Interannual variability and temporal variations of total column ozone in Visakhapatnam from ground based observations

Total column ozone (TCO) measured by the portable, handheld, multichannel Sun photometer (ozonometer-Microtops-II) at Visakhapatnam (17.43°N, 83.14°E; 51 m above mean sea level), India, which is a tropical urban station has been analysed in this study. The results showed the estimate of the annual and seasonal trends of TCO from the period February 2005 to December 2008. The linear regression technique was applied in Microtops II data to study the trend of TCO during 2005?C2008. It also provides statistics of mean and variability on temporal scale. The results showed increasing trend at Visakhapatnam an average of 1.88 DU per year (or 0.61% per year). However the maximum deviation in diurnal variability of TCO were 28 DU (9.19%) while the minimum deviation were ?36 DU (?11.8%) respectively, which is one of the unique result of this study. The range of the seasonal change represents 9.2% of the mean TCO value with maximum/minimum during March/December.     

Decolorisation of exhausted reactive dye bath using ozonator for reuse

Exhausted Reactive dye bath samples of Turquoise Blue, Olive Green and Navy Blue shades were collected from cotton knit wear dyeing units in Tirupur. Ozonation was conducted in a column reactor system fed with ozone at the rate of 0.16 g/min to assess its efficiency in reducing the color, chemical oxygen demand and total organic carbon. Complete decolorization of the effluent was achieved in 10 min contact time and ozone consumption of 153 mg/ L for Turquoise Blue, 128 for Olive Green and 143 for Navy Blue shades effluents respectively. The corresponding COD removal was 43%, 44% and 43% for the three shades while TOC removal efficiency was 45%, 45% and 40% respectively. The results from the reusability studies indicate that the dyeing quality was not affected by the reuse of decolorized dye bath for two successive cycles. It is concluded that ozonation is efficient in decolorization of exhausted dye bath effluents containing conventional reactive dyes. However, the corresponding removal of COD from the textile effluent was not significant.     

Block and boulder accumulations along the coastline between Fins and Sur (Sultanate of Oman): tsunamigenic remains?

The rocky coastline of the Sultanate of Oman between Fins and Sur is decorated by a number of large blocks and boulder accumulations forming ramparts. The blocks occur as individual rocks of up to 40 tons, as imbricated sets and as ??boulder trains.?? Landward, the deposits change into a sand/boulder mixture and distal into sands. The coast is made up of Tertiary folded limestones and beach rock of Quaternary age, both also constitute the megaclasts. The transport distance from the fractured seaward platform of 6?C10?m above mean sea level varies between 20?m and more than 50?m. We found individual blocks of recent corals and overturned blocks with attached oysters and rock pools. Terrestrial laser scanning was used to analyze geomorphologic features as well as for volumetric estimates of the block weights. Tropical cyclones such as Gonu in 2007 or Phet in 2010 are known to have affected Oman??s coastline in the past. The coastal changes during recent cyclones were minor; therefore, we interpret the block deposits as tsunamigenic. However, this interpretation is not unambiguous. The most likely source area for a tsunami is seen in the Makran Subduction Zone situated in the northern Indian Ocean. Here, at least 4?C5 tsunamigenic earthquakes are documented.     

Application of magnetic adsorbent with silicate and phenyl polymers to adsorb Rhodamine B

The extensive use of Rhodamine B (RhB) for textile, paper, pigment, food, cosmetic, and drug manufacturing and its indiscriminate disposal leads to serious human, biological, and environmental hazards. A magnetic adsorbent with silicate and phenyl polymers (Ph/SiO₂/Fe₃O₄) has been prepared to absorb RhB. The morphology and structure of the adsorbents have been characterized by TGA, XRD, FTIR, and adsorption–desorption measurement. The results revealed that Ph/SiO₂/Fe₃O₄ exhibited a paramagnetic behavior and could easily and quickly be separated from a suspension. The RhB adsorption behavior was almost pH independent due to the adsorption between the phenyl ring of Ph/SiO₂/Fe₃O₄ and RhB by π–π electron-donor–acceptor interactions. The adsorption behavior of RhB adsorption was in good agreement with the Langmuir adsorption isotherm, and the maximum adsorption capacity was 142.186 mg g^?1. Good desorption performance of Ph/SiO₂/Fe₃O₄ showed that this novel magnetic adsorbent cannot only be activated by ethanol extraction process but also reuse by the recovery of magnetic force.     

Soil-to-dwelling radon isotope ratio in the Baikal region

Relations between indoor and soil gas radon were experimentally studied in villages of the Baikal region. On the basis of the obtained data, the soil-to-indoor radon ratio was calculated, which can be used for prediction of radon pollution in buildings of the same kind.     

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

A fault plane solution using theoretical P seismograms

We use the method of Hudson and Douglas, Hudson & Blarney to compute seismograms which simulate the codas of 10 short period P -wave seismograms from a shallow earthquake. The polarities and relative amplitudes of P and pP measured from seven of the observed seismograms are used to compute a fault plane solution with confidence limits, assuming that the source radiates as a double couple. This solution is in approximate agreement with that given for the same earthquake by Sykes & Sbar, who used only the onset polarities of short-period P waves. The small difference between the two solutions can be explained by interference between the true first motion of P and microseismic noise at two stations.
The results show that, for some shallow earthquakes, the relative amplitude method has the following advantages over the first motions method. First, a P/pP amplitude ratio (with appropriate confidence limits) can always be measured, even in seismograms which are so noisy that the first motion of P is uncertain. Second, the fault plane solutions obtained from relative amplitudes have known confidence limits. Finally, by using more information from each seismogram, the relative amplitude method requires considerably fewer seismograms than the first motions method.     

A mineral equilibria study of the hydrothermal alteration in mafic greenschist facies rocks at Kalgoorlie, Western Australia

The influx of a H₂O–CO₂‐dominated fluid into actinolite‐bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite‐bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition X_CO2 = CO₂/(CO₂ + H₂O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition X_CO2≈ 0.25. Fluid‐rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.     

Implications of trace fossil assemblages from Late Paleozoic Glaciomarine Talchir Formation, Raniganj Basin, India

The trace fossil assemblages of the ice-marginal shallow marine sediments of the Talchir Formation (Permo-Carboniferous), Raniganj Basin, India, record the adverse effect of extreme climatic conditions on biota. The glaciomarine Talchir succession starts with glacial sediments near the base and gradually passes to storm-laid shallow marine sediments up-section. The fine-grained storm sediments host abundant trace fossils. Although the studied ichnites characteristically show marginal marine affinity, the ichnodiversity and bioturbation intensity suggest a lower than normal shallow marine trace fossil population. Further, endobenthic annelids, worms and crustaceans are identified as dominant trace-makers.

Sediment reworking near the ice-grounding line, extremely cold climate, high-energy storm sedimentation and anomalous water chemistry hindered organic colonization during the early phases of Talchir sedimentation. Later, climatic amelioration ushered in a favourable ambience for the benthic community to colonize within or beyond the storm weather wave-base in the outer shoreface–shelf environment. Fluctuating storm energy dominantly controlled the availability and influence of other environmental stimuli in the environment, and thus, governed the distribution, abundance and association of the studied ichnites. However, impoverished ichnodiversity, sporadic distribution of the traces, overall smaller burrow dimensions, absence of body fossils, dominance of worms and annelids as trace-makers all indicate a stressed environmental condition, induced by cold climate and lowered marine salinity due to influx of glacier melt-out freshwater during climatic amelioration, in the Permo-Carboniferous ice-marginal sea.