T-XCO2 stability relations and phase equilibria of a calcic carbonate scapolite

At a total pressure of 5 kb, calcic, Cl-free scapolite (Me₈₃) is stable relative to plagioclase-bearing assemblages at $\text{T ≧ 625°C}$, . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO₂ in the presence of H₂O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO₂, which occurs at 750°C, X_CO2 = 0.46; 700°C, X_CO2 = 0.33; 650°C, X_CO2 = 0.18, for the chosen bulk composition.Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me₇₅) has the largest T-X_CO2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and X_CO2.The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO₂-rich fluids.     

Magnetohydrodynamic oscillations due to precessional motion

Summary The motion of a non-viscous liquid medium with an ideal electrical conductivity, enclosed in the ellipsoidal cavity of an envelope subject to precessional motion, is investigated. Inside the cavity there is a toroidal magnetic field. It is proved that the precessional motion of the envelope generates forced oscillations of the medium with a period of 24 hours and two different types of eigen oscillations. Expressions for computing the amplitudes and frequencies of all types of oscillations are derived. The maximum values of disturbance fields are determined for geophysically acceptable parameters.     

MINI-MACtm—A new generation dual—Band surveyor

Summary Litton Divisions presently produce both high accuracy GPS surveyors and low—cost GPS navigation sets. Aero Service'sMACROMETER ^R Interferometric Surveyors, have become the standard against which GPS surveying equipment is measured. Litton Aero Products has developed a highly digitized, low costL ₁,C/A code GPS card set. The integration of these technologies had led to the development of a low-cost, high-precision, GPS survey system which can be configured with or without a codelessL ₂ capability. TheMINI-MAC surveying system is the first member of the new generation of GPS survey systems resulting from this joint development. The system design is described in this paper, and initial survey test results using a prototypeMINI-MAC surveying system are presented.     

The Two-Point Covariance Function of Galaxy Clustering for Extreme Values of its Argument

The two-point covariance function of galaxy clustering is discussed for small and large values of its argument.     

Frost risk mapping for landscape planning: A methodology

Summary Minimum air temperatures were measured during three winters with a network of stations in open, undulating terrain. It was observed that the change in minimum air temperature with elevation could be predicted from mean nighttime windspeed, total nighttime net radiation loss and a hill-top reference minimum temperature. It was also found that the deviation of temperatures at individual sites could be predicted from a local terrain parameter which reflects the extent of cold air accumulations. Thus a methodology for frost risk mapping has been developed which is based on regional weather dataand local terrain analysis. This paper describes the model and illustrates the regional weather and terrain effects with three-dimensional block diagrams.With 8 Figures     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz     

Uranium and lead gain of detrital zircon studied by isotopic analyses and fission-track mapping

Besides Pb and U loss and mixing of crystals of different age, U gain is considered a possible cause of discordant U-Pb ages of zircons. However, whether U gain without new zircon growth occurs in nature had not been proven, so far. In order to test this possibility, two detrital zircon populations were studied for which the absence of later zircon overgrowth after deposition could be demonstrated. The samples were separated from a metaquartzite near a large pegmatite body and from metaquartzite inclusions found in the pegmatite (Martell Valley, Italian Alps). The distribution of neutron-induced fission tracks reveals distinct accumulation of U in the rims of more than 90% of the zircon grains of the inclusions (total U in the crystals: 540–850 ppm), whereas in the country rock only some of the grains show similar but weaker patterns (total U: 155–320 ppm). From the isotopic data and from additional U-Pb and Rb-Sr analyses of minerals and whole-rock samples of the pegmatite, the marginal accumulation and the higher concentration of U in the zircon grains of the inclusions are interpreted as the result of episodic U gain during the intrusion of the pegmatite and/or during a later metamorphism. From the concentration levels of common Pb, an addition of Pb - and possibly other elements - to the zircon grains is inferred.     

Longshore variations in nearshore wave processes at magilligan point,northern ireland

Magilligan Point is a recurved cuspate foreland at the mouth of Lough Foyle. Two wave regimes intersect in the estuary mouth and the manner of their interplay controls shoreline changes. Ocean swell waves from the N and NE are refracted around the recurve, losing both height and energy longshore. Width of the surf zone decreases and waves tend to steepen, although both these changes and wave refraction owe something to nearshore geometry. Angle of wave approach becomes more acute and a westerly flowing longshore current moves sand S and SW along the beach. Estuary waves from the S and SW are wind-driven with high-frequencies and steepnesses. They generate a northeasterly current which returns material N, but dies out as the waves become obliterated by nearshore attenuation and breaking of swell. It is possible to identify a time-averaged null-point where shoreline wave power is balanced, although this tends to shift over short periods causing rapid morphological changes. The existence of two independent, but counteractive cells ensures the long-term maintenance of the foreland, without requiring major or continuous supplies of fresh sediment.