Weathering process at the natural fission reactor of Bangombé

 The uranium deposits in the basin of Franceville (Gabon) host the only natural fission reactors known in the world. Unique geological conditions favoured a natural fission reaction 2 Ga ago. This was detected by anomalous isotopic compositions of uranium and rare earth elements (REE), which are produced by the fission reaction. In total, 16 reactor zones were found. Most of them are mined out. The reactor zone of Bangombé, is only 10–11 m below the surface. This site has been influenced by surface weathering processes. Six drill cores have been sampled at the site of the reactor zone of Bangombé during the course of the study and only one drill core (BAX 08) hit the core of the reactor. From these data and previous drilling campaigns, the reactor size is estimated to be 10 cm thick, 2–3 m wide and 4–6 m long. The migration of fission products can be traced by the anomalous isotope ratios of REE because of the fission process. The ¹⁴⁹Sm/¹⁴⁷Sm ratio close to the reactor zone is only 0.28 (normal: 0.92) because of the intense neutron capture of ¹⁴⁹Sm and subsequent transmutation, whereas ¹⁴⁷Sm is enriched by the fission reaction. Similar changes in isotopic patterns are detectable on other REE. The isotope ratios of Sm and Nd of whole rock and fracture samples surrounding the reactor indicate that fission-genic REE migrated only a few decimetres above and mainly below the reactor zone. Organic matter (bitumen) seems to act as a trap for fission-genic REE. Additional REE-patterns show less intense weathering with increasing depth in the log profile and support a simple weathering model. Received: 26 November 1999 · Accepted: 2 May 2000     

Characterization of soil's structural crust by spectral reflectance in the SWIR region (1.2–2.5 μm)

Structural crust is a thin layer formed on the soil surface after a rainstorm. The crust is the result of a physical segregation and rearrangement of soil particles in a way that affects some of the soil properties, such as infiltration, runoff and soil erosion. In practice, there is no rapid, in situ method for monitoring, assessing and mapping crust intensity and quality. In this study, a controlled spectral investigation of the structural crust across the NIR–SWIR spectral region was conducted on three selected Israeli soils, to study the potential of reflectance radiation to detect structural crust in soils. Two major factors served as the driving forces for this study: (1) there is no valid method for in situ assessment of the crust's characteristics in the agriculture field, and (2) the crust might bias thematic remote sensing of soils, because the thin layer of crust blocks photon–matter interaction, which represents the relevant soil body. Through the use of a laboratory rainfall simulator and a sensitive spectrometer, it was revealed that for three selected soils, significant spectral differences occurred between the crust and its bulk soil. The spectral information was found to be related to changes in particle size distribution and texture at the surface of the soil. This conclusion was based on indications of absorption of OH in clay lattice, OH in adsorbed water and CO₃ in carbonates. It was concluded that the structural crust is a phenomenon that should not be ignored by remote-sensing users. In fact, in the field of agriculture, the spectral properties of crust can be used as tools for estimating the crust's intensity.     

Deep-ocean vertical noise directionality

The structure of beam noise measured at the output of a vertical array in a range dependent ocean basin was investigated using the modified wide-angle parabolic equation (PE). Noise sources were distributed throughout the basin, and the field due to each noise source at an array located in the midbasin was calculated. The response of the array to the superposition of the noise sources was found by beamforming. An efficient and direct approach that superimposes the noise sources on the PE field as the field is marched toward the array was developed. Downslope calculations of the midbasin vertical directionality were made between 50 and 400 Hz with this technique. Use of a geoacoustic model shows that the bottom behaves as a low-pass filter     

Depositional and post‐depositional history of warm stage deposits at Knocknacran,Co. Monaghan,Ireland: implications for preservation of Irish last interglacial deposits

Organic‐rich deposits, uncovered during overburden removal from mantled gypsum karst at Knocknacran opencast gypsum mine, Co. Monaghan, are the best candidate to date for a last interglacial record in Ireland. The two till and organic‐rich deposits (preserved at different quarry elevations) were emplaced on to a Tertiary dolerite surface during high‐energy flood events and subsequently folded and faulted by movement towards sinkholes in underlying gypsum. Uranium–thorium disequilibrium dating suggests that the organic‐rich deposits in the upper section were hydrologically isolated at ca. 41 ka and those in the lower section at ca. 86 ka. Interpretation of the pollen content, although tentative because of the depositional and post‐depositional history of the material, suggests that the organic material originated in a warm stage possibly warmer than the post‐Eemian interstadials. The unusual setting of preservation may indicate that in situ, last interglacial deposits have generally been removed by erosion in Ireland. Copyright © 2004 John Wiley & Sons, Ltd.     

Survival,growth and shell deformities of copper- and cadmium-exposed mussels (Mytilus edulis L.) in brackish water

Mussels, Mytilus edulis L., were exposed to elevated concentrations of copper or cadmium in the laboratory, then placed in cages in the sea (salinity 7‰). One year later maximum lengths of the mussels were measured and shells screened for deformities. Growth was 0·6 cm year^?1 in the control cages and retarded in cages of exposed mussels. A total of 63% of cadmium-exposed and 46% of copper-exposed mussels had shell deformities. In the control cages 26% were deformed while in a natural population only 3% were deformed. The proportion of deformities to growth was inversely related. Low concentrations showed their injuriousness in this long-term test, probably due to the closing of the valves during exposure to high concentrations.     

Factors affecting the distribution and abundance of Macrobrachium petersi (Hilgendorf) in the Keiskamma River and estuary,South Africa

A dry (1979–1980) and a wet (1980–1981) season had a marked effect on the freshwater inflow into the Keiskamma estuary. Under low inflow conditions, which results in elevated salinities in the upper reaches, an upstream migration of adult Macrobrachium petersi (Hilgendorf) to freshwater takes place. During periods of increased river inflow adult M. petersi move downstream to the more saline reaches of the estuary. These two migratory responses have been interpreted as (a) a breeding migration under high inflow conditions which ensures that larvae are in close proximity to salinities that favour growth and development, and (b) an adult upstream migration back to freshwater to escape elevated estuarine salinities as a result of the low freshwater inflow.     

Volcanic style in the Strand Fiord Formation (Upper Cretaceous), Axel Heiberg Island, Canadian Arctic Archipelago

The Strand Fiord Formation is a volcanic unit of early Late Cretaceous age which outcrops on west-central and northwestern Axel Heiberg Island in the Canadian Arctic Archipelago. The formation is part of the thick Sverdrup Basin succession and immediately precedes the final basin foundering event. The Strand Fiord volcanics are encased in marine strata and thin southward from a maximum thickness of 789+ m on northwestern Axel Heiberg to a zero edge near the southern shore of the island. Tholeiitic icelandite flows are the main constituent of the formation with volcaniclastic conglomerates, sandstones, mudrocks and rare coal seams also being present. The lava flows range in thickness from 6 to 60 m and subaerial flows predominate. Both pahoehoe and aa lava types are common and the volcanic pile accumulated mostly by the quiet effusion of lavas. The volcaniclastic lithologies become more common near the southern and eastern edges of the formation and represent lahars and beach to shallow marine reworked deposits. The Strand Fiord volcanics are interpreted to represent the cratonward extension of the Alpha Ridge, a volcanic ridge that was active during the formation of the Amerasian Basin.     

Purana basins of peninsular India: a review

Seven supracratonic, Proterozoic basins, occupying more than a fifth of the Precambrian exposures in the Indian Peninsula, comprise the Purana basins. A comprehensive review of the current status of knowledge of these voluminous orthoquartzite-carbonate-shale suites in the context of their contemporary lithostratigraphy, depositional environments and structural disposition is presented. Stromatolite biostratigraphy and available geochronological data are compared, to discern their age limits.
These basins contain perhaps one of the most elaborate records of Middle to Late Proterozoic (Riphean-Vendian) sedimentation preserved in an unmetamorphosed and only slightly deformed state. Further sedimentological and structural studies could lead to a better understanding of the Proterozoic craton-margin processes. Their close association with the Middle Proterozoic Mobile Belt of peninsular India is that of two contrasting tectonic regimes, contemporaneously adjoining each other. The existing lithostratigraphic classifications of many of these sequences may not stand the test of process - response considerations as demonstrated by the recent revisions in the stratigraphy of the Cuddapah and Bhima basins. The prolific stromatolitic, micro-organic and trace-fossil communities preserved in them require much more detailed, but cautious study, and may yield information on the Riphean-Vendian biota. However, these studies must be undertaken in association with elaborate geochronological determinations which are sparse at present.
Inadequacy of the existing knowledge of these basins is highlighted, with the view of inviting the attention of the geological community to these unique basins from peninsular India.     

The estimation of the shape of an array using a hidden Markov model

A hidden Markov model (HMM) technique for the estimation of the shape of a towed array is presented. It is assumed that there is a far-field source radiating sound containing possibly weak spectral lines. The technique uses either the Fourier coefficients at a given frequency computed from a single time block or the maximal eigenvector of a sample spectral covariance matrix. The technique is illustrated using several simulations. The results of these simulations indicate that the HMM technique yields shape and bearing estimates more accurate than those provided by a maximum-likelihood array shape estimation technique     

Cokriging nonstationary data

Universal cokriging is used to obtain predictions when dealing with multivariate random functions. An important type of nonstationarity is defined in terms of multivariate random functions with increments which are stationary of orderk. The covariance between increments of different variables is modeled by means of the pseudo-cross-covariance function. Criteria are formulated to which the parameters of pseudo-cross-covariance functions must comply so as to ensure positive-definiteness. Cokriging equations and the induced cokriging equations are given. The study is illustrated by an example from soil science.