Isotopic,mineralogical, and thermobarometric variations of Al-Wahbah crater (Maklaa Tameya), Kishb area,Saudi Arabia

The Cenozoic volcanism of western Saudi Arabia extends from southern Yemen to Jordan northward. They cover an area of nearly 180,000 km². The rocks are dominated by alkali olivine basalts and olivine basalts. Al-Wahbah crater, a part of Harrat Kishb, represents a model occurrence to study the gneisses of these rocks. New mineral chemistry and isotopic data are presented. It aims to follow the isotopic, mineralogical, and thermobarometry variations among these volcanics. Amphiboles of the studied volcanics belong to the monoclinic calcic group. The chemistry of the amphibole crystals shows two ranges of pressure. They are 3.6–5.6 and 0.38–0.78 kbar. The Al_iv values of the amphiboles are in the range of 1.202 and 1.407, indicating corresponding temperature condition of 820–920 and 620–720 °C, respectively. The feldspar of the studied samples has the composition of plagioclase, though some grains have sanidine composition. They are formed in temperature range of 975 and 400 °C. The coexisting amphiboles and plagioclases indicate two sets of pressure and temperature. They are 540–575 °C (3.5–4 kbar) and 510–525 °C (~2 kbar), respectively. Rb–Sr isochron of the whole rock yields an age of 0.867 ± 0.160 Ma with initial Sr⁸⁷/Sr⁸⁶ of 0.702 ± 0.00086. The low initial ratio of Sr⁸⁷/Sr⁸⁶ together with positive values of εNd today implies that the studied volcanics have mantle source. Meanwhile, the present isotopic data suggest extraction of juvenile magma from asthenosphere source. The present study shows that the Al-Wahbah crater rocks belong to Cenozoic basalts and indicate EM-I-like signature.     

Albian extrusion evidences of the Triassic salt and clues of the beginning of the Eocene atlasic phase from the example of the Chitana-Ed Djebs structure (N.Tunisia): Implication in the North African Tethyan margin recorded events, comparisons

In the northern part of Tunisia, close to Testour/Slouguia, new observations and updated biostratigraphy make it possible to highlight the relation between the Triassic saliferous mass and the surrounding Mesozoic beds (T. M.). Near the (T. M.) boundary, the formations observed consist dominantly of Triassic evaporites reworked in the Early and Late Albian deep-water sedimentary deposits. Throughout the studied area, Jurassic rocks are absent. We propose to interpret the Chitana-Ed Djebs structure originally emplaced as gravitational stretch masses in a passive margin in the same way as the salt bodies of widespread salt province in the Gulf of Mexico. A reconstructed schematic position of the Chitana-Ed Djebs salt body displays a scenario of setting of the salt mass on a submarine palaeo-slope. Moreover, the starting clues of the paroxysmal event of the Late Mesozoic tectonic inversion clearly fossilized through the discordance of the Middle Eocene–Early Lutetian limestone on the Albian series.     

The role of rural-rural migration as a survival strategy in the Sahelian zone of the Sudan —

Taking the example of Burush, N Darfur, Sudan, the authors analyse the role of migration as a survival strategy in the desertification-stricken Sahelian zone. It is being argued that the rual-rual migration plays a greater role than the rual-urban migration among the Berti ethnic group of northern Darfur. Their high mobility within their own area is part of their traditional economic pattern for coping with aridity and high rainfall variability     

Acquisition de salinité et qualité des eaux d’une nappe profonde en Tunisie: approche statistique et géochimique

Abstract

The multi-layered Jeffara de Gabes aquifer system is greatly influenced by tectonics. This system is limited at the base and laterally by evaporite layers and has lateral contacts with the sebkhas (salt flats). The groundwater in this aquifer is characterized by high salinity (3–10 g L^-1). Multivariate statistical analysis and a geochemical approach were applied to determine the influence of the evaporite layers and sebkhas on the hydrochemical quality of the Jeffara de Gabes aquifer, and to understand the processes governing its salinity. According to these methods, and based in part on the Sr²⁺/Ca²⁺ ratio, it is demonstrated that the strong salinity of the groundwater is due to interactions between water and the evaporite layers that act as a substratum of this aquifer, as well as saltwater intrusion from the sebkhas. Moreover, the medium- to poor-quality groundwaters are characterized by geochemical interactions: cationic exchange and the precipitation/dissolution process of minerals in the aquifer formations.

Editeur Z.W. Kundzewicz

Citation Ben Alaya, M., Zemni, T., Mamou, A. et Zargouni, F., 2014. Acquisition de salinité et qualité des eaux d’une nappe profonde, Tunisie: approche statistique et géochimique. Hydrological Sciences Journal, 59 (2), 395–419.     

Characterization and Application of Dried Plants to Remove Heavy Metals,Nitrate, and Phosphate Ions from Industrial Wastewaters

Low cost adsorbents were prepared from dried plants for the removal of heavy metals, nitrate, and phosphate ions from industrial wastewaters. The efficiency of these adsorbents was investigated using batch adsorption technique at room temperature. The dried plant particles were characterized by N₂ at 77 K adsorption, scanning electron microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, and phytochemical screening. The adsorption experiments showed that the microparticles of the dried plants presented a good adsorption of heavy metals, phosphate, and nitrate ions from real wastewaters. This adsorption increased with increasing contact time. The equilibrium time was found to be 30 min for heavy metals and nitrate ions and 240 min for phosphate ions. After the adsorption process, the Pb(II) concentrations, as well as those of Cd(II), Cu(II), and Zn(II) were below the European drinking water norms concentrations. The percentage removal of heavy metals, nitrates, and phosphates from industrial wastewaters by dried plants was ～94% for Cd²⁺, ～92% for Cu²⁺, ～99% for Pb²⁺, ～97% for Zn²⁺, ～100% for ${\rm NO}_{{\rm 3}}^{{-} } $ and ～77% for ${\rm PO}_{{\rm 4}}^{3{-} } $ ions. It is proved that dried plants can be one alternative source for low cost absorbents to remove heavy metals, nitrate, and phosphate ions from municipal and industrial wastewaters.     

Role of Fracturing in the Organization of the Karst Features of Azrou Plateau (Middle Atlas,Morroco) Studied by Remote Sensing Imagery

Karst formation geometry can be controlled by fractures and faults, and by other lithologies. Here we show the organization of kastic collapse features related to structures and to extensive basaltic lava flows in the Middle Atlas of Morocco. A lineament map of major faults and fractures has been created for the Middle Atlas using Landsat 7 ETM⁺ satellite images. This shows a dominant NE–SW regional direction and less prominent NNW–SSE and ENE–WSE directions. All these directions coincide with the alignments of karstic depressions that have formed in the Liassic limestones. The basaltic flows covering these formations on the Middle Atlas limestone plateau, have allowed the generation of cryptokarst, geometrically organized a long these major lineament directions. Karst landforms probabaly existed before the eruption of the lavas, but there were partly invaded by intrusions and volcanism. The extensive basaltic flows allowed for increased infiltration, and subsurface water flow, increasing the rate of kast formation after eruptions. Some basins show evidence of increased subsidence after lava emplacement (Aguelmam Sidi Ali Lake) and some maar-like craters also have subsided after eruption, by karts formation. We lay out the structural and lithological controls on Karstic formation in an intraplate volcanic field based on limestones and evaporites.     

Impact of shore-parallel breakwaters on the microtidal coast of Hammam-Lif (North-East of Tunisia)

The Hammam Lif coast (North-East of Tunisia) suffered from erosion mainly after the storm that damaged the zone in 1981. To protect it, eight shore-parallel breakwaters were built. The present study is interested in presenting the effect of the protection works on the coastline behavior by using aerial photographs geo-referenced by the digital photogrammetric method and empirical relationships. The successive breakwaters made a general accretion with formation of seven tombolos and salient. The response of the coast to these structures was related to the characteristics of these latter (length, distance to coast, and spacing). The effectiveness of such protection works is shown by the evaluation of the accretion areas formed behind them. The breakwaters which are the longest, less distant from the shoreline, and less spaced formed well-developed tombolos. Whereas, the structures which are short, very far from the coastline, and far from each other caused very small tombolos and even a salient.     

Comparison between measured and predicted values of axial end bearing and skin capacity of piles bored in cohesionless soils in the Arabian Gulf Region

The axial base and skin capacities of piles bored in cohesion less soils are often estimated using empirical, semi-empirical and theoretical methods. The aim of this paper is to assess the applicability and evaluate the accuracy of different predictions methods available in the literature, via comparison with data from 43 field pile load tests conducted on shafts drilled in the region of the United Arab Emirates. Janbu's theoretical method (1989) with the parameter (=75°) and Vesics theoretical method (1975) yielded accurate predictions for the base resistances. Burlands approach (1973) overpredicts the skin capacities with an average predicted-to-estimated ratio (q _p /q _e) of three times greater than the unity while using values of the coefficient of earth pressure (k=05k _o ) and the angle of soil-pile friction (=23).     

Green synthesis of magnetic mesoporous silica nanocomposite and its adsorptive performance against organochlorine pesticides

Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N₂ adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment.     

Les manifestations tectoniques synsédimentaires associées à la compression éocène en Tunisie : implications paléogéographiques et structurales sur la marge Nord-Africaine

In central Tunisia, a synsedimentary tectonic episode has been pointed out through the tectonic movements affecting the Late Palaeocene–Early Eocene successions. This tectonic episode has controlled, to a large extent, the palaeogeographic setting of the area during that period and confirmed the important effect induced by the Pyrenean shortening phase on the edge of the African plate, which obviously has witnessed a common history with the southern part of the European plate. To cite this article: A. El Ghali et al., C. R. Geoscience 335 (2003).