全文获取类型
收费全文 | 1595篇 |
免费 | 40篇 |
国内免费 | 23篇 |
专业分类
测绘学 | 53篇 |
大气科学 | 159篇 |
地球物理 | 279篇 |
地质学 | 616篇 |
海洋学 | 124篇 |
天文学 | 289篇 |
综合类 | 11篇 |
自然地理 | 127篇 |
出版年
2023年 | 9篇 |
2021年 | 17篇 |
2020年 | 17篇 |
2019年 | 17篇 |
2018年 | 34篇 |
2017年 | 28篇 |
2016年 | 40篇 |
2015年 | 25篇 |
2014年 | 44篇 |
2013年 | 70篇 |
2012年 | 54篇 |
2011年 | 74篇 |
2010年 | 74篇 |
2009年 | 117篇 |
2008年 | 78篇 |
2007年 | 96篇 |
2006年 | 77篇 |
2005年 | 86篇 |
2004年 | 53篇 |
2003年 | 48篇 |
2002年 | 52篇 |
2001年 | 41篇 |
2000年 | 40篇 |
1999年 | 29篇 |
1998年 | 26篇 |
1997年 | 21篇 |
1996年 | 20篇 |
1995年 | 19篇 |
1994年 | 21篇 |
1993年 | 16篇 |
1992年 | 15篇 |
1991年 | 14篇 |
1990年 | 14篇 |
1988年 | 12篇 |
1986年 | 11篇 |
1985年 | 15篇 |
1984年 | 13篇 |
1983年 | 22篇 |
1982年 | 16篇 |
1981年 | 15篇 |
1980年 | 12篇 |
1979年 | 9篇 |
1978年 | 9篇 |
1977年 | 8篇 |
1976年 | 15篇 |
1975年 | 8篇 |
1973年 | 15篇 |
1972年 | 15篇 |
1971年 | 11篇 |
1970年 | 9篇 |
排序方式: 共有1658条查询结果,搜索用时 15 毫秒
41.
Rabindra N Roy Lakshimi N Roy Kathleen M Vogel C Porter-Moore Tara Pearson Catherine E Good Frank J Millero Douglas M Campbell 《Marine Chemistry》1993,44(2-4)
The pK1* and pK2* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK1* have been determined from emf measurements for the cell: where X is the mole fraction of CO2 in the gas. The values of pK2* have been determined from emf measurements on the cell: The results have been fitted to the equations: where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK1* and σ = 0.0070 in lnK2*.Our new results are in good agreement at S = 35 (±0.002 in pK1*and ±0.005 in pK2*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H2|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater. 相似文献
Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag
Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag
lnK*1 = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S0.5 + 0.08468345S − 0.00654208S1
InK*2 = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S0.5 + 0.1130822S − 0.00846934S1.5
42.
43.
44.
Euglena gracilis makes two small Cd-binding proteins/peptides (Cd-BP I and Cd-BP II) in response to exposure to Cd2+. These proteins migrate slower than mammalian Cd-metallothionein (Cd-Mt) through Sephadex G-75, but like Cd-Mt also contain Zn and are separated into two species when chromatographed over a DEAE column. Both BPs are much less stable than Cd-Mt under acidic conditions. One source of this instability is that at least Cd-BP II contains acid-labile sulfide co-ordinated to the metals. It has been quantitated in Cd-BP II and shown to have a value of 1·25 ± 0·10 S2−/Cd. The reactivity of the Cd-binding sites in ligand substitution and thioldisulfide exchange reactions has been assessed. The reactions of Cd-BP I and II with pyridylazoresorcinol (PAR) were slow and displayed complex kinetic behavior. Similarly, both Cd-BPs react slowly and with complicated kinetics with 5,5′-dithiobis-(2-nitrobenzoate). 相似文献
45.
Jesper Raakjær Dao Manh Son Karl-Johan Stæhr Holger Hovgård Nguyen Thi Dieu Thuy Kristine Ellegaard Frank Riget Dang Van Thi Phung Giang Hai 《Marine Policy》2007
Vietnam is in the process of introducing adaptive management based on indicators and time-series to manage its marine fisheries. The development of indicator-based frameworks for fisheries management has accelerated in recent years. This article describes the suite of indicators being suggested or used in Vietnam including the data-collection system. The Vietnamese approach is supported by an institutional structure consisting of a multi-disciplinary advisory system to facilitate the process of using indicators and to introduce knowledge-based management. The article concludes by identifying current problems and weaknesses and by providing suggestions for future improvement of the system. 相似文献
46.
47.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2