Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

Landslide triggering scenarios in homogeneous geological contexts: The area surrounding Acri (Calabria, Italy)

The paper describes a methodology to detect landslide triggering scenarios in geological homogeneous areas and for some specific landslide categories. In these scenarios, the rainfall–landslide relationship as well as the pluviometric load conditions influencing slope instability have to be investigated.The methodology is applied to an area located in northern Calabria (Italy) and affected by widespread and different slope instability phenomena. Outcropped, fractured, and deeply weathered crystalline rock masses, determining geologic homogeneous conditions, are present. In the same area, suitable and homogeneous climatic features have also been found.According to the methodology adopted, the hydrologic analysis of rainfall time-series is initially carried out notwithstanding historical data concerning landslide mobilization, but using simple models to determine critical pluviometric scenarios for the three landslide categories: shallow, medium-deep, and deep. Landslide-triggering scenarios individualized according to this procedure are less significant as compared to the landslide mobilization detected in the study area by means of historical research and ascribed to the three landslide categories according to geomorphologic analysis.Subsequently, the possible landslide triggering scenarios are outlined by carefully investigating the hydrologic analysis limited to the periods identified according to the historical data.In the study area and approximately for all the areas characterized by the outcrop of fractured and deeply weathered crystalline rocks, significant triggering scenarios can be outlined. In particular, shallow landslide triggers could be activated by rainfall events with intensities exceeding 90 mm/day and/or with amounts exceeding 160 mm. As for medium-deep and deep landslides, triggering mechanisms are more complicated; and effective rainfall contribution must be taken into account compared to groundwater storage. Moreover, a more complex link between deep landslides and precipitation is confirmed.The results obtained to date highlight the potential of this methodology, which enables us to define and progressively improve the knowledge framework by means of a work sequence integrating different disciplinary tools and results.     

Use of Factor Analysis to Study the Distribution of Metalliferous Bauxitic Tailings in the Seabed of the Gulf of Corinth,Greece

In 1994, a detailed marine environmental survey was carried out in surface sediments of the northern flank (Antikyra Bay) and the basin floor of the Gulf of Corinth. Metalliferous tailings (red-mud slurry) of a bauxite processing plant are discharged through a pipeline at a water depth of 100 m, in the Antikyra Bay, covering an area of 16 km². The bauxitic tailings are detached from the main deposit at the outfalls, flow as turbidity currents downslope, and are redeposited on the basin floor of the Gulf of Corinth, where they cover an area of about 277 km². One hundred sediment samples, that were collected from red-mud deposits and the surrounding natural sediments, were analyzed for Ag, Al, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Si, Ti, V, and Zn concentrations. Statistical analysis of the heavy metals concentrations using factor analysis allowed (i) an examination of the interrelations among metals and (ii) distinguishing possible sample groups on the basis of metal concentrations in order to study the mechanisms of transport of the red mud and the degree of mixing with natural sediments. Factor 1 (Al, Cr, Ti, Fe, Co, Ni, Pb, Ag, Hg, V, Cd, and Cu) and the positive pole of Factor 2 (Cu, Ag, Cd, and Hg) are red-mud factors, reflecting different metal behaviors, which are related to processes that take place during the transport and redeposition of the red mud. The negative poles of Factors 2 and 3 and the positive pole of Factor 4 are related to natural sediment supply processes. Q-mode factor analysis identifies three distinct sediment groups located in different areas, on the base of the degree of mixing of red mud with natural sediments.     

REVIEWS

Book reviewed in this article:
GEOGRAPHY, ITS SCOPE AND SPIRIT. By J. O. M. Broek
GEOGRAPHY AS HUMAN ECOLOGY: METHODOLOGY BY EXAMPLE. Edited by S. R. Eyre and G. R. J. Jones
A PREFACE TO ECONOMIC GEOGRAPHY. By H. H. McCarty and J. B. Lindberg
A PROLOGUE TO POPULATION GEOGRAPHY. By W. Zelinsky     

Natural aggregates in the performance and durability of concrete: chemical characteristics

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.     

Dispersion characteristics of low-latitude whistlers

The effect of ions on whistler dispersion characteristics has been studied. It is shown that the significant changes in the dispersion characteristics of low-latitude whistlers are brought about by the presence of ions. The dispersions for Nainital (geomagnetic lat. 19°1'N) and Gulmarg (geomagnetic lat. 24°10'N) are found to peak around 800 Hz. The short whistler sonograms recorded at Nainital and Gulmarg have been analysed, using the complete dispersion equation and the effect of ions has been shown. At higher frequencies the dispersion is found to decrease steadily and becomes independent of ions. Some examples of short whistlers have been found whose characteristics do not conform to the general trend of low-latitude whistlers, and, on the other hand, these whistlers show a constant dispersion unaffected by ions up to a fairly low frequency and thereafter decrease sharply at lower frequencies.