Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.     

Synchronous pattern of moisture availability on the southern Tibetan Plateau since 17.5 cal. ka BP – the Tangra Yumco lake sediment record

A possible asynchronicity of the spatial and temporal moisture availability on the Tibetan Plateau has been a controversial subject of discussion in recent years. Here we present the first attempt to systematically investigate possible spatial and temporal variations in moisture availability by examining two lakes, Tangra Yumco and Nam Co, on an east–west transect on the southern Tibetan Plateau using identical proxies for palaeoenvironmental reconstruction. In this study, an independent record from Tangra Yumco was analysed applying a multi‐proxy approach to reconstruct variations in moisture availability since the Lateglacial. Results were subsequently compared with previously published records from Nam Co and additional records from Tso Moriri (northwestern Himalaya) and Naleng Co (southeastern Tibetan Plateau). Our results show that Tangra Yumco was at least partially ice covered prior to 17.1 cal. ka BP. A temperature rise after 17.1 cal. ka BP probably resulted in thawing of the permafrost. At 16.0 cal. ka BP moisture availability increased, representing an initial monsoonal intensification. Warmer conditions between 13.0 and 12.4 cal. ka BP and cooler conditions between 12.4 cal. ka BP and the onset of the Holocene reflect the Bølling‐Allerød and Younger Dryas. At the onset of the Holocene moisture availability rapidly increased, with moisture highest prior to 8.5 cal. ka BP when temperatures were also highest. After 8.5 cal. ka BP the moisture availability gradually decreased and showed only minor amplitude variations. These findings are consistent with the records from large lakes like Nam Co, Tso Moriri, and Naleng Co, revealing a synchronous pattern of moisture availability on the southern Tibetan Plateau.     

Local air temperature tolerance: a sensible basis for estimating climate variability

The customary representation of climate using sample moments is generally biased due to the noticeably nonstationary behaviour of many climate series. In this study, we introduce a moment-free climate representation based on a statistical model fitted to a long-term daily air temperature anomaly series. This model allows us to separate the climate and weather scale variability in the series. As a result, the climate scale can be characterized using the mean annual cycle of series and local air temperature tolerance, where the latter is computed using the fitted model. The representation of weather scale variability is specified using the frequency and the range of outliers based on the tolerance. The scheme is illustrated using five long-term air temperature records observed by different European meteorological stations.     

Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.     

Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.