Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.     

Isotopic signatures of deposition and transformation of Lower Cambrian saliferous rocks in the Irkutsk amphitheater: Communication 1. Sulfur isotopic composition

New isotope data on Lower Cambrian rocks of the Irkutsk amphitheater are reported in three communications. The first communication is devoted to the sulfur isotopic composition, which is most sensitive to ostsedimentary geochemical transformations of sulfate rocks in saliferous formations. It is shown that δ³⁴S values in Bel’sk and Zhigalovo boreholes are within 22–35‰ The lowest values are close to the sulfur isotopic composition of a halogenic basin, while the highest values are related to epigenetic sulfate reduction. This process was responsible for the elimination of 100 m of anhydrites from the Lower Cambrian section.     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.     

Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey)

In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.     

Effect of sampling and linkage on fault length and length–displacement relationship

The power-law exponent (n) in the equation: D=cL ⁿ , with D = maximum displacement and L = fault length, would be affected by deviations of fault trace length. (1) Assuming n=1, numerical simulations on the effect of sampling and linkage on fault length and length–displacement relationship are done in this paper. The results show that: (a) uniform relative deviations, which means all faults within a dataset have the same relative deviation, do not affect the value of n; (b) deviations of the fault length due to unresolved fault tip decrease the values of n and the deviations of n increase with the increasing length deviations; (c) fault linkage and observed dimensions either increase or decrease the value of n depending on the distribution of deviations within a dataset; (d) mixed deviations of the fault lengths are either negative or positive and cause the values of n to either decrease or increase; (e) a dataset combined from two or more datasets with different values of c and orders of magnitude also cause the values of n to deviate. (2) Data including 19 datasets and spanning more than eight orders of fault length magnitudes (10⁻²–10⁵ m) collected from the published literature indicate that the values of n range from 0.55 to 1.5, the average value being 1.0813, and the peak value of n _d (double regression) is 1.0–1.1. Based on above results from the simulations and published data, we propose that the relationship between the maximum displacement and fault length in a single tectonic environment with uniform mechanical properties is linear, and the value of n deviated from 1 is mainly caused by the sampling and linkage effects.