T-XCO2 stability relations and phase equilibria of a calcic carbonate scapolite

At a total pressure of 5 kb, calcic, Cl-free scapolite (Me₈₃) is stable relative to plagioclase-bearing assemblages at $\text{T ≧ 625°C}$, . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO₂ in the presence of H₂O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO₂, which occurs at 750°C, X_CO2 = 0.46; 700°C, X_CO2 = 0.33; 650°C, X_CO2 = 0.18, for the chosen bulk composition.Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me₇₅) has the largest T-X_CO2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and X_CO2.The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO₂-rich fluids.     

Sedimentology and kinematics of a large, retrogressive growth-fault system in Upper Carboniferous deltaic sediments, western Ireland

Growth faulting is a common feature of many deltaic environments and is vital in determining local sediment dispersal and accumulation, and hence in controlling the resultant sedimentary facies distribution and architecture. Growth faults occur on a range of scales, from a few centimetres to hundreds of metres, with the largest growth faults frequently being under‐represented in outcrops that are often smaller than the scale of feature under investigation. This paper presents data from the exceptionally large outcrops of the Cliffs of Moher, western Ireland, where a growth‐fault complex affects strata up to 60 m in thickness and extends laterally for ≈ 3 km. Study of this Namurian (Upper Carboniferous) growth‐fault system enables the relationship between growth faulting and sedimentation to be detailed and permits reconstruction of the kinematic history of faulting. Growth faulting was initiated with the onset of sandstone deposition on a succession of silty mudstones that overlie a thin, marine shale. The decollement horizon developed at the top of the marine shale contact for the first nine faults, by which time aggradation in the hangingwall exceeded 60 m in thickness. After this time, failure planes developed at higher stratigraphic levels and were associated with smaller scale faults. The fault complex shows a dominantly landward retrogressive movement, in which only one fault was largely active at any one time. There is no evidence of compressional features at the base of the growth faults, thus suggesting open‐ended slides, and the faults display both disintegrative and non‐disintegrative structure. Thin‐bedded, distal mouth bar facies dominate the hangingwall stratigraphy and, in the final stages of growth‐fault movement, erosion of the crests of rollover structures resulted in the highest strata being restricted to the proximity of the fault. These upper erosion surfaces on the fault scarp developed erosive chutes that were cut parallel to flow and are downlapped by the distal hangingwall strata of younger growth faults.     

Magnetohydrodynamic oscillations due to precessional motion

Summary The motion of a non-viscous liquid medium with an ideal electrical conductivity, enclosed in the ellipsoidal cavity of an envelope subject to precessional motion, is investigated. Inside the cavity there is a toroidal magnetic field. It is proved that the precessional motion of the envelope generates forced oscillations of the medium with a period of 24 hours and two different types of eigen oscillations. Expressions for computing the amplitudes and frequencies of all types of oscillations are derived. The maximum values of disturbance fields are determined for geophysically acceptable parameters.     

Towards medium-term (order of months) morphodynamic modelling of the Teign estuary, UK

The main objective of this paper is to address the principal mechanisms involved in the medium-term (order of months to years) morphodynamic evolution of estuaries through the application of a process-based numerical modelling. The Teign estuary (Teignmouth, UK) is the selected site. The system is forced by the macrotidal semi-diurnal tide in the English Channel and is perturbed to a minor extent by high river discharge events (freshets). Although waves have a definite influence on the adjacent coastal area, Wells (Teignmouth Quay Development Environmental Statement: Changes to Physical Processes. Report R.984c:140. ABP Marine Environmental Research Ltd., Southampton, 2002b) suggested that swell waves do not enter the estuary. Hence, wave effects are neglected in this study, as only tides and the river discharge are taken into account. The sediment grain size is highly variable, but mainly sandy. Within the frame of the COAST3D project (), four bathymetric surveys of the adjacent coastal area were carried out at a nearly weekly intervals. The outer estuary and the adjacent coastal area were also surveyed every 6 months as part of the COASTVIEW project (). Based on these data and on continuously measured parameters, such as water level, waves, wind and river discharge, numerical modelling of the morphodynamic processes can be tested. To replicate the morphological changes in the medium-term within a feasible simulation time, forcing conditions are reduced through the use of an input reduction method (called ensemble technique). In this study, simulations are based on the coupling between Telemac-2D and its non-cohesive sediment transport module, Sisyphe (version 5.3 for both modules). Three different sediment transport formulae were tested: (1) Engelund and Hansen (A monograph on sediment transport in alluvial streams, 3rd edn. Technological University of Denmark, Copenhagen, 1967) including the modifications proposed by Chollet and Cunge (J Hydraul Eng 17(1):1–13, 1979); (2) Bijker (Mechanics of sediment transport by the combination of waves and current. In: Design and reliability of coastal structures. 23rd international conference on Coastal Engineering, pp 147–173, 1968) and (3) Soulsby (Dynamics of Marine Sands. A manual for practical applications. HR Wallingford, Wallingford, p 142, 1997) modified version of van Rijn [J Hydraul Eng 110(10):1431–1456, 1984a, J Hydraul Eng 110(11):1613–1641, 1984b] formulation. Both a qualitative (i.e. visual comparison) and a quantitative tool [Brier Skill Score (BSS); described in Sutherland et al. in Coast Eng 51:917–939, 2004b] are applied to assess the similarity of simulations when compared to model predictions and observations. Tests confirmed the reliability and time efficiency of the ensemble technique, since it reproduced very well the results of a reference run, a computation based on the observed boundary conditions. For the spring-neap cycle modelled, the BSS was of 0.91 (a perfect modelling would have a BSS of 1), with a reduction in the simulation time on the order of 80%. For the 6-month-period simulation, results were also excellent: BSS=0.92 and a computer time reduction of 85%. In principle, this method has the advantage of being applied to any process-based numerical model.     

A study of volcanogenic exhalation mineralization

This paper considers volcanogenic exhalation mineralization using data from 35 years of observation of fumarole activity during an earlier phase of the posteruptive activity of the Second Cone, which is one of the New Tolbachik volcanoes that were formed during the eruption at the North Vent of the Great Tolbachik Fissure Eruption (Kamchatka, 1975–1976). We describe the main types of mineral associations, identify the key mineral species and the secondary and accessory minerals, as well as the sequence of mineral generation. We provide a summary of minerals and compounds that have been identified in ejecta of fumaroles on the Second Cone.     

Ice flow direction during late Paleozoic glaciation in western Paraná Basin, Brazil

The recent discovery of ice-striated surfaces associated with the late Paleozoic Aquidauana Formation suggests that glaciers coming from southwest Africa reached westernmost parts of the Paraná Basin in central Brazil. Abrasion features were developed by glaciers moving from SSE towards NNW, mainly on an unconsolidated bed. These records expand to about 1,050,000 km², the coverage of the late Paleozoic glaciation in the region of the Paraná Basin in Western Gondwana.

Resumen

A recente descoberta de superfícies estriadas associadas à Formação Aquidauana, de idade permocarbonífera, sugere que as geleiras provenientes do sudoeste da África alcançaram as porções ocidentais da Bacia do Paraná, na região central do Brasil. As feições de abrasão foram geradas pelo deslocamento de geleiras de SSE para NNW, principalmente sobre substrato inconsolidado. Estes novos registros evidenciam que a glaciação neopaleozóica cobriu uma área de pelo menos de 1.050.000 km² na região ocupada pela Bacia do Paraná no Gondwana Ocidental.     

MINI-MACtm—A new generation dual—Band surveyor

Summary Litton Divisions presently produce both high accuracy GPS surveyors and low—cost GPS navigation sets. Aero Service'sMACROMETER ^R Interferometric Surveyors, have become the standard against which GPS surveying equipment is measured. Litton Aero Products has developed a highly digitized, low costL ₁,C/A code GPS card set. The integration of these technologies had led to the development of a low-cost, high-precision, GPS survey system which can be configured with or without a codelessL ₂ capability. TheMINI-MAC surveying system is the first member of the new generation of GPS survey systems resulting from this joint development. The system design is described in this paper, and initial survey test results using a prototypeMINI-MAC surveying system are presented.     

Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.     

The generation ofK indices from digitally recorded magnetic data

TheK index was developed by Bartels and is a measure of geomagnetic activity. The important feature of this index is that it is a measure of solar activity superimposed on the regular daily variation.It is the most used estimate of activity being of particular interest to researchers in ionospheric physics and telecommunications.In response to increased availability of digital data from magnetic observatories and their demand by the scientific community it becomes desireable to check whetherK indices produced from magnetograms plotted from digital data are consistent with those handscaled from La Cour charts.This paper presents results of these comparisons and also reports on several methods tested to produce theK index directly from the digital data.Handscaled indices from digital plots are suitable for producing theK index. Computations using digital data do not reproduceK as defined by Bartels precisely but do provide an equivalent index which is satisfactory for most user and research purposes.