Distribution surfaces in solvent extraction systems

In the solvent extraction of metals, the distribution of the metal is usually dependent on the concentrations of several different species in the two phases. Despite this fact, distribution isotherms are usually presented as plots of C_o as a function of C_aq and these are used for a McCabe-Thiele type evaluation of a number of stages and flow rates, etc., each individual isotherm being valid only for one set of initial conditions; this treatment limits the possibilities of optimizing the system. In the present paper an extension of three-dimensional plots is suggested with special reference to the Cu/LIX64N extraction system. The distribution surface is defined and the general properties of the plots are outlined.A procedure is outlined whereby the surface can be represented on a two dimensional plot and a theoretical model for the surface can be superimposed.The paper also shows how distribution ratios (D values) are related to the surface.     

Novel observations of benthic enrichment in contrasting flow regimes with implications for marine farm monitoring and management

We examine macrofaunal and physico-chemical responses to organic enrichment beneath salmon farms in contrasting flow environments, and reveal pronounced flow-related differences in the magnitude and spatial extent of effects. Total macrofaunal abundances at high flow sites were nearly an order of magnitude greater than at comparable low flow sites, representing a significant benthic biomass. These very high abundances occurred in conjunction with moderate-to-high species richness, and were evident in the absence of appreciable organic matter accumulation. Biological responses to increasing sulfide were variable; however a significant biological threshold was evident at 1500 μM. Macrofaunal responses at high flow sites differed substantially from the Pearson–Rosenberg model. The atypical ecological conditions were attributed to (i) limited accumulation of fine sediments, (ii) maintenance of aerobic conditions in near-surface sediments, and (iii) an abundant food supply. Thus, enhanced resilience to organic waste at well-flushed sites appears related to both biological and physical processes.     

Scientific field training for human planetary exploration

Forthcoming human planetary exploration will require increased scientific return (both in real time and post-mission), longer surface stays, greater geographical coverage, longer and more frequent EVAs, and more operational complexities than during the Apollo missions. As such, there is a need to shift the nature of astronauts’ scientific capabilities to something akin to an experienced terrestrial field scientist. To achieve this aim, the authors present a case that astronaut training should include an Apollo-style curriculum based on traditional field school experiences, as well as full immersion in field science programs. Herein we propose four Learning Design Principles (LDPs) focused on optimizing astronaut learning in field science settings. The LDPs are as follows:

(1)

LDP#1: Provide multiple experiences: varied field science activities will hone astronauts’ abilities to adapt to novel scientific opportunities

(2)

LDP#2: Focus on the learner: fostering intrinsic motivation will orient astronauts towards continuous informal learning and a quest for mastery

(3)

LDP#3: Provide a relevant experience—the field site: field sites that share features with future planetary missions will increase the likelihood that astronauts will successfully transfer learning

(4)

LDP#4: Provide a social learning experience—the field science team and their activities: ensuring the field team includes members of varying levels of experience engaged in opportunities for discourse and joint problem solving will facilitate astronauts’ abilities to think and perform like a field scientist.

The proposed training program focuses on the intellectual and technical aspects of field science, as well as the cognitive manner in which field scientists experience, observe and synthesize their environment. The goal of the latter is to help astronauts develop the thought patterns and mechanics of an effective field scientist, thereby providing a broader base of experience and expertise than could be achieved from field school alone. This will enhance their ability to execute, explore and adapt as in-field situations require.     

The equation of state of the solar interior: A comparison of results from two competing formalisms

A recently developed treatment of partition functions in the equation of state (Mihalas, Hummer, Däppen, MH&D) has led to a substantial improvement in the agreement between observed and theoretically predicted solar p-mode oscillation frequencies. The MH&D equation of state is a realization of the free-energyminimization method, based on the so-called chemical picture, in which ionization and dissociation reactions are assumed to be those that maximize entropy, or equivalently, minimize the free energy. An alternative equation of state has recently been developed at Livermore. It realizes a virial expansion of pressure, and is based on the physical picture, in which explicitly only fundamental species (i.e., electrons and nuclei) appear. Results of a first comparison between thermodynamic quantities of the MH&D and Livermore equations of state are presented. For simplicity, a mixture with only hydrogen and helium (90% H and 10% He by number) is chosen. The comparison is made for a low-density and a high-density case. In the first case, the conditions are those of the hydrogen and helium ionization zones of the Sun, in the second case those of the solar centre. In both cases, the MH&D and Livermore results agree strikingly, despite the very different formalisms they are based on.     

Photometric observations of Earth‐impacting asteroid 2008 TC3

Abstract– A calibrated lightcurve is presented of the near‐Earth asteroid 2008 TC₃, obtained before it impacted Earth on October 7, 2008. The asteroid was observed in unfiltered images from the end of astronomical twilight until the object entered Earth’s shadow about 2 h later. The observations covered a wide range of phase angles from 14.79° to 2.93°, during which the asteroid ranged from 82,000 km to 29,000 km distance from the observer. A method is presented for obtaining photometrically filtered brightness values for the asteroid using unfiltered imaging techniques. Over 1,700 images of the asteroid produce a lightcurve with a peak‐to‐peak variation in V of 0.76 magnitude. Analysis of the lightcurve yields values for H = 30.86 ± 0.01 and G = 0.33 ± 0.03. Combined with other constraints on the kinetic energy and diameter of the asteroid, which suggest a low 1.8 g cm^?3 density and albedo 0.05 ± 0.01, the value of H implies an asteroid of about 4.1 m in diameter, 28 m³ in volume, and 51,000 kg in mass. The determined value of G is out of range for normal, larger asteroids of albedo 0.05–0.15.     

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.     

Using spatial statistics to identify and characterise ethnoburbs: establishing a methodology using the example of Auckland,New Zealand

Recent studies in the United States and other Pacific Rim countries have identified a new form of ethnic minority group clustering within the residential mosaic—ethnoburbs. These are suburban in location, occupied by relatively high-income, predominantly Asian, immigrants, and low density in their nature: many migrants move directly to those suburbs rather than the inter-generational outward migration from central city clusters typical of other migrant streams. Although ethnoburb residents tend to cluster in particular segments of the built-up area they do not to form large percentages of the population there. As yet, no methodology has been developed to identify these clusters, as a prelude to identifying their characteristics. This paper offers such a procedure, based on local statistical analysis. It is applied to six Asian groups in Auckland, New Zealand.     

The inner city: In search of the problem

This paper explores the theoretical content of the inner-city debate in Britain and seeks to examine the extent to which the ‘problem’ is either new or primarily economic. It is argued that the inner-city issue, while subject to specific political and ideological forces, is associated with the general processes of uneven capitalist development. In this sense, metropolitan decline is a further manifestation of the relationship between the built environment, the transience of economic activity and social change. More specifically the decline of the inner city relates to the incipient role of Britain in the development of capitalism and its current position in the world economy. The emergence of this as a ‘problem’ for the British state is combined with a convenient spatial determinism, which isolates the inner city as an anomaly even as the search for palliatives is erected to the status of a major social task.