A high resolution,multiproxy Late‐glacial record of climate change and intrasystem responses in northwest England

A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.     

Late Quaternary vegetation changes around Lake Rutundu,Mount Kenya,East Africa: evidence from grass cuticles,pollen and stable carbon isotopes

Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C₄ photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C₄ grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC₄ subpathway. Copyright © 2003 John Wiley & Sons, Ltd.     

The Pleistocene history of Wales and the borderland

The Pleistocene rock-stratigraphic record is accorded more or less traditional time-stratigraphic interpretation which was held widely before application of an Irish developmental model in 1960. The following sequence of events are recognised: (1) Complete glaciation, of indeterminate age, which antedated the raised beach interglacial. (2) The raised beach episode which is shown to be the last (Ipswichian) interglacial. (3) The last (Devensian/Weichselian) glaciation, followed by possible readvance in northwest and northeast Wales; prior and subsequent to glaciation periglacial conditions obtained. It is shown that the Irish model, relying heavily as it does on the equation of rock and time stratigraphy, is inapplicable in Wales.     

Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

柴达木盆地北缘大柴旦地区古生代花岗岩锆石SHRIMP定年

大柴旦地区是柴北缘古生代超高压带的重要组成部分,与超高压岩石相伴的花岗岩十分发育。这些花岗岩具有两类不同的岩石地球化学特征,Ⅰ类以 Na_2O/K_2O 比值小于1、明显的负 Eu 异常和低 Sr、高 Y 为特征,具有 S-型花岗岩的属性,Ⅱ类以 Na_2O/K_2O 比值大于1、弱负 Eu 异常到正 Eu 异常和高 Sr、低 Y 为特征,具有Ⅰ-型花岗岩的属性,反映了它们的源岩及成因上的差异。锆石 SHRIMP U—Ph 定年结果表明,大柴旦地区花岗岩的年龄可分为三组,第一组年龄为446.3±3.9Ma,第二组年龄分别为408.6±4.4Ma、403.3±3.8Ma、401.8±3Ma,第三组年龄分别为374.5±1.6Ma、372±2.1Ma。结合区域地质特征,我们认为,第一组年龄可能反映了柴达木陆块与中南祁连板块碰撞的时代,第二组年龄可能反映了深俯冲地下的板块由于拆沉而折返的时代,第三组年龄可能反映了碰撞隆起后造山带上不同块体之间的伸展、滑塌的时代。     

Precipitation variability during the past 400?years in the Xiaolong Mountain (central China) inferred from tree rings

We developed the first tree-ring chronology, based on 73 cores from 29 Pinus tabulaeformis trees, for the Xiaolong Mountain area of central China, a region at the boundary of the Asian summer monsoon. This chronology exhibits significant (at 0.01 level) positive correlations with precipitation in May and June, and negative correlations with temperature in May, June and July. Highest linear correlation is observed between tree growth and the seasonalized (April–July) precipitation, suggesting that tree rings tend to integrate the monthly precipitation signals. Accordingly, the April–July total precipitation was reconstructed back to 1629 using these tree rings, explaining 44.7?% of the instrumental variance. A severe drought occurred in the area during the 1630s–1640s, which may be related to the weakened Asian summer monsoon caused by a low land-sea thermal gradient. The dry epoch during the 1920s–1930s and since the late 1970s may be explained by the strengthened Hadley circulation in a warmer climate. The dry (wet) epochs of the 1920s–1930s (the 1750s and 1950s) occurred during the warm (cold) phases of the El Ni?o-Southern Oscillation and the Pacific Decadal Oscillation that are often associated with weakened (strengthened) East Asian summer monsoon. These relationships indicate significant teleconnections operating over the past centuries in central China related to large-scale synoptic features.     

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.