Effects of organic pollutants on methanogenesis,sulfate reduction and carbon dioxide evolution in salt marsh sediments

Anaerobic salt marsh sediments were amended with a variety of organic pollutants and the effects on methanogenesis, sulfate reduction and carbon dioxide evolution were examined. Addition of 1000 μg g^?1 (dry weight sediment) Arochlor 1221, lindane, endrin, benzene and phenanthrene resulted in no significant effects on the activities studied. Methanogenesis was inhibited by 1000 μg g^?1toxaphene, PCP, chlordane, naphthalene, DDT, Kepone and heptachlor and by 100 μg g^?1 PCP and toxaphene. At 1000 μg g^?1 naphthalene and toxaphene and 100 μg g^?1 PCP, a period of initial inhibition of methanogenesis was followed by stimulation relative to controls. Arochlor 1254 (1000 μg g^?1) and Temik (500 and 10 μg g^?1) stimulated methanogenesis from the outset. Temik at 500 μg g^?1 gave the greatest stimulation of methanogenesis (900% of controls) of any of the compounds studied. Sulfate reduction was inhibited by 1000 μg g^?1 PCP, toxaphene, naphthalene and chlordane and by 500 μg g^?1 atrazine and 100 μg g^?1 heptachlor. Sustained inhibition of sulfate reduction by naphthalene, toxaphene and PCP may have contributed to the stimulation of methanogenesis. Carbon dioxide evolution was not significantly affected by most of the compounds studied except for 100 μg g^?1 PCP and 1000 μg g^?1 aphthalene, each of which gave significant inhibition in only one of three experiments.Concentrations of individual organic pollutants required to cause observable effects were high. It is concluded that, except for highly polluted sediments, methanogenesis, sulfate reduction and CO₂ evolution would not be affected by the compounds studied here at concentrations typically found in the environment.     

Evidence for slope instability and current-induced sediment transport,the RMSTitanic wreck search area,Newfoundland rise

The first map of the sea bed morphology and sedimentary features within the RMSTitanic search area is proposed from the interpretation of SAR side-scan sonar images. Downslope sedimentary features such as erosional furrows and crown scarps constitute a 7 km wide instability corridor. A large field (15 km²) of asymmetrical sediment waves indicating a downslope transport is identified. Current-induced features corresponding to associated sand ribbons and barchan dunes resulting from the Western Boundary Undercurrent action are mapped. The morphology of theTitanic Canyon is also precised from the SAR images. Finally, the origin of the sea bed features is discussed in an attempt to link each bed form to a sedimentary process.     

Descriptive Analysis and Classification of Benthic Communities in Some Mediterranean Coastal Lagoons (Central Italy)

Abstract. Benthic samples were taken seasonally at 32 stations in five coastal lagoons of Central Italy (Fogliano, Monaci, Caprolace, Fondi, and Lungo) during a two-year period (1982–1984). Composition and distribution of benthic populations in each lagoon as well as seasonal trends of species richness, density, diversity, and redundancy are presented and discussed.
The faunal differentiation appeared to be mainly due to the different degree of water exchange, both with marine and continental systems.     

A new methodology developed by cetena to assess the seakeeping behaviour of marine vessels

The paper describes an analytical method to determine an operability index for a marine vehicle when its geometric characteristics, the geographical area in which the vessel is supposed to operate, and the limiting criteria for operations are known. The computer program based on strip theory provides reliable results not only for conventional hullforms, but also for catamarans, offshore vehicles, etc. The results are presented in the form of figures for different vessels, namely, crane barge, naval vessels and SWATH type catamarans. The authors are of the opinion that the proposed method would provide the designer with a valid tool to improve the seakeeping qualities of a vessel, while taking into account the limiting conditions imposed due to seaway operations.     

Using ocean ambient noise for array self-localization and self-synchronization

Estimates of the travel times between the elements of a bottom hydrophone array can be extracted from the time-averaged ambient noise cross-correlation function (NCF). This is confirmed using 11-min-long data blocks of ambient noise recordings that were collected in May 1995 near the southern California coast at an average depth of 21 m in the 150-700 Hz frequency range. Coherent horizontal wavefronts emerging from the time derivative of the NCF are obtained across the array's aperture and are related to the direct arrival time of the time-domain Green's function (TDGF). These coherent wavefronts are used for array element self-localization (AESL) and array element self-synchronization (AESS). The estimated array element locations are used to beamform on a towed source.     

Degradation in Cemented Marine Clay Subjected to Cyclic Compressive Loading

The influence of cyclic loading on the strength and deformation behavior of cemented marine clay has been studied. This marine clay is of recent Pleistocene origin and deposited in a shallow water marine environment. Open pits were dug in sheeted enclosures and from these pits, undisturbed samples were taken for strength testing. A series of standard triaxial shear tests and stress controlled one-way cyclic load tests were conducted at consolidation stress ranges below and above the preconsolidation pressure. For the stress levels below the preconsolidation pressure, the cyclic loading has brought about the collapse of the cementation bond through an increase in strains, and at higher pressure ranges, the soil behaves like typical soft clay. This experiment studied the rate of development of strain and pore water pressure and shows that rate is a function of number of cycles, applied stress, and stress history. In addition, soil degradation during cyclic loading is studied in terms of Degradation Index. Attempt has been made to predict stain, pore water pressure, and degradation index through an empirical model.     

The relationship between the amplitudinal characteristics of the high-frequency spectral components of wind-generated waves and the wind velocity over the sea

The relationship between the RMS amplitudes of the wind wave spectral components and the wind speed has been studied at ten frequencies in the band of 0.65–23 Hz. To measure the parameters of the high-frequenci waves, a resistance elevation wave gauge was operated, which was deployed in the Black See on an oceanographic platform near Katsively. The correlation between the wave amplitudes and the wind velocity at high frequencies of 5–23 Hz, corresponding to gravitation-capillary ripples, was found to reach a value of 0.8. At lower frequencies of 0.65–4.3 Hz, corresponding to short gravity waves, it dropped to 0.5–0.7. The response of spectral components to the wind speed variations in the gravity-capillary range is higher than in the range of short gravity waves. The results obtained differ from Phillips' idea about a saturated range for the frequency form of the spectrum of high-frequency gravity waves, since a linear dependence of the spectral amplitudes on the wind speed is established at a wind of force 1–8.Translated by Mikhail M. Trufanov.     

Glutathione S-transferase from an antarctic fish, Dissostichus mawsoni

Glutathione S-transferase activity was measured in the hepatic cytosol front Dissostichus mawsoni and Pagothenia borchgrevinki. Activity measures with 1-chloro-2,4-dinitrobenzene as substrate were 11·2 and 16·7 μmol/min/g tissue respectively. Little or no activity was detected when p-nitrobenzyl chloride or 3,4-dichloro-1-nitrobenzene were used as substrate. The hepatic glutathione S-transferases from D. mawsoni were partially purified using gel filtration and chromatofocusing. Three peaks of activity were resolved. The major isozyme (158-fold purification) eluting at pH7·1 appeared to be catalytically a homodimer. The isozyme was highly inhibited by triphenyltin chloride (IC₅₀ = 0·1 μ) while inhibition constants for Cibicron Blue 3GA, bromosulphophalein and hematin were 1·1, 20 and 34 μ respectively.     

Implications from a field study regarding the relationship between polycyclic aromatic hydrocarbons and glutathione S-transferase activity in mussels

An aluminium smelter on the west coast of Scotland discharges an aqueous effluent containing polycyclic aromatic hydrocarbons (PAHs) at the head of Loch Leven. The loch also supports two mussel (Mytilus edulis) farms. Data are presented on burdens of PAHs in the soft tissues of mussels and the effect of these contaminants on glutathione S-transferase (GST) activity in mussel hepatopancreas. GST activity is shown to be correlated with total PAH burden and also with the concentrations of certain individual PAHs. These field data show that high molecular weight PAHs are closely correlated to GST activity, whereas low molecular weight PAHs are not. This suggests that 5- and 6-ring PAHs have a more pronounced role than 2- to 4-ring compounds in inducing GST activity in mussels from Loch Leven. It is proposed that it may be more appropriate to link GST activity with 5- and 6-ring compounds only, rather than with the total PAH burden.