Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Water transport from the North-east Irish Sea to western Scottish coastal waters: Further observations from time-trend matching of Sellafield radiocaesium

Radiocaesium isotopes, discharged into the North-east Irish Sea from the Sellafield (formerly Windscale) nuclear fuel reprocessing plant in Cumbria, have been employed as flow monitors to update and extend the record of coastal water movement from the Irish Sea to the Clyde Sea area and, further north, to Loch Etive. The temporal trends in radiocaesium levels have been used to determine the extent of water mixing en route and to define mean advection rates. Flow conditions from the Irish Sea have changed considerably since the mid-1970s, the residence time of northern Irish Sea waters being ～12 months during 1978–1980 inclusive. Average transport times of four and six months are estimated for the Sellafield to Clyde and Sellafield to Etive transects respectively. Sellafield ¹³⁷Cs levels in seawater were diluted by factors of 27 and 50 respectively during current movement to the Clyde and Etive areas. The decrease in salinity-corrected ¹³⁷Cs concentrations between the Clyde and Etive suggests that dilution by Atlantic water occurs, the latter mainly entering the Firth of Lorne from the west. The majority (～94%) of the radiocaesium supply to Loch Etive enters the Firth of Lorne via the portion of the coastal current circulating west of Islay, only ～6% arriving via the Sound of Jura.     

One hundred years of mountain hydrology in Switzerland by the WSL

In 1903 the Swiss Federal Research Institute WSL started its first forest hydrology measurements with the aim to deliver a sound scientific basis for the implementation of new forest legislation introduced in Switzerland in 1876. This legislation was triggered by several large floods that occurred in Switzerland, for which a major cause was widely seen as the poor condition of forests at that time. Consequently, hydrologic research at WSL first focused on the influence of forests on floods. In the second half of the 20th century, other hydrological issues such as water quality, snow hydrology and sediment transport complemented the hydrologic research at WSL. Some recent results of this work are presented in three papers joining this introductory paper to mark the 100th anniversary of hydrologic research at WSL. Copyright © 2006 John Wiley & Sons, Ltd.     

Pb, Sr and Nd isotope study of two co-existing magmas in the Nízke Tatry Mountains, Western Carpathians (Slovakia)

Summary Two co-existing plutonic rocks (diorite and granodiorite) were studied from an intrusion of Variscan age in the Raztocna Valley – Nízke Tatry Mountains, Western Carpathians. Geochemical analyses of major and trace elements constrain a volcanic arc as emplacement environment and give the first hints of a mixture of two magmatic end-members: the so-called Prasivá granodiorite and the Raztocna diorite. The ⁸⁷Sr/⁸⁶Sr₍₀₎ ratios vary between 0.7075 and 0.7118, the ε Nd₍₀₎ values range from −1.4 to −5.0. Common Pb isotopes reveal a dominant crustal source with minor influences from a mantle and a lower crustal source. Modelling based on Sr and Nd isotope data and using three component mixing calculations indicates that mixing of 2/3 of upper mantle material with 1/3 upper crustal material can produce the isotopic composition of the Raztocna diorite. Very minor amounts of lower crust were incorporated in the diorite. For the Prasivá granodiorite, the mixing ratio of upper mantle and upper crust is similar, but a lower crustal reservoir contributed about 5–10% of the source material.     

A new stereo‐analytical method for determination of removal blocks in discontinuous rock masses

The paper provides a new stereo‐analytical method, which is a combination of the stereographic method and analytical methods, to separate finite removable blocks from the infinite and tapered blocks in discontinuous rock masses. The methodology has applicability to both convex and concave blocks. Application of the methodology is illustrated through examples. Addition of this method to the existing block theory procedures available in the literature improves the capability of block theory in solving practical problems in rock engineering. Copyright © 2003 John Wiley & Sons, Ltd.     

Infiltration at the Tai rain forest (Ivory Coast): Measurements and modelling

Infiltration experiments have been performed at three sites along a well-known catena under virgin tropical rain forest using a portable sprinkling infiltrometer. Experimentally determined infiltration curves are presented. Infiltration curves are also simulated on the basis of the Mein-Larson equation. The parameters for this model have been obtained from the infiltration curves (saturated conductivity) and simple soil moisture determinations (fillable porosity). The agreement between experimentally determined and modelled infiltration is reasonable, provided (a) saturated conductivity as derived from the experimental data is corrected, (b) a storage parameter, also derived from the experimental data, is added to the Mein-Larson model, and (c) the decline in soil porosity with depth is either small or occurs abruptly at shallow depth. Comparison of observed infiltration rates with rainfall intensity shows that Horton Overland Flow has to occur naturally at least on the middle and lower section of the catena. Despite the fact that most parameters can be estimated in principle from basic soil data, it remains advisable to obtain sprinkling infiltrometer field measurements, because of soil variability due to dynamic surface conditions, macroporosity, air entrapment, and irregularity of the wetting front.     

Rapid vegetation change during the early Holocene in the Faroe Islands detected in terrestrial and aquatic ecosystems

High‐resolution pollen, plant macrofossil and sedimentary analyses from early Holocene lacustrine sediments on the Faroe Islands have detected a significant vegetation perturbation suggesting a rapid change in climate between ca. 10 380 cal. yr BP and the Saksunarvatn ash (10 240±60 cal. yr BP). This episode may be synchronous with the decline in δ¹⁸O values in the Greenland ice‐cores. It also correlates with a short, cold event detected in marine cores from the North Atlantic that has been ascribed to a weakening of thermohaline circulation associated with the sudden drainage of Lake Agassiz into the northwest Atlantic, or, alternatively, a period with distinctly decreased solar forcing. The vegetation sequence begins at ca. 10 500 cal. yr BP with a succession from tundra to shrub‐tundra and increasing lake productivity. Rapid population increases of aquatic plants suggest high summer temperatures between 10 450 and 10 380 cal. yr BP. High pollen percentages, concentrations and influx of Betula, Juniperus and Salix together with macrofossil leaves indicate shrub growth around the site during the initial phases of vegetation colonisation. Unstable conditions followed ca. 10 380 cal. yr BP that changed both the upland vegetation and the aquatic plant communities. A decrease in percentage values of shrub pollen is recorded, with replacement of both aquatics and herbaceous plants by pioneer plant communities. An increase in total pollen accumulation rates not seen in the concentration data suggests increased sediment delivery. The catchment changes are consistent with less seasonal, moister conditions. Subsequent climatic amelioration reinitiated a warmth‐driven succession and catchment stabilisation, but retained high precipitation levels influencing the composition of the post‐event communities. Copyright © 2003 John Wiley & Sons, Ltd.     

SANICLAY: simple anisotropic clay plasticity model

SANICLAY is a new simple anisotropic clay plasticity model that builds on a modification of an earlier model with an associated flow rule, in order to include simulations of softening response under undrained compression following K_o consolidation. Non‐associativity is introduced by adopting a yield surface different than the plastic potential surface. Besides, the isotropic hardening of the yield surface both surfaces evolve according to a combined distortional and rotational hardening rule, simulating the evolving anisotropy. Although built on the general premises of critical state soil mechanics, the model induces a critical state line in the void ratio–mean effective stress space, which is a function of anisotropy. To ease interpretation, the model formulation is presented firstly in the triaxial stress space and subsequently, its multiaxial generalization is developed systematically, in a form appropriate for implementation in numerical codes. The SANICLAY is shown to provide successful simulation of both undrained and drained rate‐independent behaviour of normally consolidated sensitive clays, and to a satisfactory degree of accuracy of overconsolidated clays. The new model requires merely three constants more than those of the modified Cam clay model, all of which are easily calibrated from well‐established laboratory tests following a meticulously presented procedure. Copyright © 2006 John Wiley & Sons, Ltd.