The effect of alkalis and polymerization on the solubility of H<Subscript>2</Subscript>O and CO<Subscript>2</Subscript> in alkali-rich silicate melts

The effect of alkalis on the solubility of H₂O and CO₂ in alkali-rich silicate melts was investigated at 500 MPa and 1,250 °C in the systems with H₂O/(H₂O + CO₂) ratio varying from 0 to 1. Using a synthetic analog of phonotephritic magma from Alban Hills (AH1) as a base composition, the Na/(Na + K) ratio was varied from 0.28 (AH1) to 0.60 (AH2) and 0.85 (AH3) at roughly constant total alkali content. The obtained results were compared with the data for shoshonitic and latitic melts having similar total alkali content but different structural characteristics, e.g., NBO/T parameter (the ratio of non-bridging oxygens over tetrahedrally coordinated cations), as those of the AH compositions. Little variation was observed in H₂O solubility (melt equilibrated with pure H₂O fluid) for the whole compositional range in this study with values ranging between 9.7 and 10.2 wt. As previously shown, the maximum CO₂ content in melts equilibrated with CO₂-rich fluids increases strongly with the NBO/T from 0.29 wt % for latite (NBO/T = 0.17) to 0.45 wt % for shoshonite (NBO/T = 0.38) to 0.90 wt % for AH2 (NBO/T = 0.55). The highest CO₂ contents determined for AH3 and AH1 are 1.18 ± 0.05 wt % and 0.86 ± 0.12 wt %, respectively, indicating that Na is promoting carbonate incorporation stronger than potassium. At near constant NBO/T, CO₂ solubility increases from 0.86 ± 0.12 wt % in AH1 [Na/(Na + K)] = 0.28, to 1.18 ± 0.05 wt % in AH3 [Na/(Na + K)] = 0.85, suggesting that Na favors CO₂ solubility on an equimolar basis. An empirical equation is proposed to predict the maximum CO₂ solubility at 500 MPa and 1,100–1,300 °C in various silicate melts as a function of the NBO/T, (Na + K)/∑cations and Na/(Na + K) parameters: \({\text{wt}}\% \;{\text{CO}}_{2} = - 0.246 + 0.014\exp \left( {6.995 \cdot \frac{\text{NBO}}{T}} \right) + 3.150 \cdot \frac{{{\text{Na}} + {\text{K}}}}{{\varSigma {\text{cations}}}} + 0.222 \cdot \frac{\text{Na}}{{{\text{Na}} + {\text{K}}}}.\) This model is valid for melt compositions with NBO/T between 0.0 and 0.6, (Na + K)/∑cation between 0.08 and 0.36 and Na/(Na + K) ratio from 0.25 to 0.95 at oxygen fugacities around the quartz–fayalite–magnetite buffer and above.     

How light affect the magnetotactic behavior and reproduction of ellipsoidal multicellular magnetoglobules?

Journal of Oceanology and Limnology - Magnetotactic bacteria (MTB) synthesize intracellular magnetic organelles, magnetosomes, which consist of magnetic crystals that are enveloped in a membrane....     

GMRT and VLA observations at 49 cm and 20 cm of the HII region near <Emphasis Type="Italic">l</Emphasis> = 24.8°, <Emphasis Type="Italic">b</Emphasis> = 0.1°

We report multi-frequency radio continuum and hydrogen radio recombination line observations of HII regions near l = 24.8°, b = 0.1° using the Giant Metrewave Radio Telescope (GMRT) at 1.28 GHz (n = 172), 0.61 GHz (n = 220) and the Very Large Array (VLA) at 1.42 GHz (n = 166). The region consists of a large number of resolved HII regions and a few compact HII regions as seen in our continuum maps, many of which have associated infrared (IR) point sources. The largest HII region at l = 24.83° and b = 0.1° is a few arcmins in size and has a shell-type morphology. It is a massive HII region enclosing ∼550 M_⊙ with a linear size of 7 pc and an rms electron density of ∼110 cm⁻³ at a kinematic distance of 6 kpc. The required ionization can be provided by a single star of spectral type O5.5. We also report detection of hydrogen recombination lines from the HII region at l = 24.83° and b = 0.1° at all observed frequencies near V _lsr = 100 km s⁻¹. We model the observed integrated line flux density as arising in the diffuse HII region and find that the best fitting model has an electron density comparable to that derived from the continuum. We also report detection of hydrogen recombination lines from two other HII regions in the field.     

A spectroscopic study of the surfaces of Saturn's large satellites: H2O ice, tholins, and minor constituents

We present spectra of Saturn's icy satellites Mimas, Enceladus, Tethys, Dione, Rhea, and Hyperion, 1.0-2.5 μm, with data extending to shorter (Mimas and Enceladus) and longer (Rhea and Dione) wavelengths for certain objects. The spectral resolution (R=λ/Δλ) of the data shown here is in the range 800-1000, depending on the specific instrument and configuration used; this is higher than the resolution (R=225 at 3 μm) afforded by the Visual-Infrared Mapping Spectrometer on the Cassini spacecraft. All of the spectra are dominated by water ice absorption bands and no other features are clearly identified. Spectra of all of these satellites show the characteristic signature of hexagonal H₂O ice at 1.65 μm. We model the leading hemisphere of Rhea in the wavelength range 0.3-3.6 μm with the Hapke and the Shkuratov radiative transfer codes and discuss the relative merits of the two approaches to fitting the spectrum. In calculations with both codes, the only components used are H₂O ice, which is the dominant constituent, and a small amount of tholin (Ice Tholin II). Tholin in small quantities (few percent, depending on the mixing mechanism) appears to be an essential component to give the basic red color of the satellite in the region 0.3-1.0 μm. The quantity and mode of mixing of tholin that can produce the intense coloration of Rhea and other icy satellites has bearing on its likely presence in many other icy bodies of the outer Solar System, both of high and low geometric albedos. Using the modeling codes, we also establish detection limits for the ices of CO₂ (a few weight percent, depending on particle size and mixing), CH₄ (same), and NH₄OH (0.5 weight percent) in our globally averaged spectra of Rhea's leading hemisphere. New laboratory spectral data for NH₄OH are presented for the purpose of detection on icy bodies. These limits for CO₂, CH₄, and NH₄OH on Rhea are also applicable to the other icy satellites for which spectra are presented here. The reflectance spectrum of Hyperion shows evidence for a broad, unidentified absorption band centered at 1.75 μm.     

Spin axis of (2953) Vysheslavia and its implications

Photometric observations made during the years 2000-2005 are used to determine the pole orientation of (2953) Vysheslavia, a ?15-km size member of the Koronis family. We find admissible solutions for ecliptic latitude and longitude of the rotation pole P₃: βp=−64°±10° and λp=11°±8° or P₄: βp=−68°±8° and λp=192°±8°. These imply obliquity values γ=154°±14° and γ=157°±11°, respectively. The sidereal rotation period is Psid=0.2622722±0.0000018 day. This result is interesting for two reasons: (i) the obliquity value between 90° and 180° is consistent with a prediction done by Vokrouhlický et al. [Vokrouhlický, D., Bro?, M., Farinella, P., Kne?evi?, Z., 2001. Icarus 150, 78-93] that Vysheslavia might have been transported to its unstable orbit by the Yarkovsky effect, and (ii) with the obliquity close to 180°, Vysheslavia seems to belong to one of the two distinct groups in the Koronis family found recently by Slivan [Slivan, S.M., 2002. Nature 419, 49-51], further supporting the case of dichotomy in the spin axis distribution in this family. We also argue against the possibility that Vysheslavia reached its current orbit by a recent collisional breakup.     

Climatic change in Central Asia during MIS 3/2: a case study using biological responses from Lake Baikal

A Marine Isotope Stage (MIS) 3/early MIS 2 section from a structural high along the east coast of the North Basin of Lake Baikal was analysed for diatoms, C/N ratios, and organic carbon isotope ratios. Diatoms were present throughout MIS 3 and early MIS 2, with high concentrations of the planktonic taxa Cyclotella sp. c.f. gracilis between 54 and 51.5 kyr BP indicating relatively warm, interstadial, conditions. Following a %TOC inferred climatic cooling between 43.2 and 39.1 kyr BP, evidence of a more muted δ¹³C_(organic) and %TOC inferred climatic warming from c. 39.1–34.7 kyr BP coincides with a period of very high diatom concentrations, indicating high aquatic productivity, at the Buguldeika Saddle in the South Basin of Lake Baikal. No evidence exists for a ‘Kuzmin’ catchment erosional event in the North Basin during MIS 3. This, however, may reflect the location of the coring site away from major riverine inputs. Abrupt climatic cooling at the culmination of both warm phases in the North Basin are associated, on the basis of the palaeomagnetic age-model and correlations to existing sites in Lake Baikal, with the initiation of Heinrich events 5 (c. 50 kyr BP) and 4 (c. 35 kyr BP), respectively, in the North Atlantic. The amount of organic material declines across the MIS 3/MIS 2 transition while constant C/N ratios suggest organic material to be predominantly derived from phytoplankton. An increase in δ¹³C_(organic) at the MIS 3/MIS 2 transition may therefore indicate changes in aquatic productivity, pCO₂ or the inorganic carbon pool.     

Figure of the double Asteroid 90 Antiope from adaptive optics and lightcurve observations

A long-term adaptive optics (AO) campaign of observing the double Asteroid (90) Antiope has been carried out in 2003-2005 using 8-10-m class telescopes, allowing prediction of the circumstances of mutual events occurring during the July 2005 opposition [Marchis, F., Descamps, P., Hestroffer, D., Berthier, J., de Pater, I., 2004. Bull. Am. Astron. Soc. 36, 1180]. This is the first opportunity to use complementary lightcurve and AO observations to extensively study the (90) Antiope system, an interesting visualized binary doublet system located in the main belt. The orbital parameters derived from the AO observations have served as input quantities for the derivation of a whole set of other physical parameters (namely shapes, surface scattering, bulk density, and internal properties) from analysis of collected lightcurves. To completely model the observed lightcurves, we employed Roche figures to construct an overall shape solution. The combination of these complementary observations has enabled us to derive a reliable physical and orbital solution for the system. Our model is consistent with a system of slightly non-spherical components, having a size ratio of 0.95 (with Ravg=42.9±0.5 km, separation=171±1 km), and exhibiting equilibrium figures for homogeneous rotating bodies. A comparison with grazing occultation event lightcurves suggests that the real shapes of the components do not depart from Roche equilibrium figures by more than 10%. The J2000 ecliptic coordinates of the pole of the system are λn=200°±2° and αn=38°±2°. The orbital period was refined to P=16.5051±0.0001 h, and the density is found to be slightly lower than previous determinations, with a value of 1.25±0.05 g/cm³, leading to a significant macro-porosity of 30%. Possible scenarios for the origin of the system are also discussed.     

The self-organizing map,a new approach to apprehend the Madden–Julian Oscillation influence on the intraseasonal variability of rainfall in the southern African region

The Madden–Julian Oscillation (MJO) is the major mode of intraseasonal variability (30–60 days) in the tropics, having large rainfall impacts globally, and possibly on southern Africa. However, the latter impact is not well understood and needs to be further explored. The life cycle of the MJO, known to be asymmetric, has been nevertheless analyzed usually through methods constrained by both linearity and orthogonality, such as empirical orthogonal function analysis. Here we explore a non-linear classification method, the self-organizing map (SOM), a type of artificial neural network used to produce a low-dimensional representation of high-dimensional datasets, to capture more accurately the life cycle of the MJO and its global impacts. The classification is applied on intraseasonal anomalies of outgoing longwave radiation within the tropical region over the 1980–2009 period. Using the SOM to describe the MJO is a new approach, complimentary to the usual real-time multivariate MJO index. It efficiently captures this propagative phenomenon and its seasonality, and is shown to provide additional temporal and spatial information on MJO activity. For each node, the subtropical convection is analyzed, with a particular focus on the southern Africa region. Results show that the convection activity over the central tropical Indian Ocean is a key factor influencing the intraseasonal convective activity over the southern African region. Enhanced (suppressed) convection over the central Indian Ocean tends to suppress (enhance) convection over the southern African region with a 10-day lag by modulating the moisture transport.