Molecular evidence for life in the 3.5 billion year old Warrawoona chert

The biological origin of organic matter in the oldest siliceous sediments (cherts) is still debated. To address this issue, the insoluble organic matter (kerogen) was isolated from a chert of the Warrawoona group. The chemical structure of the kerogen was investigated through a combination of analytical techniques including solid-state ¹³C nuclear magnetic resonance and pyrolysis. Although dominated by aromatic hydrocarbons, the pyrolysate comprises a homologous series of long chain aliphatic hydrocarbons characterized by odd-over-even carbon number predominance. This distribution is only consistent with a biological origin. As kerogen must be contemporaneous of the solidification of the chert, this observation should be regarded as an evidence for the presence of life on Earth, 3.5 By ago.     

Occurence of abundant diradicaloid moieties in the insoluble organic matter from the Orgueil and Murchison meteorites: a fingerprint of its extraterrestrial origin?

The highly aromatic structure of the macromolecular organic matter (OM) of the Murchison and Orgueil meteorites was recently shown to contain free organic radicals which are concentrated in micro-regions in contrast with terrestrial samples which always show an homogeneous distribution of radicals. An additional signature is revealed, in the present study, by the evolution of the radical concentration with temperature. Whereas in terrestrial samples, this concentration is independent of temperature (Curie magnetism), a significant increase is observed above 150 K in the two meteorites. Based on the electronic structure of organic radicals, calculated by Extended Hückel and Density Functional methods, this behavior was assigned to the occurrence of diradicaloid moieties hosted by aromatic structures of 10 to 15 rings and having a quinoidal structure. They represent 40 and 25% of the total radicals in Orgueil and Murchison, respectively. The search for the cosmochemical interpretation of this unique observation should open a new field of experimental investigations.     

Arsenic in an alkaline AMD treatment sludge: Characterization and stability under prolonged anoxic conditions

Lime treatment of acid mine drainage (AMD) generates large volumes of neutralization sludge that are often stored under water covers. The sludge consists mainly of calcite, gypsum and a widespread ferrihydrite-like Fe phase with several associated species of metal(loid) contaminants. The long-term stability of metal(loid)s in this chemically ill-defined material remains unknown. In this study, the stability and speciation of As in AMD sludge subjected to prolonged anoxic conditions is determined. The total As concentration in the sludge is 300 mg kg⁻¹. In the laboratory, three distinct water cover treatments were imposed on the sludge to induce different redox conditions (100%N₂, 100%N₂ + glucose, 95%N₂:5%H₂). These treatments were compared against a control of oxidized, water-saturated sludge. Electron micro-probe (EMP) analysis and spatially resolved synchrotron X-ray fluorescence (SXRF) results indicate that As is dominantly associated with Fe in the sludge. In all treatments and throughout the experiment, measured concentrations of dissolved As were less than 5 μg L⁻¹. Dissolved Mn concentration in the N₂ + glucose treatment increased significantly compared to other treatments. Manganese and As K-edge X-ray absorption near edge structure spectroscopy (XANES) analyses showed that Mn was the redox-active element in the solid-phase, while As was stable. Arsenic(V) was still the dominant species in all water-covered sludges after 9 months of anoxic treatments. In contrast, Mn(IV) in the original sludge was partially reduced into Mn(II) in all water-covered sludges. The effect was most pronounced in the N₂ + glucose treatment, suggesting microbial reduction. Micro-scale SXRF and XANES analysis of the treated sludge showed that Mn(II) accumulated in areas already enriched in Fe and As. Overall, the study shows that AMD sludges remain stable under prolonged anoxic conditions. External sources of chemical reductants or soluble C were needed to induce lower redox state in the systems, and even under these imposed treatments, only weakly reducing conditions (Mn threshold) developed. The results suggest that As(V) in AMD sludge will remain stable under prolonged anoxic conditions as long as Mn(IV) is present and organic matter accumulation is negligible.     

Insects as zoogeomorphic agents: an extended review

Insects are the largest and most diverse group of living organisms on Earth, playing a critical but underestimated role as agents of geomorphic change. Burrowing insects create micro-scale landforms such as subterranean tunnels and surface mounds and, by this way, exert an influence on hydrology, soil erosion and sediment transfer at a wider landscape scale. However, social insects represented by ants and termites were the main taxa studied as geomorphic agents and ecosystem engineers. This article proposes an extended and critical literature review of insects as zoogeomorphic agents, with reference to various taxonomic orders and families of insects having a burrowing behaviour. It provides a large overview of their primary and secondary impacts on Earth surface systems, both supported by naturalistic evidence and available quantitative data. Some evolutionary insights are discussed based on fossil evidence of geomorphic work by insects and, at finer temporal scale, on recent advances in radiometric and luminescence dating of insect mounds. Finally, this article explores the fruitful links between geomorphology and entomology, and suggests several research perspectives in order to develop an integrated understanding of the importance of insects in Earth surface processes and landforms. © 2020 John Wiley & Sons, Ltd.     

Description de deux nouvelles Cyclotelles (Bacillariophyceae) de milieux alcalins et eutrophes:Cyclotella costei nov. sp. etCyclotella wuethrichiana nov. sp.

Two new species of the genus Cyclotella are presented which have been discovered during ecological and paleoecological research studies in the littoral zone of two small alkaline eutrophic lakes in France (Lake Paladru) and in Switzerland (Lake Le Loclat). These new species are namedCyclotella costei nov. sp. andCyclotella wuethrichiana nov. sp.     

The stratospheric quasi-biennial oscillation observed in the semidiurnal ground pressure data

Ground pressure observations made at Macao (22^○N, 113^○E) from 1953 to 1991 are analyzed and compared with the stratospheric quasi-biennial oscillation (QBO) data obtained during the same interval. The periods of the two phenomena and their time evolution are found to be close to each other. Furthermore, the time series of the stratospheric winds and the S2(p) QBO signature are highly correlated, thus confirming earlier analysis. On this basis, pressure measurements obtained at Batavia (now Djakarta: 6^○S, 107^○E) from 1870 to 1944 are used to trace back the QBO phenomenon before the advent of systematic stratospheric balloon measurements. The inferred period, which varies between 25 and 32 months, suggests that the QBO has been present in the atmosphere at least since 1870.     

Numerical homogenization-based seismic assessment of an English-bond masonry prototype: Structural level application

A multiscale strategy is evaluated at a structural level for the analysis of unreinforced masonry structures. The mechanical characterization of the masonry is deduced from homogenization-based micro-scale finite element (FE) models. The derived data are here employed at a structural level via a discrete FE model. The discrete FE model is composed of quadrilateral rigid plates interconnected through vertical and horizontal interfaces. On the interfaces, between adjoining discrete elements, a model that accounts for the in- and out-of-plane behavior of masonry, with damage and plasticity, is adopted. Such interfaces represent the material pre- and post-peak regimes, its orthotropy, and, depending on the micro-model assumed, account by three-dimensional shear effects that are especially important for multi-leaf walls and complex regular textures. The discrete model has been implemented in an advanced structural analysis software where powerful built-in features as the arc-length method, line-search algorithm, and implicit or explicit solver schemes are available. The multi-scale model is applied for the dynamic study of a small English-bond masonry house prototype subjected to a series of consecutive earthquake records. Detailed comparisons between the experimental and numerical data are presented, including the results obtained through a continuous total strain rotating crack model. Quasi-static and dynamic analyses are conducted. Results demonstrate that when enough experimental information is available on the masonry components under tension, shear, and compression regimes, the approach predicts well the seismic structural response in terms of time-history displacements, seismic capacity, and damage patterns. The required computational cost (CPU time) is very attractive.     

Water-poverty relationships in the coastal town of Mbour (Senegal): Relevance of GIS for decision support

Coastal area is always a zone with complex problems. Due to the attraction they exert, are facing many social problems. Therefore, a coastal city is usually a city with problems. Its extension, caused by the influx of people from different backgrounds, creates an increased demand for services. One of the problems frequently encountered, especially in Senegal, is access to water. The problem of access to water is poorly treated, without being correlated with the urban evolution, i.e. with increasing population and demand growth. The water resource is facing numerous complications such as the lack of integrated management, integration issues at the governance level, where the local factor is often forgotten.The town of Mbour, object of our study, does not come out of that lot, being an attractive coastal city, from an African country. This indicates the need for an integrated management oriented from local to a global basis and not vice versa. The study presented in this paper indicates that a large proportion of the population has not access to a verified drinking water system and uses water from wells or standpipes. Half of the surveyed population (50%) has no access to a water supply system. The water poverty map of the town overlaps with that of the general poverty excepting few neighborhoods. This means that even areas that are not affected by poverty have a very low or poor access to water, which so far remains the perverse effect of the reform of the Senegalese water sector in 1995.