosynthetic-reinforced soil retaining walls and slopes during the Ji-Ji earthquake of Taiwan

This paper gives an overview on the application of geosynthetic-reinforced soil structures in Taiwan. Taiwan has an unique topography and geotechnical conditions that rendered a less conservative and more challenging design compared to that of North America, Europe and Japan. The Ji-Ji (Chi-Chi) earthquake of 1999 gave an opportunity to examine the behavior of reinforced soil structures. The performance of several modular-block reinforced soil retaining walls and reinforced slopes at the vicinity of the fault was evaluated. Reinforced structures performed better than unreinforced soil retaining walls. The failure cases were highlighted and the cause of failure was identified. The lack of seismic design consideration could be a major cause of failure. The compound failure mode, the inertia force of the blocks, and the connection stiffness and strength relative to the large dynamic earth pressure, were among major items that would warrant further design consideration.     

Method and results of assimilation of climatic data on temperature,salinity, and sea level into a numerical model of the Black Sea

A method for combined assimilation of climatic hydrologic fields of temperature, salinity, and the climatic dynamic level of the Black Sea into a model of sea dynamics is proposed. The monthly mean fields of the dynamic sea level were obtained from the results of assimilation of satellite altimetry data into the model. The statistical characteristics of errors in the forecasts of the level, salinity, and temperature were assumed to be proportional to the statistical characteristics of the differences between monthly mean climatic fields of temperature, salinity, and sea level calculated by means of assimilating altimetry observations of the sea level and analogous climatic hydrologic fields. The climatic fields of currents are reconstructed and analyzed. The assimilation of the climatic altimetry level allows the reproduction (in current fields) of quasi-stationary synoptic anticyclonic eddies located along the periphery of the Black Sea Rim Current.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Viscous overstability and eccentricity evolution in three-dimensional gaseous discs

We investigate the growth or decay rate of the fundamental mode of even symmetry in a viscous accretion disc. This mode occurs in eccentric discs and is known to be potentially overstable. We determine the vertical structure of the disc and its modes, treating radiative energy transport in the diffusion approximation. In the limit of very long radial wavelength, an analytical criterion for viscous overstability is obtained, which involves the effective shear and bulk viscosity, the adiabatic exponent, and the opacity law of the disc. This differs from the prediction of a two-dimensional model. On shorter wavelengths (a few times the disc thickness), the criterion for overstability is more difficult to satisfy because of the different vertical structure of the mode. In a low-viscosity disc a third regime of intermediate wavelengths appears, in which the overstability is suppressed as the horizontal velocity perturbations develop significant vertical shear. We suggest that this effect determines the damping rate of eccentricity in protoplanetary discs, for which the long-wavelength analysis is inapplicable and overstability is unlikely to occur on any scale. In thinner accretion discs and in decretion discs around Be stars overstability may occur only on the longest wavelengths, leading to the preferential excitation of global eccentric modes.     

The properties of convective storms in central Mexico: A radar and lightning approach

Radar data from Cerro Catedral (a peak close to Mexico City) were used to investigate the properties of convective storms over central Mexico, a region with complex orography. The spatial distribution shows a preference for storms to form and move to the west of radar, over a narrow band of high terrain. However, the storms with the higher volumes and echo-top heights tend to be located southwestward over lower terrain. Each radar feature was matched with the number of cloud-to-ground (CG) lightning produced inside it, as retrieved from the World Wide Lightning Location Network dataset. The storms in which lightning was detected, with an average of more than six lightning bolts, clearly outperform in size and intensity the group of storms in which lightning was not detected, and tend to lie over lower terrain. The sample of over 98 000 identified cells was divided into four elevation groups to look for elevation trends in the mean properties, as reported for other Mexican regions. While the number of storms per unit area increases with terrain height, the average values for properties related to both size (area, volume, echo-top height) and intensity (maximum reflectivity, number of CG bolts, height of maximum reflectivity, maximum height of 30 dBZ echo) decrease. These results could be related to the possible shallower warm-cloud depths over the higher elevations. The diurnal cycles of convection and lightning north of the radar show a nearly typical continental regime of precipitation in that zone, with maxima at 18:00 LT in both variables. However, south of the radar, a maximum in lightning activity occurs during late night and early morning, which is linked with the deeper nocturnal convection over the lower terrain in that zone.